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Microalgae have tremendous potential for producing liquid renewable fuel. Many methods for converting microalgae to biofuel have been proposed; however, an economical and energetically feasible route for algal fuel production is yet to be found. This paper presents a review on the comparison of the most promising conversion pathways of microalgae to liquid fuel: hydrothermal liquefaction (HTL), wet extraction and non-destructive extraction. The comparison is based on important assessment parameters of product quality and yield, nutrient recovery, GHG emissions, energy and the cost associated with the production of fuel from microalgae, in order to better understand the pros and cons of each method. It was found that the HTL pathway produces more oil than the wet extraction pathway; however, higher concentrations of unwanted components are present in the HTL oil produced. Less nutrients (N and P) can be recovered in HTL compared to wet extraction. HTL consumes more fossil energy and generates higher GHG emissions than wet extraction, while the production cost of fuel from HTL pathway is lower than wet extraction pathway. There is considerable uncertainty in the comparison of the energy consumption and economics of the HTL pathway and the wet extraction pathway due to different scenarios analysed in the assessment studies. To be able to appropriately compare methodologies, the conversion methods should be analysed from growth to upgradation of oil utilising sufficiently similar assumptions and scenarios. Based on the data in available literature, wet oil extraction is the more appropriate system for biofuel production than HTL. However, the potential of alternative extraction/conversion technologies, such as, non-destructive extraction, need to be further assessed.

Abstract An outlook into the country profile at the existing electricity generation with crude oil production at the present level with accompanying gas flares cause CO 2 emission as well as the industrial, human activities and the grid electricity distribution has been accounted for. The estimation of solar radiation levels as well as its productivity in terms of photovoltaics (PV׳s), concentrated solar powers (CSP) and chimney towers have been paid for others renewable energies; wind, tidal and geothermal productivity. A selection of possible site for installation according to the given geographical hazard and the maximum solar radiation could be collected. An overview for futuristic demands and possible solar energy supply that could be generated has reviewed. Furthermore, the desalination of underground or polluted water to support the solar system as well as the needed plantation to preserve a clean and green environment and low dust climate is presented.

Abstract The combination of biomass gasification with fuel cells, especially high temperature Solid Oxide Fuel Cells (SOFCs) promises sustainable and highly efficient (decentralized and modular) energy conversion systems. This review encompasses the components of biomass integrated gasification–SOFC technology including biomass characteristics, the thermochemical conversion in gasifiers and the factors affecting the gasification process, the cleaning technologies for raw producer gas and its conditioning and finally the integration of gasifier with SOFCs. The influence of impurities present in biomass producer gas such as particulates, tar, H 2 S, HCl and alkali compounds based on recent experimental studies and their tolerance limits towards SOFCs are presented. Even though analysis based on the probable tolerance limits of impurities towards SOFCs and a comprehensive overview of the cleaning technologies for producer gas impurities indicate that producer gas cleaning at various temperatures using current technologies to meet SOFC requirements is possible, more experimental studies are still needed to acquire the detailed information on the tolerance limits of impurities for SOFCs. The recent theoretical modeling and experimental studies of biomass integrated gasification–SOFC systems are also presented.

It is now recognized that analytical chemistry must also be a target for green principles, in particular chromatographic methods which typically use relatively large volumes of hazardous organic solvents. More generally, high performance liquid chromatography (HPLC) is employed routinely for quality control of complex mixtures in various industries. Acetonitrile and methanol are the most commonly used organic solvents in HPLC, but they generate an impact on the environment and can have a negative effect on the health of analysts. Ethanol offers an exciting alternative as a less toxic, biodegradable solvent for HPLC. In this work we demonstrate that replacement of acetonitrile with ethanol as the organic modifier for HPLC can be achieved without significantly compromising analytical performance. This general approach is demonstrated through the specific example analysis of a complex plant extract. A benchmark method employing acetonitrile for the analysis of Bidens pilosa extract was statistically optimized using the Green Chromatographic Fingerprinting Response (GCFR) which includes factors relating to separation performance and environmental parameters. Methods employing ethanol at 30 and 80°C were developed and compared with the reference method regarding their performance of separation (GCFR) as well as by a new metric, Comprehensive Metric to Compare Liquid Chromatography Methods (CM). The fingerprint with ethanol at 80°C was similar to or better than that with MeCN according to GCFR and CM. This demonstrates that temperature may be used to replace harmful solvents with greener ones in HPLC, including for solvents with significantly different physiochemical properties and without loss in separation performance. This work offers a general approach for the chromatographic analysis of complex samples without compromising green analytical chemistry principles.

