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The combustion of coal is responsible for nearly 40% of the world's electricity production, and char combustion accounts for about half of that amount. Clearly, an understanding of the combustion mechanism of carbon is of great importance not only because of its industrial significance but because it is a model heterogeneous reaction. A number of recent studies have been concerned with ab initio molecular orbital calculations on graphite including model chemistry and the reactions with molecular oxygen. This study is concerned with oxidation steps involving the attachment of oxygen to a graphene layer at high temperature leading to the formation of carbon monoxide, and particular attention is paid to the subsequent oxidation reactions. In addition, the reaction of oxygen with carbon catalyzed by metals inherent within the char matrix and the reaction of molecular oxygen with the analogous biomass char are investigated and their reaction paths are discussed.

The operation of centrifugal pumps can generate instabilities and pressure pulsations that may be detrimental to the integrity and performance of the pump. In the present study a numerical investigation of the time variation of pressure within a complete centrifugal pump was undertaken. A range of parameters and three flow rates were investigated and the pulsations were extracted at 15 different locations covering important pump regions. The transient flow results compared reasonably with experimental data obtained in a limited experimental survey and clearly indicated the pump locations experiencing the largest pulsation levels. It was also noted that monitoring pulsations at the top dead centre of the pump volute casing would provide a better indication of internal pump pulsations than monitoring at the discharge.

Abstract This paper investigates the hydrodynamics of a seabed-mounted, bottom-hinged, flap-type wave energy converter in shallow water. A conceptual model of the hydrodynamics of the device has been formulated and shows that, as the motion of the flap is highly constrained, the magnitude of the wave force on the flap is the key determinant of power capture. The results from a physical modelling program have been used in conjunction with numerical data from WAMIT to validate the conceptual model. The work finds that designing the device to increase the wave force is more profitable than designing it to be tuned to the incident wave climate. As wave force is the primary driver of device performance it is shown that the flap should fill the water column and pierce the water surface to reduce decoupling due to wave overtopping. It is concluded that, in order to maximize capture factor at a typical North Atlantic site, the flap should be approximately 20–30 m wide, with large diameter rounded side edges, having its pivot close to the seabed and its top edge piercing the water surface.

Abstract Stable aqueous TiO2 nanofluids with different particle (agglomerate) sizes and concentrations are formulated and measured for their static thermal conductivity and rheological behaviour. The nanofluids are then measured for their heat transfer and flow behaviour upon flowing upward through a vertical pipe in both the laminar and turbulent flow regimes. Addition of nanoparticles into the base liquid enhances the thermal conduction and the enhancement increases with increasing particle concentration and decreasing particle (agglomerate) size. Rheological measurements show that the shear viscosity of nanofluids decreases first with increasing shear rate (the shear thinning behaviour), and then approaches a constant at a shear rate greater than ∼100 s−1. The constant viscosity increases with increasing particle (agglomerate) size and particle concentration. Given the flow Reynolds number and particle size, the convective heat transfer coefficient increases with nanoparticle concentration in both the laminar and turbulent flow regimes and the effect of particle concentration seems to be more considerable in the turbulent flow regime. Given the particle concentration and flow Reynolds number, the convective heat transfer coefficient does not seem to be sensitive to the average particle size under the conditions of this work. The results also show that the pressure drop of the nanofluid flows is very close to that of the base liquid flows for a given Reynolds number.

Abstract The combined production of electricity, heat and cold by a polygeneration system connected to a district heating and cooling network can provide high energy utilization efficiency. The inherent complexity of simultaneous production of different services and the high variability in the energy demand make combined cooling and heating systems performance highly dependent on the operational strategy. In this paper, an operational optimization method based on the moving average of real-time measurements of energy demands and ambient conditions is proposed. Real energy demand data from a district heating and cooling network close to Barcelona, Spain, are used to test the method. A complex polygeneration system is considered, consisting of an internal combustion engine, a double-effect absorption chiller, an electric chiller, a boiler and a cooling tower. A detailed modelling of the system is provided, considering partial load behavior of the components and ambient conditions effects. Results of the real-time optimal management are discussed and compared to traditional operational strategies and to the ideal optimal management achievable with perfectly accurate forecast of energy demands. Moreover, the optimal width of the window adopted for the moving average of real-time data is identified.

This paper reports on a methodology developed for studying the effects of various types of prosthetic feet on the gait of trans-femoral amputees. It is shown that an analysis in three planes of motion of not only the prosthetic, but also the sound limb provides important information on the performance of prosthetic feet. Two male trans-femoral amputees were tested with four different prosthetic feet; the Springlite II, Carbon Copy III, Seattle LightFoot and the Multiflex foot. A detailed analysis of the results of one amputee and a summary of the most important results of a second subject is presented. The tests were carried out at normal (1.16 m s(-1)) and fast (1.56 m s(-1)) walking speeds. Three dimensional gait analysis was carried out to derive the time curves of the joint angles, intersegmental moments and power at the ankle, knee and hip joints at both the prosthetic and sound sides. A higher first peak of the ground reaction force at the sound side with the Seattle LightFoot compared to that with the Springlite II, may be the result of the lower late stance dorsiflexion angle with the former. Compared to the other two feet, the Carbon Copy III and the Springlite II showed higher prosthetic dorsiflexing moments and positive power at late stance, which could assist in the push-off. The 3D intersegmental loads at the ankle and knee can be used as a guide for design and for compilation of standards for testing of lower limb prostheses incorporating flexible feet.

Abstract Like cities, many large national parks in the United States often include “urban” visitor and residential areas that mostly demand (rather than produce) energy and key urban materials. The U.S. National Park Service has committed to quantifying and reducing scopes 1 and 2 emissions by 35% and scope 3 emissions by 10% by 2020 for all parks. Current inventories however do not provide the specificity or granularity to evaluate solutions that address fundamental inefficiencies in these inventories. By quantifying and comparing the importance of different inventory sectors as well as upstream and downstream emissions in Yosemite National Park (YNP), this carbon footprint provides a case study and potential template for quantifying future emissions reductions, and for evaluating tradeoffs between them. Results indicate that visitor-related emissions comprise the largest fraction of the Yosemite carbon footprint, and that increases in annual visitation (3.43–3.90 million) coincide with and likely drive interannual increases in the magnitude of Yosemite′s extended inventory (126,000–130,000 t CO2e). Given this, it is recommended that “per visitor” efficiency be used as a metric to track progress. In this respect, YNP has annually decreased kilograms of GHG emissions per visitor from 36.58 (2008) to 32.90 (2011). We discuss opportunities for reducing this measure further.

Abstract In this work, Co/Cu nanowires are fabricated by pulsed electrodeposition from a single bath solution containing both Co and Cu ions. Alternate Co and Cu layers are deposited into the nanopores of track etched polycarbonate templates. Although the feasibility of this process is generally recognized, some important issues such as process reproducibility and how structural defects affect the nanowires arrays’ sensing performances are still open; conditions necessary to turn a this made system into a magnetic field sensor. The present work aims at pushing forward knowledge concerning the nanowires fabrication and defining the best growth parameters; in particular, a tight control of the growth process parameters such as single metal deposition potentials and single cycle deposition durations have been carried out for nanowires of 80 nm diameter and correlated to the system magneto-electric response.