• Energy Research
• ES close
• JP close

Considering recent environmental regulations, the need to adapt domestic biomass combustion systems to models that generate less emissions has gained relative importance. The present research proposes an analysis of the bed cooling effects on emission patterns, specifically focusing on the concentration, typology and morphological aspects of the released particles. The study was carried out by comparing the behaviour of a small-scale pilot plant with air stratification, with and without bed cooling. The results revealed an optimal behaviour of the facility with distributions of 30% primary-70% secondary air, accompanied by a significant decrease in emissions due to the reduction in the operating temperatures. More than 75% of the particles were retained in the bed on the cooled surfaces due to the effect of the prominent temperature gradient that was produced. Among the types of emitted particles (mostly with sizes below 0.1 μm), the presence of partial biomass degradation remnants was observed, representing three-quarters of the total collected matter. To a lesser extent, the presence of carbonaceous agglomerates was detected and usually in very compact clusters; however, in cases of high primary air supply, large amounts of immature soot were observed. Agencia Estatal de Investigación | Ref. RTI2018-100765-B-I00

We evaluated the effects of the seed saponins of Thea sinensis L. on alcohol absorption and metabolism in rats and mice. An ethanolic extract from the seeds of T. sinensis was orally administered to the rats 1 hr before or 0.5 hr after administration of ethanol (2 g/kg), and the blood ethanol assayed 0.5, 1, 2, 3, and 4 hr after ethanol administration. The ethanol level decreased after both pre- and post-administration of the extract. The extract was further purified to obtain a saponin fraction which was orally administered to mice 1 hr before ethanol administration. Blood, liver, and stomach were obtained 0, 1, 3, and 6 hr after ethanol administration, and the ethanol, acetaldehyde, acetate, and acetone concentrations in each specimen were measured by head space gas chromatography. The saponin fraction decreased the ethanol levels in the blood and liver but increased that in the stomach five-fold over the control level, suggesting inhibition of alcohol absorption. The ethanol disappearance time from the blood was shortened, suggesting the promotion of alcohol disappearance. The acetate and acetone levels were unaffected. However, the acetaldehyde level decreased in the blood, liver, and stomach. The decreases in the ethanol and acetaldehyde levels in the liver suggested the protective effects of the seed saponins on the liver. The saponins did not directly inhibit hepatic alcohol dehydrogenase activity. The seed saponins of T. sinensis seem to suppress alcohol absorption by slowing gastric emptying and by inhibiting absorption across the cell membranes of the digestive tract.

Percutaneous transluminal septal myocardial ablation (PTSMA) is a new therapeutic option for patients with hypertrophic obstructive cardiomyopathy (HOCM). In the present study, the acute and follow-up results of PTSMA were evaluated. From August 1997 to March 2003 27 medically refractory patients (New York Heart Association (NYHA) functional class 2.9+/-0.6) with HOCM underwent PTSMA. The target septal branch was determined by probationary ballooning in 3 and by myocardial contrast echocardiography in 24 patients. The mean resting left ventricular outflow tract pressure gradient (PG) was reduced from 70+/-44 to 24+/-22 mmHg (p<0.0001); the peak concentration of creatine kinase was 1545+/-686 IU/L. Although transient trifascicular block was observed in 14 patients, permanent pacemaker implantation was not required. There were no major adverse cardiac events during the hospital stay; the mean clinical follow-up was 2.2+/-1.7 years. Repeated PTSMA was needed in 1 patient; however, symptomatic improvement had been well preserved in all patients (NYHA class 1.2+/-0.4). Follow-up echocardiographic examination showed sustained improvement in PG, septal and left ventricular posterior wall thicknesses, and the grade of systolic anterior movement and regurgitation of the mitral valve. In conclusion, PTSMA is a safe and effective therapeutic option for medically refractory patients with HOCM.

Fullerene-based materials are widely used as acceptor and electron transport layer materials in organic and planar perovskite solar cells. Modeling of electronic properties such as band alignment and charge transport for these applications is typically done using optimized geometries. Here, we estimate the effects of nuclear motions on band structure, and electron and hole transport in two prototypical fullerenes, C60 and C70. We model the dynamics in solid fullerenes using Density Functional Tight Binding and we use the Density Functional Theory based Projection of Monomer Orbitals on Dimer Orbitals (DIPRO) approach to estimate the effects on the charge transfer integral in the Marcus approximation. We show that room-temperature molecular dynamics cause a shift and spread of frontier orbital energies on the order of 0.1 eV, which leads to an increase by more than a factor of two in the Marcus exponent, and can cause a decrease by up to orders of magnitude in the overlap integral, leading, in most cases, to an overall decrease in the charge transport rate.

Analyzing television discourse during 2021 through a statistical sample of records extracted from TV networks, the configuration that, in the pandemic, adjusted the dialectical mediation between television communication and cognitive capital available for resilience to Climate Change is revealed. This study originates from reports that in collaboration with ECODES and funding from the Ministry for the Ecological Transition and the Demographic Challenge, carried out by the Media Communication Observatory on Climate Change at its headquarters of the MDCS Research Group of the UCM. The analysis revealed how the causes, impacts, mitigation, and adaptation projects to the effects of climate change were communicated, and the identity of those who speak and/or are referred to. The discursive hegemony of mediators (journalists) and politicians is confirmed, to the detriment of scientists, and improved communication for resilience to climate change is promoted. ; Analizado el discurso televisivo durante 2021 a través de una muestra representativa de registros extraídos de cadenas de TV, se revela la configuración que, en la pandemia, ajustó la mediación dialéctica entre comunicación televisiva y capital cognitivo disponible para la resiliencia ante el Cambio Climático. Este estudio se origina en informes que en colaboración con ECODES y financiación del Ministerio para la Transición Ecológica y el Reto Demográfico, realiza el Observatorio de la Comunicación Mediática del Cambio Climático en su sede del Grupo de Investigación MDCS, de la UCM. El análisis desveló cómo se comunicaron las causas, los impactos, los proyectos de mitigación y adaptación ante los efectos del cambio climático, y la identidad de quienes toman la palabra y/o son aludidos. Se confirma la hegemonía discursiva de mediadores (periodistas) y políticos, en detrimento de los científicos, y se promueve mejorar la comunicación para la resiliencia ante el cambio climático.

Free energy of micelle formation has been evaluated for spherical sodium dodecyl sulfate (SDS) in water by a thermodynamic integration method combined with a series of large-scale molecular dynamics calculations following the chemical species model. In particular, free energy change Δμn+10 with respect to the addition of one surfactant molecule to the spherical micelle of size n was obtained as a function of n. The free energy profile showed a minimum followed by a maximum, which corresponds to a peak in the size distribution. The calculated peak size n=57 near its critical micelle concentration is in good agreement with the experimental averaged aggregation number n=55–75 of the SDS micelle. The distribution showed a rather sharp peak, indicating that the size is almost a monodisperse one. The size is likely to be insensitive to the total concentration of the surfactant.