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Abstract. The impact of multiphase reactions involving nitrogen dioxide (NO2) and aromatic compounds was simulated in this study. A mechanism (CAPRAM 2.4, MODAC Mechanism) was applied for the aqueous phase reactions, whereas RACM was applied for the gas phase chemistry. Liquid droplets were considered as monodispersed with a mean radius of 0.1 µm and a liquid content (LC) of 50 µg m-3. The multiphase mechanism has been further extended to the chemistry of aromatics, i.e. reactions involving benzene, toluene, xylene, phenol and cresol have been added. In addition, reaction of NO2 with dissociated hydroxyl substituted aromatic compounds has also been implemented. These reactions proceed through charge exchange leading to nitrite ions and therefore to nitrous acid formation. The strength of this source was explored under urban polluted conditions. It was shown that it may increase gas phase HONO levels under some conditions and that the extent of this effect is strongly pH dependent. Especially under moderate acidic conditions (i.e. pH above 4) this source may represent more than 75% of the total HONO/NO2 - production rate, but this contribution drops down close to zero in acidic droplets (as those often encountered in urban environments).

The variability of large scale wind power generation at high penetration levels has a significant impact on the secure and economic operation of onshore power systems. Grid bottlenecks, high gradients and wasting of wind energy can be avoided using local Energy Storage Systems (ESS) with dedicated power and capacity. The storage type considered in this study is an adiabatic compressed air energy storage (ACAES). This paper presents a comparison of different ESS applications aiming both to increase the profit of the power plant operator in selling the electricity into the electricity market and to support the intermittent electricity production of the wind park. This contribution presents the investigation methodology and discusses computation results for a region in Germany.

Nowadays in current cities the increasing levels of pollution emissions and fuel consumption derived from the road traffic directly affect to the air quality, the economy, and specially the health of citizens. Therefore, improving the traffic flow is a mandatory task in order to mitigate such critical problems. In this work, we propose a Swarm Intelligence approach for optimizing signal light timing programs in metropolitan areas. In this way, we can improve the traffic flow of vehicles with the global target of reducing their fuel consumption and gas emissions (CO and NOx). In this article we optimize the timing programs of signal lights and analyze their effect in pollution by following the standard HBEFA as traffic emission model. In concrete, we are focused here on two large and heterogeneous urban instances located in the cities of Malaga and Seville (in Spain). In comparison with timing programs of signal lights predefined by experts (close to real ones), our proposal obtains significant reductions in terms of the emission rate and the total fuel consumption. Junta de Andalucía P07-TIC-03044 Ministerio de Ciencia e Innovación TIN2011-28194 Ministerio de Ciencia e Innovación TIN2008-06491-C04-01 Ministerio de Ciencia, Innovación y Universidades BES-2009-018767

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

Abstract Electrolytic pickling of hot-rolled 304 stainless steel in Na 2 SO 4 electrolyte was investigated with electrochemical, weight loss and SEM–EDX measurements. Pickling took place upon both active and transpassive polarisations. Mechanism and kinetics of pickling during active and transpassive polarisations were unravelled. Metallic phase in oxide layer was dissolved during active polarisation while the oxide layer was significantly undercut. Chromium oxide in the oxide layer was oxidised to soluble anions during transpassive polarisation, while iron oxide and metallic phase could either be remained or removed. Pickling due to undercutting with active polarisation was highly pronounced.

This paper presents a wind resource assessment in Venezuela using an efficient combination of spatial interpolation and orographic correction for wind mapping. Mesoscale modelling offers a relatively accurate means to model meteorological conditions by solving the continuity and momentum equations. However, this approach is both time and computationally demanding. The methodology used in this work offers a computationally inexpensive solution by combining both a simple geo-statistical Kriging method to interpolate horizontal wind speed and an orographic correction to account for changes on terrain elevation. Hourly observations of wind speed and direction for 34 masts recorded during the period 2005–2009 have been analysed in order to define a statistical model of wind resources. The resulting method, which includes an exploratory statistical analysis of the wind data, is a computationally economical alternative to mesoscale modelling. Simulations results include equivalent mean wind speeds and wind power maps which have been created to a height of 50, 80 and 120 m above the ground based on a horizontal resolution of 15×15 km. Results show that the greatest wind energy resources are located in the coastal area of Venezuela with a potential for offshore applications. Preliminary findings provide a very positive evidence for offshore exploitation of wind power. Results also suggest that wind energy resources for commercial use (utility-scale) are available in northern Venezuela, additionally; they suggest excellent conditions for wind power production for micro-scale applications, both on- and off-grid.

Environmental problems that seriously affect both natural systems and social development of human beings have drawn extensive attention from governing authorities all around the world, and become an urgent issue to be addressed. Ports play a significant role in the international shipping which inevitably influence the global environment. Thus, the concept of green port is developed to mitigate the negative impacts of inappropriate port operations on environment. This paper analyzes the current status of green port development worldwide. An evaluation model for quantitative measurement of green port development is established based on the Drivers, Pressures, States, Impacts and Responses (DPSIR) framework. The weight of each index composing the evaluation model is calculated through an analytical hierarchy process method, and the evaluation results of the investigated ports with respect to each index are aggregated using an evidential reasoning approach. The evaluation model is further demonstrated through a comparative analysis of five major ports in China. The novel model developed along with the methods applied in this paper can provide significant insights for the comparative evaluation on the development of green ports in other countries and/or regions, as well as a powerful tool to conduct self-assessment of green port development. © 2017 Elsevier Ltd.