• Energy Research
• Open Access close
• Restricted close
• Embargo close
• 13. Climate action close
• 15. Life on land close
• 2. Zero hunger close
• US close
• ES close

Abstract. The impact of multiphase reactions involving nitrogen dioxide (NO2) and aromatic compounds was simulated in this study. A mechanism (CAPRAM 2.4, MODAC Mechanism) was applied for the aqueous phase reactions, whereas RACM was applied for the gas phase chemistry. Liquid droplets were considered as monodispersed with a mean radius of 0.1 µm and a liquid content (LC) of 50 µg m-3. The multiphase mechanism has been further extended to the chemistry of aromatics, i.e. reactions involving benzene, toluene, xylene, phenol and cresol have been added. In addition, reaction of NO2 with dissociated hydroxyl substituted aromatic compounds has also been implemented. These reactions proceed through charge exchange leading to nitrite ions and therefore to nitrous acid formation. The strength of this source was explored under urban polluted conditions. It was shown that it may increase gas phase HONO levels under some conditions and that the extent of this effect is strongly pH dependent. Especially under moderate acidic conditions (i.e. pH above 4) this source may represent more than 75% of the total HONO/NO2 - production rate, but this contribution drops down close to zero in acidic droplets (as those often encountered in urban environments).

This paper addresses some questions that climate change raises for international law. It focuses in particular on the request for an advisory opinion submitted by the United Nations General Assembly to the International Court of Justice (ICJ) on 29 March 2023. This request is analysed as a further manifestation of the international community’s concern to clarify the international responsibility of states to prevent, mitigate and remedy the damage caused by climate change. The study argues that the ICJ could clarify obligations under existing treaties. There may also be a particular opportunity for the Court to expand its jurisprudence on other sources of international law. In particular, it asks whether the ICJ could confirm the emergence of a specific customary rule on the issue.

AbstractGold, silver, platinum and palladium typically crystallize with the face-centred cubic structure. Here we report the high-yield solution synthesis of gold nanoribbons in the 4H hexagonal polytype, a previously unreported metastable phase of gold. These gold nanoribbons undergo a phase transition from the original 4H hexagonal to face-centred cubic structure on ligand exchange under ambient conditions. Using monochromated electron energy-loss spectroscopy, the strong infrared plasmon absorption of single 4H gold nanoribbons is observed. Furthermore, the 4H hexagonal phases of silver, palladium and platinum can be readily stabilized through direct epitaxial growth of these metals on the 4H gold nanoribbon surface. Our findings may open up new strategies for the crystal phase-controlled synthesis of advanced noble metal nanomaterials.

SummaryInequality has recently become a major concern in economics. Leaving aside its social and economic effects is also possible to trace its environmental consequences, which this article attempts to assess. The indicator to be measured is the household's carbon footprint (CF) for different social groups. The deep economic crisis in the Spanish economy between 2008 and 2013 has increased consumption inequality and doubled the number of households below the poverty line. When focusing on domestic consumption, we found that the shopping basket of all income groups has very similar emissions intensities; therefore, the differences among the household CFs depend mainly on the scale effect (i.e., the size of consumption). However, when international trade is also considered, we found that the emission intensity of imports is bigger than the intensity of all the respective domestic goods. Therefore, the share of imported goods and services by social class will be an important determinant of the respective total CF. Before the crisis, households with higher incomes imported 30% of their total consumption items whereas households with lower income imported only 20% of their consumption. During the crisis, the imports of medium‐high‐income households fell to 20%, whereas low‐ and middle‐income families maintained the same import share, which contributed to the reduction of the total household CF.

Nowadays, the issues related with environment preservation assume an increasing importance. Progressively, more sustainable solutions/techniques are being developed to combat environmental destruction. The decision to include themes related to the environment in the curriculum of technological courses in higher education aims to promote more sustainable behaviors and in an indirect way, increase the environmental literacy of the population. Thus, this study aims to evaluate the environmental literacy focusing on four topics, i.e., air pollution, water pollution, global warming, and energy resources. For this purpose, a questionnaire was developed and applied to a convenience sample, formed by individuals of both genders, aged between 20 and 81 years old. The questionnaire intended to collect data to characterize the sample and assess the literacy regarding environmental issues. In order to carry out the environmental literacy assessment, the respondents were asked to express their degree of agreement with some statements related with the environmental themes mentioned above. The data collected was analyzed using data mining tools. The results suggest that the population’s literacy is satisfactory in relation to some issues, but insufficient in relation to others, equally important, but less disseminated.

SignificanceMarginal emissions of CO2from the electricity sector are critical for evaluating many climate policies. We provide estimates of marginal CO2emissions for electricity use in the United States that vary by region, hour of day, and year to year. Despite a decrease in average emissions over the last decade, marginal emissions have increased. We apply our estimates to an analysis of the Biden administration’s target of having electric vehicles make up 50% of new vehicle purchases by 2030. We find that, without significant and concurrent changes to the electricity sector far more substantial than those over the last decade, the increase in electricity emissions is likely to offset more than half the emission reductions from having fewer gasoline-powered vehicles.