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Abstract Planar perovskite solar cells using organic charge selective contacts were fabricated. In a vacuum deposited perovskite-based solar cell, dopant and additive free triazatruxene as the hole transport layer was introduced for device fabrication. High open-circuit voltage of 1090 mV was obtained using methylammonium lead iodide (Eg=1.55 eV) as light harvesting material, thus representing a loss of only 460 mV which is in close vicinity of mature silicon technology (400 mV). The devices showed a very competitive photovoltaic performance, monochromatic incident photon-to-electron conversion efficiency of 80% and the power conversion efficiencies in excess of 15% were measured with a negligible degree of hysteresis.

Abstract Planar perovskite solar cells using organic charge selective contacts were fabricated. In a vacuum deposited perovskite-based solar cell, dopant and additive free triazatruxene as the hole transport layer was introduced for device fabrication. High open-circuit voltage of 1090 mV was obtained using methylammonium lead iodide (Eg=1.55 eV) as light harvesting material, thus representing a loss of only 460 mV which is in close vicinity of mature silicon technology (400 mV). The devices showed a very competitive photovoltaic performance, monochromatic incident photon-to-electron conversion efficiency of 80% and the power conversion efficiencies in excess of 15% were measured with a negligible degree of hysteresis.

Abstract Breakthrough alternative technologies are urgently required to alleviate the critical need to decarbonise our energy supply. We showcase non-conventional approaches to battery and solar energy conversion and storage (ECS) system designs that harness key attributes of immiscible electrolyte solutions, especially the membraneless separation of redox active species and ability to electrify certain liquid–liquid interfaces. We critically evaluate the recent development of membraneless redox flow batteries based on biphasic systems, where one redox couple is confined to an immiscible ionic liquid or organic solvent phase, and the other couple to an aqueous phase. Common to all solar ECS devices are the abilities to harvest light, leading to photo-induced charge carrier separation, and separate the products of the photo-reaction, minimising recombination. We summarise recent progress towards achieving this accepted solar ECS design using immiscible electrolyte solutions in photo-ionic cells, to generate redox fuels, and biphasic “batch” water splitting, to generate solar fuels.

Abstract Breakthrough alternative technologies are urgently required to alleviate the critical need to decarbonise our energy supply. We showcase non-conventional approaches to battery and solar energy conversion and storage (ECS) system designs that harness key attributes of immiscible electrolyte solutions, especially the membraneless separation of redox active species and ability to electrify certain liquid–liquid interfaces. We critically evaluate the recent development of membraneless redox flow batteries based on biphasic systems, where one redox couple is confined to an immiscible ionic liquid or organic solvent phase, and the other couple to an aqueous phase. Common to all solar ECS devices are the abilities to harvest light, leading to photo-induced charge carrier separation, and separate the products of the photo-reaction, minimising recombination. We summarise recent progress towards achieving this accepted solar ECS design using immiscible electrolyte solutions in photo-ionic cells, to generate redox fuels, and biphasic “batch” water splitting, to generate solar fuels.

Organic monogastric agriculture is challenged because of a limited availability of regional and organic protein-rich ingredients to fulfill the amino acid requirements. The development of novel feed ingredients is therefore essential. The use of starfish (Asterias rubens), mussel (Mytilus edilus), insect, green and brown seaweed, and forage crop extracts exhibits different approaches to increase protein availability in a sustainable manner through improving the protein quality of existing ingredients, better use of under- or unutilized material, or development of circular bioeconomy. This review assessed limitations and opportunities of producing, processing, and using these novel ingredients in feed. The use of non-renewable resources and the effect on the environment of production and processing the feed ingredients are described. Protein concentration and amino acid quality of the feed ingredients are evaluated to understand their substitution potential compared with protein-rich soya bean and fishmeal. Feedstuffs’ effect on digestibility and animal performance is summarized. With the exception of seaweed, all novel ingredients show potential to partly substitute fishmeal or soya bean fulfilling part of the protein requirement in organic monogastric production. However, improvements during production and processing can be made to enhance protein quality, sustainability of the novel ingredients, and nutrient utilization of novel feed ingredients.

Organic monogastric agriculture is challenged because of a limited availability of regional and organic protein-rich ingredients to fulfill the amino acid requirements. The development of novel feed ingredients is therefore essential. The use of starfish (Asterias rubens), mussel (Mytilus edilus), insect, green and brown seaweed, and forage crop extracts exhibits different approaches to increase protein availability in a sustainable manner through improving the protein quality of existing ingredients, better use of under- or unutilized material, or development of circular bioeconomy. This review assessed limitations and opportunities of producing, processing, and using these novel ingredients in feed. The use of non-renewable resources and the effect on the environment of production and processing the feed ingredients are described. Protein concentration and amino acid quality of the feed ingredients are evaluated to understand their substitution potential compared with protein-rich soya bean and fishmeal. Feedstuffs’ effect on digestibility and animal performance is summarized. With the exception of seaweed, all novel ingredients show potential to partly substitute fishmeal or soya bean fulfilling part of the protein requirement in organic monogastric production. However, improvements during production and processing can be made to enhance protein quality, sustainability of the novel ingredients, and nutrient utilization of novel feed ingredients.