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AbstractDecarbonising the energy system requires high shares of variable renewable generation and sector coupling like power to heat. In addition to heat supply, heat pumps can be used in future energy systems to provide flexibility to the electricity system by using the thermal storage potential of the building stock and buffer tanks to shift electricity demand to hours of high renewable electricity production. Bridging the gap between two methodological approaches, we coupled a detailed building technology operation model and the open-source energy system model Balmorel to evaluate the flexibility potential that decentral heat pumps can provide to the electricity system. Austria in the year 2030 serves as an example of a 100% renewable-based electricity system (at an annual national balance). Results show that system benefits from heat pump flexibility are relatively limited in extent and concentrated on short-term flexibility. Flexible heat pumps reduce system cost, CO2 emissions, and photovoltaics and wind curtailment in all scenarios. The amount of electricity shifted in the assessed standard flexibility scenario is 194 GWhel and accounts for about 20% of the available flexible heat pump electricity demand. A comparison of different modelling approaches and a deterministic sensitivity analysis of key input parameters complement the modelling. The most important input parameters impacting heat pump flexibility are the flexible capacity (determined by installed capacity and share of control), shifting time limitations, and cost assumptions for the flexibility provided. Heat pump flexibility contributes more to increasing low residual loads (up to 22% in the assessed scenarios) than decreasing residual load peaks. Wind power integration benefits more from heat pump flexibility than photovoltaics because of the temporal correlation between heat demand and wind generation.

To determine the potential impacts of micro-turbines on future distribution system, dynamic models of micro-turbines should be created, reduced in order, and scattered throughout test feeders. This paper presents the implementation of an efficient method for computing low order linear system models of micro-turbines from time domain simulations. The method is the Box-Jenkins algorithm for calculating the transfer function of a linear system from samples of its input and output.

BackgroundAlcohol abuse is a risk factor for bone damage and fracture‐related complications. Through precise β‐catenin signaling, canonical Wnt signaling plays a key role in fracture repair by promoting the differentiation of new bone and cartilage cells. In this study, we examined the effects of alcohol on the Wnt pathway in injured bone using a murine model of alcohol‐induced impaired fracture healing.MethodsMale C57Bl/6 or T cell factor (TCF)‐transgenic mice were administered 3 daily intraperitoneal doses of alcohol or saline. One hour following the final injection, mice were subjected to a stabilized, mid‐shaft tibial fracture. Injured and contralateral tibias were harvested at 6, 9, or 14 days post‐fracture for the analysis of biomechanical strength, callus tissue composition, and Wnt/β‐catenin signaling.ResultsAcute alcohol treatment was associated with a significant decrease in fracture callus volume, diameter, and biomechanical strength at day 14 post‐fracture. Histology revealed an alcohol‐related reduction in cartilage and bone formation at the fracture site, and that alcohol inhibited normal cartilage maturation. Acute alcohol exposure caused a significant 2.3‐fold increase in total β‐catenin protein at day 6 and a significant decrease of 53 and 56% at days 9 and 14, respectively. lacZ staining in β‐galactosidase‐expressing TCF‐transgenic mice revealed spatial and quantitative differences in Wnt‐specific transcriptional activation at day 6 in the alcohol group. Days 9 and 14 post‐fracture showed that acute alcohol exposure decreased Wnt transcriptional activation, which correlates with the modulation of total β‐catenin protein levels observed at these time points.ConclusionsAcute alcohol exposure resulted in significant impairment of fracture callus tissue formation, perturbation of the key Wnt pathway protein β‐catenin, and disruption of normal Wnt‐mediated transcription. These data suggest that the canonical Wnt pathway is a target for alcohol in bone and may partially explain why impaired fracture healing is observed in alcohol‐abusing individuals.

Abstract Socio-technical transformations towards low-carbon energy systems are on the way in developed countries. Conversely, developing countries tend to be locked in fossil fuels and foster coal-based energy structures, emphasizing reliable and cost-effective energy provision and sidelining environmental concerns. In this study, we identified and analysed the predominant factors related to coal-based power generation in Bangladesh. We applied a mixed-method approach, initially conducting a systematic literature review and, subsequently, semi-structured expert interviews to identify and validate relevant factors. We then assessed their relative importance using an Analytical Hierarchy Process based on expert judgments. The results of this assessment reveal that socio-economic aspects and environmental issues scored highest, while technological aspects and sector regulations were considered to be less relevant for large-scale coal power implementation. We conclude that future energy policies created in Bangladesh will need to use appropriate legal instruments and address issues such as human displacement and resettlement, low levels of public acceptance, health hazards and environmental pollution. Participative policy frameworks should be deployed in coal plant projects, and active monitoring systems are necessary to reduce the negative consequences associated with increased electrification and energy consumption. To address foreseeable structural challenges, it furthermore will be crucial to explore sustainable alternatives.