Abstract Many countries produced biodiesel from crude vegetable oil. However, current vegetable oil feedstock to produce biodiesel slow the growth of biodiesel blend implementation due to the high cost of feedstock production. As a result, waste cooking oil (WCO) is claimed to be economic and readily available without cultivation and highly potential feedstock for high yield biodiesel. In this study, Fe-exchanged montmorillonite K10 (Fe-MMT K10) was employed as a catalyst in converting WCO to biodiesel. In comparison, Fe-MMT K10 was able to produce 95.26% biodiesel, which is higher than biodiesel produced using unmodified MMT K10 as catalyst and reaction without catalyst (38.39% and 29.50%, respectively). The full process of biodiesel production was carried out by response surface methodology (RSM) in conjunction with the central composite design (CCD) for statistically optimization and modelling. From the ANOVA, it was found that the production of biodiesel achieved an optimum level of 92.74% biodiesel at 134.07 °C, under a specific optimized condition of 6.32 h reaction time, 4.68 wt% of catalyst and 11.77:1 methanol to oil ratio.

Abstract There are instances in remote areas where heat is being wasted, e.g., in internal combustion, engines, etc. Some of this heat can be recovered to produce distilled water in solar stills. The solar still replaces the cooling tower, ponds, or radiators normally used to control the engine temperature. The diesel cooling water in such a system remains separate from the saline water in the solar still. The advantages of using such a system compared with a conventional solar still are: 1. (a) water costs are very much reduced 2. (b) the area occupied is much less, i.e., about 1 5 th 3. (c) production has much less seasonal variation 4. (d) the efficiency of the solar still is improved due to the higher operating temperatures. From experiments conducted at Highett using a Mk VI solar still fitted with a simple heat exchanger and a separate electrically-heated source of hot water to simulate the waste heat, design data are not available for application to working systems. The information required to match a solar still to a diesel's cooling requirement is: 1. (a) engine efficiency 2. (b) hourly fuel consumption 3. (c) hourly solar radiation 4. (d) hourly ambient temperatures. A by-product of this work has been the production of a “solar water heater” which costs less than that of the cheapest conventional system. This “solar” hot water system uses a heat exchanger similar to what is used to transfer the waste heat to the saline water. It is envisaged to have hot water productions approximately the same as the distilled water productions. The influence of hot water production on the output of the waste heat solar still is discussed.

Abstract Catalytic ethanol steam reforming (ESR) offers a sustainable and attractive route for hydrogen production, which can be utilized as a substitute for fossil fuels. ESR for hydrogen production involves complex reactions and yield of hydrogen depends upon several process variables such as temperature, molar feed ratio and pressure. In this study, a thermodynamics analysis coupled with experimentation for ESR toward hydrogen production has been investigated. The structured montmorillonite (MMT) nanoclay and TiO2 supported catalyst incorporated by nickel (Ni) was developed via a sol-gel and impregnation methods. The catalyst samples were characterized by XRD, FE-SEM, EDX, BET and TGA to understand crystallinity, surface morphology, pore structure and stability. Initially, thermodynamic analysis was employed to study the effect of reaction conditions on equilibrium product distribution of ESR. The equilibrium concentrations of different compounds were calculated by the method of direct minimization of the Gibbs free energy. Optimum conditions for ESR were found to be; atmospheric pressure, temperatures between 600 and 700 °C and steam to ethanol (S/E) feed molar ratio of 10:1, at which highest hydrogen can be produced with minimum coke formation. Next, catalytic performance of NiO/MMT-TiO2 catalyst for enhanced ESR for hydrogen production was conducted in a tubular fixed bed reactor at 500 °C and atmospheric pressure. Noticeably, Ni-promoted TiO2 NPs found efficient for selective hydrogen production, yet MMT-supported Ni/TiO2 gave much higher ethanol conversion with improved hydrogen yield. Using 12% Ni-10% MMT/TiO2 catalyst, ethanol conversion of 89% with H2 selectivity and yield of 61 and 55%, respectively were obtained. The stability test revealed MMT-supported catalysts maintained activity even after 20 h. By comparing results, it was possible to explain deviations between thermodynamic analysis and experimental results regarding carbon deposition and selective hydrogen production.

Electricity generation systems have traditionally been evaluated using only a limited number of economic or environmental indicators, for example capital investment, generation cost or carbon dioxide emissions. Moreover, the evaluations have generally been restricted to performance within the geographic boundary of the power station. This paper reports a sustainability assessment of power generation from Australian fossil fuels, notably black coal, brown coal and natural gas. A range of key sustainability indicators incorporating environmental, economic and social performance are included. The system boundary incorporates fuel extraction, fuel transport to the power station, generation of power, and transmission of electricity to the point of use. Most commonly employed existing technologies and some promising advanced technologies for power generation are considered. The cases of exporting Australian LNG and black coal to Japan for power generation in that country have also been considered. No one fuel or technology system was superior or inferior for every indicator. However the following generalizations can be made: Natural gas combined cycle systems have advantages for the majority of environmental and economic indicators, brown coal has an advantage in terms of value added, and black coal has relatively poor safety performance.