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Abstract This paper aims to present a feasibility study of the innovative plant for methanol synthesis from carbon dioxide-sequestered by fossil fuel power plant and hydrogen, which is produced by water electrolyzer employing the over-production on the electrical grid. The thermo-economic analysis is performed in the framework of the MefCO2 H2020 EU project and it is referred to the German economic scenario, properly taking into account the real market costs and cost functions for different components of the plant. Three different plant capacities for methanol production (4000 10,000 and 50,000 ton/year) have been investigated, assuming an average cost for electrical energy to feed electrolysers and analyzing the influence of the most significant parameters (oxygen selling option, methanol selling price and electrolysers’ capital cost) on the profitability of the plant. The analysis has been performed in W-ECoMP, software for the thermo-economic analysis and plant optimization developed by the University of Genoa.

It's not only the carbon in the trees Forest loss affects climate not just because of the impacts it has on the carbon cycle, but also because of how it affects the fluxes of energy and water between the land and the atmosphere. Evaluating global impact is complicated because deforestation can produce different results in different climate zones, making it hard to determine large-scale trends rather than more local ones. Alkama and Cescatti conducted a global assessment of the biophysical effects of forest cover change. Forest loss amplifies diurnal temperature variations, increases mean and maximum air temperatures, and causes a significant amount of warming when compared to CO 2 emission from land-use change. Science , this issue p. 600

This paper presents the design of an extended Kalman filter (EKF) as a state-of-charge (SoC) estimator for a lithium–titanate (LTO) battery cell. The design is based on a Thevenin model of the equivalent battery electrical circuit with two parallel resistive-capacitive (RC) elements for the emulation of electrolyte polarization effects. The effectiveness of the proposed SoC estimator is verified through computer simulations on the comprehensive nonlinear battery simulation model featuring battery parameter vs. SoC variations, which is subject to highly dynamic loading regimes.

Abstract Some new structures of thin-film solar converters (SC) based on heterojunctions (HJ) with intermediate semiconductor layers are suggested. Thin protective layers and a quasi-electric field incorporated into the space charge region (SCR) prevent cross-diffusion of HJ components and increase efficiency of charge carrier separation. They also decrease the diode dark current and provide high stability of the converter parameters. Thin (∼ 0.1 μ M) (CdSe) x (ZnTe) 1− x or Zn x Cd 1− x Se layers were used as graded band-gap layers. They were places between a photosensitive II-VI-compound (CdTe, CdSe, CdSe x Te 1− x ) base layer and the transparent Cu 1.8 S layer. The above structures were prepared by vacuum closed space sublimation. The properties of these compounds were studied by electron microscopy and X-ray photoelectron spectroscopy (XPS) with ion etching. The photoelectron properties of structures such as Cu 1.8 S/(CdSe) x )(ZnTe) 1− x /CdSe are presented in detail. The manufacturing technology for the integrated solar batteries based on CdTe, CdSe, and CdSe x Te 1− x compounds was developed. The solar cell parameters under low illumination intensities are comparable to those of solar batteries based on c-Si and a-Si. The competitiveness of the polycrystalline thin-film SC is due to ease and low cost of fabrication (as compared with c-Si and a-Si) and also to the extended photosensitivity range (as compared to a-Si).

The identification of species-rich areas and their prognosticated turnover under climate change are crucial for the conservation of endemic taxa. This study aims to identify areas of reptile endemicity richness in a global biodiversity hot spot (Morocco) under current and future climatic conditions and to investigate the role of protected areas in biodiversity conservation under climate change. Species distribution models (SDM) were performed over the distribution of 21 endemic reptiles, combined to estimate current species richness at 1 × 1 km resolution and projected to years 2050 and 2080 according to distinct story lines and ensemble global circulation models, assuming unlimited and null dispersion ability. Generalized additive models were performed between species richness and geographic characteristics of 43 protected areas. SDM found precipitation as the most important factor related to current species distributions. Important reductions in future suitable areas were predicted for 50 % of species, and four species were identified as highly vulnerable to extinction. Drastic reductions in species-rich areas were predicted for the future, with considerable variability between years and dispersal scenarios. High turnover rates of species composition were predicted for eastern Morocco, whereas low values were forecasted for the Northern Atlantic coast and mountains. Species richness for current and future conditions was significantly related to the altitude and latitude of protected areas. Protected areas located in mountains and/or in the Northern Atlantic coast were identified as refugia, where population monitoring and conservation management is needed.

