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Sustainable electricity generation is one of the major current challenges for our society. In this context, the evolution of nanomaterials and nanotechnologies has enabled the fabrication of microscopic devices to produce clean energy from a great variety of renewable sources. To expand the possibilities of energy generation, we have designed and fabricated bioinorganic generators capable to produce electricity by conversion of chemical energy from renewable fuel sources. Unlike traditional generators, the systems described herein produce mechanical energy through enzyme-driven gas production which generates vibration and pressure that are thus converted into electricity by the action of a piezoelectric component properly integrated into the device. Our generators are able to produce an electric ernergy from different renewable sources like glucose, ethanol, and amino acids, attaining energy outputs around 250 nJ cm–2 and reaching maximum open-circuit voltages of up to 1 V. In addition, the produced energy can be easily regulated by adjusting both enzyme and fuel concentration which can tune the electrical output according to the application. The systems described herein propose a new concept for self-sufficient energy harvesting that bridges biocatalysis and piezoelectricity, where the energy production is based on the piezoelectric effect triggered by enzymatic action rather than on the enzyme-driven electron transfer that governs biofuel cells. Although the electric output is too low yet to be considered an alternative for energy production, this technology opens the door to power small devices. We envision the utilization of this technology in such remote locations where mechanical energy is lacking but there are chemical energy reservoirs. We would like to acknowledge Marie-Curie Actions (NANOBIENER project), IKERBASQUE foundation for funding F.L.-G., and the support of COST Action CM1303 Systems Biocatalysis. We also acknowledge HERGAR foundation for the funding. Peer reviewed

El proyecto REVen “Rehabilitación energética de viviendas sociales, aplicando productos innovadores de ventana con marcado CE” (BIA2014-56650-JIN), tiene como objetivo realizar un análisis integral del impacto de la ventana en los aspectos relativos a eficiencia energética y calidad ambiental. Para caracterizar los flujos de energía y las condiciones ambientales internas se ha construido el Laboratorio REVen. Este artículo describe la construcción y la monitorización de este laboratorio analizando los datos de su primer año de funcionamiento. Los resultados permiten afirmar que se logra una mejora significativa del confort térmico obteniendo un ahorro de energía anual del 25 %.

Recurrent cycles of climatic change during the Quaternary period have dramatically affected the population genetic structure of many species. We reconstruct the recent demographic history of the coyote ( Canis latrans ) through the use of Bayesian techniques to examine the effects of Late Quaternary climatic perturbations on the genetic structure of a highly mobile generalist species. Our analysis reveals a lack of phylogeographic structure throughout the range but past population size changes correlated with climatic changes. We conclude that even generalist carnivorous species are very susceptible to environmental changes associated with climatic perturbations. This effect may be enhanced in coyotes by interspecific competition with larger carnivores.

We analyzed 19 annual Landsat Thematic Mapper images from 1984 to 2011 to determine changes of the glaciated surface and snow line elevation in six mountain areas of the Cordillera Huaytapallana range in Peru. In contrast to other Peruvian mountains, glacier retreat in these mountains has been poorly documented, even though this is a heavily glaciated area. These glaciers are the main source of water for the surrounding lowlands, and melting of these glaciers has triggered several outburst floods. During the 28-year study period, there was a 55% decrease in the surface covered by glaciers and the snowline moved upward in different regions by 93 to 157. m. Moreover, several new lakes formed in the recently deglaciated areas. There was an increase in precipitation during the wet season (October-April) over the 28-year study period. The significant increase in maximum temperatures may be related to the significant glacier retreat in the study area. There were significant differences in the wet season temperatures during El Niño (warmer) and La Niña (colder) years. Although La Niña years were generally more humid than El Niño years, these differences were not statistically significant. Thus, glaciers tended to retreat at a high rate during El Niño years, but tended to be stable or increase during La Niña years, although there were some notable deviations from this general pattern. Climate simulations for 2021 to 2050, based on the most optimistic assumptions of greenhouse gas concentrations, forecast a continuation of climate warming at the same rate as documented here. Such changes in temperature might lead to a critical situation for the glaciers of the Cordillera Huaytapallana, and may significantly impact the water resources, ecology, and natural hazards of the surrounding areas. © 2013 Elsevier B.V. This work was supported by funding from the Spanish Research Council (research project I-COOP0089: “Glacier retreat in the Cordillera Blanca and Cordillera Huaytapallana in Peru: Evidences and Impacts on local population”) Peer Reviewed

The increase in abiotic and biotic stress driven by global change threatens forest ecosystems and challenges understanding of mechanisms producing mortality. Phytophthora spp. like P. cinnamomi (PHYCI) are among the most lethal pathogens for many woody species including Quercus spp. Dynamics of biotic agents and their hosts are complex and influenced by climatic conditions. We analysed radial growth trends of dead and live adult Quercus ilex trees from agrosilvopastoral open woodlands under intense land-use. A pronounced warming trend since the 1980s has coincided in these woodlands with high oak mortality rates generally attributed to PHYCI. Yet, tree mortality and latency of the pathogen could be expressed at variable time spans, whereas, like in many other forests worldwide, tree death could also be explained by other factors like drought. PHYCI was isolated from roots of all dead oaks from one region. Trees were younger than generally believed and ages of dead trees ranged between 38 and 230 years. Growth of dead trees reached a tipping point in 1980 and 1990 coincident with two-year extraordinary droughts. These dates set the start of growth declines up to 30 years before tree death. Live trees did not exhibit any recent growth decline. Tree growth was highly sensitive to climatic variability associated with water stress and climate-growth relationships suggested phenological changes since the 1980s. Live and dead trees showed differences in their sensitivity to moisture availability and temperature. The sensitivity of growth to climate was partially related to site environmental conditions. Simulated gross and net primary productivity were higher in live sites with less atmospheric demand for water. Tree death was not sudden but a slow multiannual process as expressed by radial growth declines likely triggered by drought. Regardless of the causal agent or mechanism, the observed mortality affected trees exhibiting negative drought and land-use legacies.

The agro-livestock sector produces about one third of global greenhouse gas (GHG) emissions. Since more energy is needed to meet the growing demand for food and the industrial revolution in agriculture, renewable energy sources could improve access to energy resources and energy security, reduce dependence on fossil fuels, and reduce GHG emissions. Hydrogen production is a promising energy technology, but its deployment in the global energy system is lagging. Here, we analyzed the theoretical and practical application of green hydrogen generated by electrolysis of water, powered by renewable energy sources, in the agro-livestock sector. Green hydrogen is at an early stage of development in most applications, and barriers to its large-scale deployment remain. Appropriate policies and financial incentives could make it a profitable technology for the future.

The interest in high homogenization pressure technology has grown over the years. It is a green technology with low energy consumption, not generating high CO2 emissions or polluting effluents. The main food applications derive from its effect on particle size, causing a more homogeneous distribution of fluid elements (particles, globules, droplets, aggregates, etc.) and favouring the release of intracellular components; and its effect on the structure and configuration of chemical components such as polyphenols and macromolecules such as carbohydrates (fibres) and proteins (also microorganisms and enzymes). The challenges of the 21st century lead food industry processing towards obtaining food with high nutritional quality and taking advantage of waste to obtain ingredients with specific properties. For this purpose, soft and non-thermal technologies such as high pressures homogenization have a huge potential. The objective of this work is to review how the need to combine safety, functionality and sustainability in food industry has conditioned the last decade applications of high-pressure homogenization technology.