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Abstract We propose a novel transparent electrode consisting of silver (Ag)–aluminum doped zinc oxide (AZO)–nickel (Ni) deposited at room temperature on glass and polyethylene terephthalate (PET) for flexible organic photovoltaics. The electrode combines the high electrical conductivity and mechanical ductility of Ag, the transparency and antireflection of AZO and the high work function and stability of Ni. Environmental stability results confirmed that the electrode maintains its optical and electrical properties at both elevated temperature (500 °C) and under damp heat conditions (85 °C and 85% relative humidity). To demonstrate its functional potential, the electrode has been used as the transparent anode in an organic solar cell (OSC), which shows an efficiency of 2.6%, very close to the value (2.9%) obtained in a similar cell using the widely used indium tin oxide (ITO). With respect to ITO, the proposed transparent electrode has several advantages, including mechanical flexibility, room temperature processing and low cost.

beta-Carotene and six xanthophylls (lutein, neoxanthin, violaxanthin, luteoxanthin, cryptoxanthin, and echinenone) have been identified and semiquantitatively or quantitatively determined in musts and port wines for the first time. An HPLC method was developed and compared with that of one based on thin layer cromatography with scanning densitometry. The most abundant carotenoids present in red grape varieties are beta-carotene and lutein. In wines, significant quantities of violaxanthin, luteoxanthin, and neoxanthin were found. This study was done with berries (skin and pulp), musts, and fortified wines. Some experiments were performed to follow carotenoid content from grapes to wines. Although the levels of beta-carotene and lutein found in fortified wines were lower than those found in musts, other xanthophylls, such as neoxanthin, violaxanthin, and luteoxanthin, exist in appreciable amounts in young ports.

Artículos en revistas In this paper we apply stochastic dual dynamic programming decomposition to a nonconvex multistage stochastic hydrothermal model where the nonlinear water head effects on production and the nonlinear dependence between the reservoir head and the reservoir volume are modeled. The nonconvex constraints that represent the production function of a hydro plant are approximated by McCormick envelopes. These constraints are split into smaller regions and the McCormick envelopes are used for each region. We use binary variables for this disjunctive programming approach and solve the problem with a decomposition method. We resort to a variant of the L-shaped method for solving the MIP subproblem with binary variables at any stage inside the stochastic dual dynamic programming algorithm. A realistic large-scale case study is presented. info:eu-repo/semantics/publishedVersion

Abstract In this paper, the integration of a biomass-based diesel–wind system is investigated. The system consists of a pitch controlled wind turbine, which is equipped with an induction generator. The induction generator is connected to an ac bus-bar in parallel with a diesel-generator set consisting of a diesel engine driving a synchronous generator. A power plant can generate electric power using biomass from the olive tree in Spain. A gasifier is capable of converting tons of wood chips per day into a gaseous fuel that is fed into a diesel engine. While there are significant systems whose models may be exactly obtained from physical laws and whose states are measured, it is much less realistic to assume that all the parameters, such as the higher heating value of the biogas or wind speed, are exactly known. It is then natural to investigate what happens to control systems involving unknown, or not precisely known, parameters. In this paper, the derived model of biomass-based wind–diesel systems is quite valid for robust control studies.

The identification of species-rich areas and their prognosticated turnover under climate change are crucial for the conservation of endemic taxa. This study aims to identify areas of reptile endemicity richness in a global biodiversity hot spot (Morocco) under current and future climatic conditions and to investigate the role of protected areas in biodiversity conservation under climate change. Species distribution models (SDM) were performed over the distribution of 21 endemic reptiles, combined to estimate current species richness at 1 × 1 km resolution and projected to years 2050 and 2080 according to distinct story lines and ensemble global circulation models, assuming unlimited and null dispersion ability. Generalized additive models were performed between species richness and geographic characteristics of 43 protected areas. SDM found precipitation as the most important factor related to current species distributions. Important reductions in future suitable areas were predicted for 50 % of species, and four species were identified as highly vulnerable to extinction. Drastic reductions in species-rich areas were predicted for the future, with considerable variability between years and dispersal scenarios. High turnover rates of species composition were predicted for eastern Morocco, whereas low values were forecasted for the Northern Atlantic coast and mountains. Species richness for current and future conditions was significantly related to the altitude and latitude of protected areas. Protected areas located in mountains and/or in the Northern Atlantic coast were identified as refugia, where population monitoring and conservation management is needed.

Abstract Sodium-promoted vanadium oxide catalysts supported on MCM-41 and TiO 2 (anatase) were investigated for the partial oxidation of ethanol to acetaldehyde. The catalysts were prepared by incipient wetness impregnation with a vanadium oxide content of 6 wt.%. The experimental characterization was performed by X-ray diffraction (XRD), N 2 adsorption, temperature-programmed reduction (TPR), and diffuse reflectance UV–vis. Temperature-programmed oxidation (TPO) was also used to identify carbon deposits on the spent catalysts. The presence of sodium plays a strong role in the dispersion and reducibility of the vanadium species as detected by TPR analysis and optical absorption spectroscopy. While sodium addition increases the dispersion of the VO x species, its presence also decreases their reducibility. Additionally, TPO of the spent catalysts revealed that an increase in the Na loading decreases the carbon deposition during reaction. In the case of the catalysts supported on MCM-41, these modifications were mirrored by a change in the activity and selectivity to acetaldehyde. Additionally, on the VO x /TiO 2 catalysts the catalytic activity decreased with increasing sodium content in the catalyst . A model in which sodium affects dispersion, reducibility and also acidity of the supported-vanadia species is proposed to explain all these observations.

Third-generation biofuels are currently a promising alternative for energy production, since electricity prices have risen sharply and the search for alternative energy sources to fossil fuels has become a necessity. The use of the anaerobic digestion process for the production of biomethane from microalgae has been studied over the years and has reached a certain degree of maturity, becoming the most straightforward way to obtain energy from microalgae without the need for a previous drying or extraction phase, thus eliminating the costs associated with these operations. Microalgae also show a high potential to grow in different media, including wastewater, as well as a high capacity for nutrient absorption and carbon dioxide fixation, which aid in decarbonization. These characteristics, combined with biomethane production, can contribute to achieving a satisfactory bioenergy production in a circular economy model. Peer reviewed 2 Tablas