Abstract Offshore wind energy is a seminal technology to achieve the goals set for renewable energy deployment. However, today's offshore wind energy projects are mostly not yet sufficiently competitive. The optimization of offshore wind turbine substructures with regard to costs and reliability is a promising approach to increase competitiveness. Today, interdisciplinary analyses considering sophisticated engineering models and their complex economic effects are not widespread. Existing approaches are deterministic. This research gap is addressed by combining an aero-elastic wind turbine model with an economic viability model for probabilistic investment analyses. The impact of different monopile designs on the stochastic cost-efficiency of an offshore wind farm is investigated. Monopiles are varied with regard to diameters and wall thicknesses creating designs with increased lifetimes but higher capital expenditures (durable designs) and vice versa (cheaper designs). For each substructure, the aero-elastic wind turbine model yields distributions for the fatigue lifetime and electricity yield and different capital expenditures, which are applied to the economic viability model. For other components, e.g. blades, constant lifetimes and costs are assumed. The results indicate that the gain of increased stochastic lifetimes exceeds the benefit of reduced initial costs, if the overall lifetime is not governed by other turbine components' lifetimes.

Abstract Decarbonizing world economies implies the deployment of “green technologies”, meaning a renovation of the energy sector towards using renewable sources and zero emission transport technologies. This renovation will require huge amounts of raw materials, some of them with high supply risks. To assess such risks a new methodology is proposed, identifying possible bottlenecks of future demand versus geological availability. This has been applied to the world development of wind power, solar photovoltaic, solar thermal power and passenger electric vehicles for the 2016–2050 time period under a business as usual scenario considering the impact on 31 different raw materials. As a result, 13 elements were identified to have very high or high risk, meaning that these could generate bottlenecks in the future: cadmium, chromium, cobalt, copper, gallium, indium, lithium, manganese, nickel, silver, tellurium, tin and zinc. Tellurium, which is mostly demanded to manufacture solar photovoltaic cells, presents the highest risk. To overcome these constraints, measures consisting on improving recycling rates from 0.1% to 4.6% per year could avoid material shortages or restrictions in green technologies. For instance, lithium recycling rate should increase from 1% to 4.8% in 2050. This study aims to serve as a guideline for developing eco-design and recycling strategies.

This paper investigates the impact of plug-in electric vehicle (EV) integration on the power systems scheduling and energy cost. An intermediary entity, the EV aggregator, participates in the market on behalf of the EV owners by optimally self-scheduling under the price-taking approach. Through detailed rolling simulations for a year and different EVs’ penetration scenarios at a large insular power system, this work highlights the different impact of direct and smart charging on power system scheduling and energy costs, the limitations of the price-taking approach, which is widely used in self-scheduling models, and the difference in system value and market value that smart charging adoption creates in restructured markets under the marginal pricing rule.

Abstract The paper presents a model-based approach to supporting battery selection for a fuel cell (FC)-based auxiliary power unit (APU). It is introduced to a case study of electrical power production and consumption management in a truck anti-idling application of a diesel-powered FC-based APU, a system under development in FCGEN, a FCH JU European project of the FP7 program. With fuel cell and related technologies increasingly competing with others in the market, they need to form complete systems with matching and well-balanced components to enable using the technology to its best. Within the whole system, the battery, serving as an energy buffer, represents a medium-cost element, but it affects the operating parameters importantly. Within the scope of this study, a purpose-oriented model of the diesel powered FC-based system is developed together with a realistic load scenario for the comparison of three batteries. The battery size and type are investigated and discussed in the light of the simulation results.