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In cold regions, the occurrence of frozen ground has a fundamental control over the character of the water cycle. To investigate the impact of changing ground temperature conditions on hydrological processes in the context of climate change, a distributed hydrological model with an explicit frozen ground module was applied to an alpine watershed in the upstream area of the Hei'he River in the Qilian Mountains, northwest China. After evaluating the base model, we considered scenarios of frost-free ground and climate change. Results showed that the base model with a frozen ground module successfully captured the water balance and thermal regimes in the basin. When the frozen ground module was turned off, the simulated groundwater recharge and base flow increased by a factor of two to three because surface runoff caused by exceeding infiltration capacities at high elevations, which occurred in the base model, was eliminated. Consequently, the river hydrograph became smoother and flatter, with summer flood peaks delayed and reduced in volume. The annual mean depth where subsurface runoff was generated, was about 2.4m compared to 1.1m in the base model. For a warming climate, a combination of increasing evapotranspiration and reducing permafrost area results in smoother and flatter hydrographs, and a reduction in total river discharge. Although our analysis using numerical models has its limitations, it still provides new quantitative understanding of the influences of frozen ground and climate change on hydrological processes in an alpine watershed.

One-stage autotrophic nitrogen (N) removal, requiring the simultaneous activity of aerobic and anaerobic ammonium oxidizing bacteria (AOB and AnAOB), can be obtained in spatially redox-stratified biofilms. However, previous experience with Membrane-Aerated Biofilm Reactors (MABRs) has revealed a difficulty in reducing the abundance and activity of nitrite oxidizing bacteria (NOB), which drastically lowers process efficiency. Here we show how sequential aeration is an effective strategy to attain autotrophic N removal in MABRs: Two separate MABRs, which displayed limited or no N removal under continuous aeration, could remove more than 5.5 g N/m(2)/day (at loads up to 8 g N/m(2)/day) by controlled variation of sequential aeration regimes. Daily averaged ratios of the surficial loads of O(2) (oxygen) to NH(4)(+) (ammonium) (L(O(2))/L(NH(4))) were close to 1.73 at this optimum. Real-time quantitative PCR based on 16S rRNA gene confirmed that sequential aeration, even at elevated average O(2) loads, stimulated the abundance of AnAOB and AOB and prevented the increase in NOB. Nitrous oxide (N(2)O) emissions were 100-fold lower compared to other anaerobic ammonium oxidation (Anammox)-nitritation systems. Hence, by applying periodic aeration to MABRs, one-stage autotrophic N removal biofilm reactors can be easily obtained, displaying very competitive removal rates, and negligible N(2)O emissions.

Eutrophication of lakes leading to loss of submersed macrophytes and higher turbidity is a worldwide phenomenon, attributed to excessive loading of phosphorus (P). However, recently, the role of nitrogen (N) for macrophyte recession has received increasing attention. Due to the close relationship between N and P loading, disentanglement of the specific effects of these two nutrients is often difficult, and some controversy still exists as to the effects of N. We studied the effects of N on submersed macrophytes represented by Vallisneria natans (Lour.) Hara in pots positioned at three depths (0.4 m, 0.8 m, and 1.2 m to form a gradient of underwater light conditions) in 10 large ponds having moderate concentrations of P (TP 0.03 ± 0.04 mg L(-1)) and five targeted concentrations of total nitrogen (TN) (0.5, 2, 10, 20, and 100 mg L(-1)), there were two ponds for each treatment. To study the potential shading effects of other primary producers, we also measured the biomass of phytoplankton (ChlaPhyt) and periphyton (ChlaPeri) expressed as chlorophyll a. We found that leaf length, leaf mass, and root length of macrophytes declined with increasing concentrations of TN and ammonium, while shoot number and root mass did not. All the measured growth indices of macrophytes declined significantly with ChlaPhyt, while none were significantly related to ChlaPeri. Neither ChlaPhyt nor ChlaPeri were, however, significantly negatively related to the various N concentrations. Our results indicate that shading by phytoplankton unrelated to the variation in N loading and perhaps toxic stress exerted by high nitrogen were responsible for the decline in macrophyte growth.

In industrialized countries, large amounts of mineral wastes are produced. They are re-used in various ways, particularly in road and earth constructions, substituting primary resources such as gravel. However, they may also contain pollutants, such as heavy metals, which may be leached to the groundwater. The toxic impacts of these emissions are so far often neglected within Life Cycle Assessments (LCA) of products or waste treatment services and thus, potentially large environmental impacts are currently missed. This study aims at closing this gap by assessing the ecotoxic impacts of heavy metal leaching from industrial mineral wastes in road and earth constructions. The flows of metals such as Sb, As, Pb, Cd, Cr, Cu, Mo, Ni, V and Zn originating from three typical constructions to the environment are quantified, their fate in the environment is assessed and potential ecotoxic effects evaluated. For our reference country, Germany, the industrial wastes that are applied as Granular Secondary Construction Material (GSCM) carry more than 45,000 t of diverse heavy metals per year. Depending on the material quality and construction type applied, up to 150 t of heavy metals may leach to the environment within the first 100 years after construction. Heavy metal retardation in subsoil can potentially reduce the fate to groundwater by up to 100%. One major challenge of integrating leaching from constructions into macro-scale LCA frameworks is the high variability in micro-scale technical and geographical factors, such as material qualities, construction types and soil types. In our work, we consider a broad range of parameter values in the modeling of leaching and fate. This allows distinguishing between the impacts of various road constructions, as well as sites with different soil properties. The findings of this study promote the quantitative consideration of environmental impacts of long-term leaching in Life Cycle Assessment, complementing site-specific risk assessment, for the design of waste management strategies, particularly in the construction sector.

