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The hygrothermal behaviour of an internally insulated historic wall is still hard to predict, mainly because the physical characteristics of the materials composing the historic wall are unknown. In this study, the hygrothermal assessment of an internally thermal insulated masonry wall of an historic palace located in Ferrara, in Italy, is shown. In situ non-destructive monitoring method is combined with a hygrothermal simulation tool, aiming to better analyse and discuss future refurbishment scenarios. In this context, the original U-value of the wall (not refurbished) is decreased from 1.44 W/m2K to 0.26 W/m2K (10 cm stone wool). Under the site specific conditions of this wall, not reached by the sun or rain, it was verified that even in the absence of vapour barrier, no frost damage is likely to occur and the condensation risk is very limited. Authors proposed further discussion based on simulation. The results showed that the introduction of a second gypsum board to the studied technology compensated such absence, while the reduction of the insulation material thickness provides a reduction of RH peaks in the interstitial area by 1%; this second solution proved to be more efficient, providing a 3% RH reduction and the avoidance of further thermal losses.

Supercritical Carbon Dioxide (SCO2) is considered as a potential working fluid in next generation power and energy systems. The SCO2 Brayton cycle is advantaged with higher cycle efficiency, smaller compression work, and more compact layout, as compared with traditional cycles. When the inlet total condition of the compressor approaches the critical point of the working fluid, the cycle efficiency is further enhanced. However, the flow acceleration near the impeller inducer causes the fluid to enter two-phase region, which may lead to additional aerodynamic losses and flow instability. In this study, a new impeller inlet design method is proposed to achieve a better balance among the cycle efficiency, compressor compactness, and inducer condensation. This approach couples a concept of the maximum swallowing capacity of real gas and a new principle for condensation design. Firstly, the mass flow function of real gas centrifugal compressors is analytically expressed by non-dimensional parameters. An optimal inlet flow angle is derived to achieve the maximum swallowing capacity under a certain inlet relative Mach number, which leads to the minimum energy loss and a more compact geometry for the compressor. Secondly, a new condensation design principle is developed by proposing a novel concept of the two-zone inlet total condition for SCO2 compressors. In this new principle, the acceptable acceleration margin (AAM) is derived as a criterion to limit the impeller inlet condensation. The present inlet design method is validated in the design and simulation of a low-flow-coefficient compressor stage based on the real gas model. The mechanisms of flow accelerations in the impeller inducer, which form low-pressure regions and further produce condensation, are analyzed and clarified under different operating conditions. It is found that the proposed method is efficient to limit the condensation in the impeller inducer, keep the compactness of the compressor, and maintain a high cycle efficiency.

The large potential for waste resource and heat recovery in industry has been motivating research toward increasing efficiency. Process integration methods have proven to be effective tools in improving industrial sites while decreasing their resource and energy consumption; however, location aspects and their impact are generally overlooked. This paper presents a method based on process integration, which considers the location of plants. The impact of the locations is included within the mixed integer linear programming framework in the form of heat losses, temperature and pressure drop, and piping cost. The objective function is selected as minimisation of the total cost of the system excluding piping cost and ϵ -constraints are applied on the piping cost to systematically generate multiple solutions. The method is applied to a case study with industrial plants from different sectors. First, the interaction between two plants and their utility integration are illustrated, depending on the piping cost limit which results in the heat pump and boiler on one site being gradually replaced by excess heat recovered from the other plant. Then, the optimisation of the whole system is carried out, as a large-scale application. At low piping cost allowances, heat is shared through high pressure steam in above-ground pipes, while at higher piping cost limits the system switches toward lower pressure steam sharing in underground pipes. Compared to the business-as-usual operation of the sites, the optimal solution obtained with the proposed method leads to 20% reduction in the overall cost of the system, including the piping cost. Further reduction in the cost is possible using a state of the art method but the technical and economic feasibility is not guaranteed. Thus, the present work provides a tool to find optimal industrial symbiosis solutions under different investment limits on the infrastructure between plants.

