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AbstractMononuclear trivalent lanthanide complexes with formula [Ln(L)(NO3)3] [in which L=4,4‐difluoro‐8‐(2′:2′′;6′′:2′′′‐terpyridin‐4′′‐yl)‐1,3,5,7‐tetramethyl‐2,6‐diethyl‐4‐bora‐3a,4a‐diaza‐s‐indacene (Boditerpy)] are reported for Ln=Yb, Nd, Er, La and Gd. According to the crystal structure of the Yb complex, the lanthanide ion is bound to the terdentate terpyridine and the inner coordination sphere of the nine‐coordinate lanthanide ion is completed by three bidentate nitrate anions. The coordination polyhedron can be described as a distorted tricapped antiprism. The terpyridine chelate is almost planar and tilted by nearly 60° from the indacene subunit. FT‐IR spectra confirm the bidentate binding mode of the nitrate anions for the other complexes. NMR and ES‐MS spectra (through characteristic isotopic patterns) confirm the chemical formulation. The complexes have high molar absorption coefficients in the visible spectral region (65 000 M−1 cm−1 at 529 nm) and display sizeable NIR luminescence (900 to 1600 nm, for Ln=Yb, Nd and Er), upon irradiation through the electronic state of the indacene moiety at 514 nm. Crystal‐field splitting was analysed at low temperature. The quantum yield of the Yb solution (10−4 M) in dichloromethane amounts to 0.31 %, corresponding to a sensitisation efficacy of the ligand of ca. 63 %.

Abstract Sugarcane is a major crop cultivated globally and the residue left over after the crop harvest and extraction of juice is a good biomass source that can be used for the production of several useful chemicals. The sugarcane bagasse is an excellent substrate for the production of various biochemicals and enzymes through fermentation. Now major interest is focused on the utilization of these residue for biofuel production. The sugarcane crop residue is rich in cellulose and hemicellulose, hence it can be used for the production of bioethanol and other liquid transportation fuels. The present review gives a detailed account of the availability of sugarcane residue and various commercially important products that can be produced from this residue. It also provides recent developments in R&D on the bioconversion of sugarcane crop residue for value added products.

Silicon heterojunction solar cells use crystalline silicon (c-Si) wafers as optical absorbers and employ bilayers of doped/intrinsic hydrogenated amorphous silicon (a-Si:H) to form passivating contacts. Recently, we demonstrated that such solar cells increase their operating voltages and thus their conversion efficiencies during light exposure. We found that this performance increase is due to improved passivation of the a-Si:H/c-Si interface and is induced by injected charge carriers (either by light soaking or forward-voltage biasing of the device). Here, we discuss this counterintuitive behavior and establish that: (i) the performance increase is observed in solar cells as well as modules; (ii) this phenomenon requires the presence of doped a-Si:H films, but is independent from whether light is incident from the a-Si:H(p) or the a-Si:H(n) side; (iii) UV and blue photons do not play a role in this effect; (iv) the performance increase can be observed under illumination intensities as low as 20 W m(-1) (0.02-sun) and appears to be almost identical in strength when under 1-sun (1000 W m(-1)); (v) the underlying physical mechanism likely differs from annealing-induced surface passivation.

Dietary change presents an opportunity to meet the dual challenges of non-communicable diseases and the effects of climate change in China. Based on a food survey and reviewed data sets, we linked nutrient composition and carbon footprint data by aggregating 1950 types of foods into 28 groups. Nine dietary scenarios for both men and women were modeled based on the current diet and latest National Program for Food and Nutrition. Linear uncertainty optimization was used to produce diets meeting the Chinese Dietary Reference Intakes for adults aged 18-50years while minimizing carbon footprints. The theoretical optimal diet reduced daily footprints by 46%, but this diet was unrealistic due to limited food diversity. Constrained by acceptability, the optimal diet reduced the daily carbon footprints by 7-28%, from 3495 to 2517-3252g CO2e, for men and by 5-26%, from 3075 to 2280-2917g CO2e, for women. Dietary changes for adults are capable of benefiting China in terms of the considerable footprint reduction of 53-222Mt.CO2eyear-1, when magnified based on the Chinese population, which is the largest worldwide. Seven of eight scenarios showed that reductions in meat consumption resulted in greater reductions in greenhouse gas emissions. However, dramatic reductions in meat consumption may produce smaller reductions in emissions, as the consumption of other ingredients increases to compensate for the nutrients in meat. A trade-off between poultry and other meats (beef, pork, and lamb) is usually observed, and rice, which is a popular food in China, was the largest contributor to carbon footprint reductions. Our findings suggest that changing diets for climate change mitigation and human health is possible in China, though the per capital mitigation potential is slight lower than that in developed economies of France, Spain, Sweden, and New Zealand.