The paper explores, by means of CFD simulations, the potential of the Miller cycle, applied to High Speed Direct Injection (HSDI) Diesel engines, facing the challenge of emissions reduction enforced by the nearterm regulations, with particular reference to Euro VI. In fact, a valuable benefit of the Miller technique is the strong reduction of combustion temperature, thus the abating of NOx emissions, compared to a traditional cycle with the same values of AFR and EGR rate. The practical application of the Miller cycle yields a number of critical issues, which are generally addressed in the paper. However, the goal of the study is to assess the potential and the limits of this technique, more than develop a specific engine configuration. For the analysis, a 2.8 L 4-cylinder turbocharged engine produced by VM Motori was selected, carrying out a comprehensive experimental campaign, at both full and partial load. The experimental data allowed the authors to calibrate two types of numerical models, one for the whole engine analyses (0/1D), the other for the combustion process simulation (CFD-3D). The integrated use of these computational tools provides a reliable comparison between the base engine and the one modified according to the Miller cycle, in terms of both emissions and fuel consumption in the European Driving Cycle. It was found a reduction of NOx and Soot of 25% and 60%, respectively, and a worsening of fuel efficiency of 2%. The abating of NOx can be further enhanced, since it is demonstrated that the engine operated according to the Miller cycle can tolerate higher rates of EGR. (C) 2013 Elsevier Ltd. All rights reserved.

Multi-layer microgrids cluster (MLMC) has been formed in some certain areas with microgrids (MGs) merging into smart distributed system. It relies on an energy management system (EMS) to manage and schedule the optimal power flow among MGs and public power system in a stable and balanced way. Compared with EMS for single MG, energy management optimization for MLMC is much more complex that the interactions with other MGs require to be considered. In this paper a multi-time-scales EMS is proposed to minimize the total operating cost of MLMC. It consists of two parts: day-ahead static scheduling and real-time dynamic compensation. The day-ahead scheduling is an economic optimization based on the forecasting data within 24 hours. The real-time dynamic compensation is presented to compensate scheduling signal based on the real-time operating information, which is caused by the predictive error. Furthermore, charge-discharge protections of energy storage system (ESS) for each single MG are taken into account. A general-structure MLMG is studied as an example, and this problem is solved by mixed integer linear programming (MILP). The effectiveness of proposed EMS is verified in the MG Research Laboratory in Aalborg University, Denmark. The hardware-in-loop simulation results show the proposed EMS has a good convergence and performance in grid-connected mode.

| openaire: EC/H2020/856602/EU//FINEST TWINS Funding Information: This work has been supported by the European Commission through the H2020 project Finest Twins grant No. 856602; and by the Estonian Ministry of Education and Research and European Regional Fund grant 2014-2020.4.01.20-0289. Additional support was acquired from the Estonian Research Council grant PSG739. Publisher Copyright: © 2023 Increasing use of volatile renewable energy sources causes challenges in balancing supply and demand. Therefore, demand-side flexibility has rising importance for system operators and balancing authorities. Flexibility management methods are needed to integrate loads like ventilation systems of different buildings (e.g., residential and commercial) into flexibility service. However, the available methods described in research papers require further development for implementation in practice. Heating and cooling systems have received much attention from researchers, but the potential of ventilation systems has been left out of focus. Therefore, this paper provides a complete set of novel flexibility management methods for ventilation systems created from an aggregator's viewpoint. The flexibility is quantified through capacity (e.i. the amount of power consumption that can be altered), forced ventilation rate duration, and the tendered price for the service. The proposed methods were tested on a building model constructed and simulated in IDA ICE. The data processing and flexibility management methods were applied in MATLAB. Two types of ventilation systems with different sensor configurations were considered: constant and variable air volume. Forced ventilation rate duration is calculated using energy and mass balance analysis where the root means squared error was 10 to 33 min, depending on the system type, measured parameter, and sensor location. The flexibility service pricing model was tested on the 2022 years' manual frequency restoration reserve (mFRR) activation and balance energy market data. Peer reviewed

Abstract Thermal cross-linking in presence of residual solvent dimethylsulfoxide without any addition of cross-linker molecules is described. This elegant method increases spectacularly the mechanical and hydrolytic stability of sulfonated aromatic polymers (SAP), making them suitable for use in liquid water also at 145 °C. Data on water uptake, mechanical properties and proton conductivity are presented and discussed from a bond energy point of view. The developed method is also inexpensive, being incorporated in the normal membrane casting procedure. This opens new horizons and hitherto conventionally disregarded SAP membranes should be reconsidered as fuel cell membranes.