Construction involves the use of significant quantities of raw materials and entails high-energy consumption. For the sake of choosing the most appropriate solution that considers environmental and sustainable concepts, tools such as the integrated value model for sustainable assessment (Modelo Integrado de Valor para una Evaluación Sostenible, MIVES) used in Spain, plays a key role in obtaining the best solution. MIVES is a multi-criteria decision-making method based on the value function concept and the seminars delivered by experts. Such tools, in order to show how they may work, require application to case studies. In this paper, two concrete slabs manufactured with differing reinforcements during the construction of the La Canda Tunnels are compared by means of MIVES. The two concrete slabs were reinforced with a conventional steel-mesh and with polyolefin fibres. This research was focussed on the main aspects affecting the construction. That is to say, the environmental, economic, and social factors were assessed by the method, being of special impact the issues related with maintenance of the structure. The results showed that from the point of view of sustainability, the use of polyolefin fibres provided a significant advantage, mainly due to the lower maintenance required.

The ethanolic fermentation of liquid fractions (hydrolysates) issued from dilute acid pre-treatment of olive tree biomass by Pichia stipitis is reported for the first time. On the one side, P. stipitis has been reported as the most promising naturally occurring C5 fermenting microorganism; on the other side, olive tree biomass is a renewable, low cost, and lacking of alternatives agricultural residue especially abundant in Mediterranean countries. The study was performed in two steps. First, the fermentation performance of P. stipitis was evaluated on a fermentation medium also containing the main inhibitors found in these hydrolysates (acetic acid, formic acid, and furfural), as well as glucose and xylose as carbon sources. The effect of inhibitors, individually or in a mixture, on kinetic and yield parameters was calculated. In a second step, hydrolysates obtained from 1% (w/w) sulfuric acid pre-treatment of olive tree biomass at 190ºC for 10 min were used as a real fermentation medium with the same microorganism. Due to inhibition, effective fermentation required dilution of the hydrolysate and either overliming or activated charcoal treatment. Results show that ethanol yields obtained from hydrolysates, ranging from 0.35 to 0.42 g/g, are similar to those from synthetic medium, although the process proceeds at lower rates. Inhibiting compounds affect the fermentation performance in a synergistic way. Furfural is rapidly assimilated by the yeast; acetic acid and formic acid concentrations decrease slowly during the process. Activated charcoal or overliming detoxification improve the fermentability of diluted hydrolysates.

This article examines land-use, market and welfare implications of lignocellulosic bioethanol production in Hawaii to satisfy 10% and 20% of the State's gasoline demand in line with the State's ethanol blending mandate and Alternative Fuels Standard (AFS). A static computable general equilibrium (CGE) model is used to evaluate four alternative support mechanisms for bioethanol. Namely: (i) a federal blending tax credit, (ii) a long-term purchase contract, (iii) a state production subsidy financed by a lump-sum tax and (iv) a state production subsidy financed by an ad valorem gasoline tax. We find that because Hawaii-produced bioethanol is relatively costly, all scenarios are welfare reducing for Hawaii residents: estimated between -0.14% and -0.32%. Unsurprisingly, Hawaii.s economy and its residents fair best under the federal blending tax credit scenario, with a positive impact to gross state product of $49 million. Otherwise, impacts to gross state product are negative (up to -$63 million). We additionally find that Hawaii-based bioethanol is not likely to offer substantial greenhouse gas emissions savings in comparison to imported biofuel, and as such the policy cost per tonne of emissions displaced ranges between $130 to $2,100/tonne of CO2e. The policies serve to increase the value of agricultural lands, where we estimate that the value of pasture land could increase as much as 150% in the 20% AFS scenario.

Sustainable electricity generation is one of the major current challenges for our society. In this context, the evolution of nanomaterials and nanotechnologies has enabled the fabrication of microscopic devices to produce clean energy from a great variety of renewable sources. To expand the possibilities of energy generation, we have designed and fabricated bioinorganic generators capable to produce electricity by conversion of chemical energy from renewable fuel sources. Unlike traditional generators, the systems described herein produce mechanical energy through enzyme-driven gas production which generates vibration and pressure that are thus converted into electricity by the action of a piezoelectric component properly integrated into the device. Our generators are able to produce an electric ernergy from different renewable sources like glucose, ethanol, and amino acids, attaining energy outputs around 250 nJ cm–2 and reaching maximum open-circuit voltages of up to 1 V. In addition, the produced energy can be easily regulated by adjusting both enzyme and fuel concentration which can tune the electrical output according to the application. The systems described herein propose a new concept for self-sufficient energy harvesting that bridges biocatalysis and piezoelectricity, where the energy production is based on the piezoelectric effect triggered by enzymatic action rather than on the enzyme-driven electron transfer that governs biofuel cells. Although the electric output is too low yet to be considered an alternative for energy production, this technology opens the door to power small devices. We envision the utilization of this technology in such remote locations where mechanical energy is lacking but there are chemical energy reservoirs. We would like to acknowledge Marie-Curie Actions (NANOBIENER project), IKERBASQUE foundation for funding F.L.-G., and the support of COST Action CM1303 Systems Biocatalysis. We also acknowledge HERGAR foundation for the funding. Peer reviewed