High reactivity coke is beneficial for achieving low carbon emission blast furnace ironmaking. Therefore, the preparation of highly reactive ferro-coke has aroused widespread attention. However, the effects of the particle size of iron ore on the pyrolysis behaviour of a coal-iron ore briquette are still unclear. In this study, the effect of three particle sizes (0.50–1.00 mm, 0.25–0.50 mm and <0.74 mm) of iron ore on the thermal and kinetic behaviours of coal-iron ore briquettes were investigated by non-isothermal kinetic analysis. The results showed that the synergistic effect of iron ore and coal during coking mainly occurred during the later reaction stage (850–1100 °C) and smaller particle sizes of iron ore have a stronger synergistic effect. The addition of iron ore had little effect on T0 (the initial temperature) and Tp (the temperature at the maximum conversion rate) of briquette pyrolysis, however itgreatly affected the conversion rate and Tf (the final temperature) of the briquettes. T0 decreased with the decrease of iron ore particle sizes, while Tp and Tf showed opposite trends. After adding iron ore into the coal briquette, the reaction kinetics at all stages of the coal-iron ore briquettes changed. The weighted apparent activation energy of the caking coal (JM) briquette was 35.532 kJ/mol, which is lower than that of the coal-iron ore briquettes (38.703–55.627 kJ/mol). In addition, the weighted apparent activation energy gradually increased with decreasing iron ore particle sizes.

In renewable energy based systems Grid-Connected Voltage Source Converters (GC-VSC) are used in many applications as grid-feeding converters, which transfer the power coming from the renewable energy sources to the grid. In some cases, the operation of GC-VSC may become unstable or uncontrollable due to, among others: a grid fault or an inappropriate current-power reference, that give rise to fast electrical transients or a saturation of the controller. In this paper, an improved control scheme is proposed to enhance the controllability of GC-VSC in all these situations. This solution consists of two parts, on the one hand a new Proportional-Resonant (PR) controller with anti-windup capability to be used as current controller, and secondly a new current/power reference modifier, which defines the suitable reactive current/power reference to keep the system stable. It is worth to mention that the proposed scheme does not need information about the grid parameters as it only uses the converter current, and the voltage at the capacitors of Inductor-Capacitor (LC) output filter.

Climate change has brought a compelling need for cooling living spaces to the attention of researchers as well as construction professionals. The problem of overheating enclosures is now exacerbated in traditionally affected areas and is also affecting countries that were previously less prone to the issue. In this paper, we address measurements of thermal comfort and cooling emission efficiency parameters for different devices: ceiling panels, underfloor cooling, fan-assisted radiators, and fan coil. These devices were tested in low and high cooling capacities of up to 40 W/m2 while also featuring heating dummies to imitate internal heat gains. Air temperatures were measured at different heights, allowing to evaluate the thermal stratification with high accuracy. Thermal comfort differences of the tested systems were quantified by measuring both air velocities and operative temperatures at points of occupancy. In summary, the best-performing cooling devices for the studied cooling applications were the ceiling panels and fan radiators, followed by underfloor cooling, with a limitation of stratification. Because of the strong jet, fan coil units did not achieve thermal comfort within the whole occupied zone. The results can be utilized in future studies for cooling emission efficiency and energy consumption analyses of the different cooling devices.

The renewable biomass material obtained from rice husk, a low-cost agricultural waste, was used as a precursor to synthesize a highly porous graphene-based carbon as electrode material for supercapacitors. Activated graphene-based carbon (AGC) was obtained by a two-step chemical procedure and exhibited a very high specific surface area (SSA) of 3292 m2 g−1. The surface morphology of the synthesized materials was studied using scanning and transmission electron microscopy (SEM, TEM). Furthermore, the AGC was modified with nickel hydroxide Ni(OH)2 through a simple chemical precipitation method. It was found that the most significant increase in capacitance could be reached with Ni(OH)2 loadings of around 9 wt.%. The measured specific capacitance of the pure AGC supercapacitor electrodes was 236 F g−1, whereas electrodes from the material modified with 9 wt.% Ni(OH)2 showed a specific capacitance of up to 300 F g−1 at a current density of 50 mA g−1. The increase in specific capacitance achieved due to chemical modification was, therefore 27%.