Information about decadal to millennial variability of El Nino Southern Oscillation (ENSO) is fundamental for the assessment of ENSO responses to natural and anthropogenic forcings. Despite a growing number of ENSO reconstructions, the overall picture of Holocene ENSO variability is inconsistent. Here, we revisit the iconic Holocene ENSO sediment record of Lake Pallcacocha, Ecuador (Rodbell et al., 1999). We asked: (i) How coherent are the records of clastic layers (flood layers) in the sediments of Lake Pallcacocha and adjacent Lake Fondococha? (ii) What are the synoptic-scale atmospheric conditions that lead to intense precipitation and, potentially, to alluvial activity promoting the deposition of clastic layers in these lakes? (iii) Is intense precipitation in this area associated with El Nino, or not? We analyzed clastic layers in Late-Holocene sediments from multiple cores in Lakes Pallcacocha and Fondococha from Cajas National Park, southern Ecuadorian Andes. Additionally, we investigated precipitation data from 13 nearby meteorological stations to test if intense precipitation (percentiles P0.95, P0.99, P0.995) is predominantly related to El Nino conditions or not (based on 15 different ENSO indices). Our results show that the absolute flood frequencies (clastic layers per 100 years) differ substantially from lake to lake. This indicates that the frequency of clastic layers reflects different sensitivities (thresholds of precipitation) of the catchments to alluvial activity. 210Pb ages suggest that neither the 1982/83 nor the 1997/98 very strong El Ninos produced clastic layers comparable to those found in the late Holocene. Daily precipitation records from meteorological stations close to Lake Pallcacocha including a high-altitude station from the western slope of the Andes did not show unusually high precipitation during the super El Nino 2015/16. We further find that intense precipitation in this area occurs at roughly equal probability under El Nino, La Nina and neutral conditions. Although the spectral properties of the late Holocene clastic layers in Lake Pallcacocha fall into the typical ENSO frequency band, we do not find evidence in the recent sediments and the meteorological data that would support a diagnostic link between alluvial activity in Lake Pallcacocha and strong El Nino events. Our data do not support the idea that the (late) Holocene flood record of Lake Pallcacocha is a conclusive paleo-El Nino record

AbstractCurrent anthropogenic environmental change causes rapid loss of biodiversity. Although the effects of the main causes of this loss (habitat fragmentation, climate change, and invasive species) on single species have been widely studied, the effects on species interactions are poorly understood. In particular, we do not yet understand how these phenomena affect the evolutionary processes that impact species interactions. Coevolution is a dominant process that organizes the web of life: most species are involved in at least one coevolved interaction. Due to rapid human modification of landscapes it is important to understand how subsequent changes in biotic and abiotic environment and in the level and distribution of genetic variation, as well as changes in population structures, influence the elements of the coevolutionary process. In this review, we synthesize recent development of theoretical work on the coevolution of interacting species with conservation genetics and the impact of anthropogenic environmental changes on single species to address the potential effects of habitat fragmentation, climate change, and invasive species on plant‐herbivore coevolution.

Photocatalysis by titanium dioxide (TiO2), operational in the UV-A domain with a potential use of solar radiation, could be an alternative to conventional water detoxification and disinfection technologies. However, employing the photocatalyst as a suspension or slurry makes the scaling-up of the process difficult, as the TiO2 has to be removed from the decontaminated water to be reused several times. In this work the photocatalytic activity of different types of TiO2 catalyst (Degussa P-25, Millennium PC-100 and PC-500, Tayca AMT-100 and AMT-600) in suspension or coated on fibrous web were studied in both decontamination and disinfection experiments at laboratory scale. Gallic acid was chosen as the model pollutant for detoxification experiments and Escherichia coli as the model microorganism for disinfection experiments. The influence of the surface area and other characteristics of TiO2 are discussed concerning the photocatalytic properties of TiO2. The role of adsorption is suggested, indicating that the reaction occurs at the TiO2 surface and not in the solution. Gallic acid degradation kinetics were found to be of the same extent for both TiO2 suspended and fixed, whereas for the bacterial inactivation efficiency was significantly less important with coated than with suspended TiO2.