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Abstract Adsorbent-based carbon capture is only feasible if adsorption-desorption cycles are both fully regenerating and efficient. This work proposes a regenerative pH swing process and a pH swing regenerative adsorbent that are inspired by natural CO2 conversion by carbonic anhydrase biocatalysts found in mammalian red blood cells. The main objective is to develop, test and analyze a synthetic pH Swing Adsorption (pHSA) system as well as a pHSA compatible solid adsorbent to capture CO2 from a simulated ambient air gas stream. The lead developed adsorbent is a carbon black co-activated with potassium carbonate and nitrogenous copolymer that is impregnated with immobilized bovine carbonic anhydrase and thereby deemed “BCA/KN-CB”. BCA/KN-CB has preliminarily demonstrated both competitive CO2 adsorption capacity and limited regenerative ability under experimental pHSA conditions. In addition, BCA-based adsorbents achieved higher adsorption capacities than non-BCA adsorbent counterparts. The BCA/KN-CB adsorbent displayed both large point of zero charge (PZC) swings and regenerative stability. The proposed pHSA system requires essentially zero energy expenditure to achieve intended environments for capture and regeneration. With 1 kg of adsorbent, pHSA has the ability to capture 1 kg CO2 in less than 4 h of cycling. The tested pHSA adsorbent can also capture more than 96% of total CO2 in a given raw gas stream flowing through the capture chamber. This proof-of-concept study of a pH swing adsorption/biocatalytic adsorbent system suggests the potential to effectively operate under ambient conditions and exhibit advantageous operational efficiencies to other high-profile CO2 capture systems.

Abstract Adsorbent-based carbon capture is only feasible if adsorption-desorption cycles are both fully regenerating and efficient. This work proposes a regenerative pH swing process and a pH swing regenerative adsorbent that are inspired by natural CO2 conversion by carbonic anhydrase biocatalysts found in mammalian red blood cells. The main objective is to develop, test and analyze a synthetic pH Swing Adsorption (pHSA) system as well as a pHSA compatible solid adsorbent to capture CO2 from a simulated ambient air gas stream. The lead developed adsorbent is a carbon black co-activated with potassium carbonate and nitrogenous copolymer that is impregnated with immobilized bovine carbonic anhydrase and thereby deemed “BCA/KN-CB”. BCA/KN-CB has preliminarily demonstrated both competitive CO2 adsorption capacity and limited regenerative ability under experimental pHSA conditions. In addition, BCA-based adsorbents achieved higher adsorption capacities than non-BCA adsorbent counterparts. The BCA/KN-CB adsorbent displayed both large point of zero charge (PZC) swings and regenerative stability. The proposed pHSA system requires essentially zero energy expenditure to achieve intended environments for capture and regeneration. With 1 kg of adsorbent, pHSA has the ability to capture 1 kg CO2 in less than 4 h of cycling. The tested pHSA adsorbent can also capture more than 96% of total CO2 in a given raw gas stream flowing through the capture chamber. This proof-of-concept study of a pH swing adsorption/biocatalytic adsorbent system suggests the potential to effectively operate under ambient conditions and exhibit advantageous operational efficiencies to other high-profile CO2 capture systems.

Abstract For 118 million residential housing units in the U.S., there is currently a gap between the potential energy savings that can be achieved through the use of existing energy efficiency technologies, and the actual level of energy savings realized, particularly for the 37% of housing units that are considered residential rental properties. Additional quantifiable benefits are needed beyond energy savings to help further motivate residential property owners to invest in energy efficiency upgrades. This research focuses on assessing the adoption of energy efficient upgrades in U.S. residential housing and the impact on rental prices. Ten U.S. cities are chosen for analysis; these cities vary in size across multiple climate zones, and represent a diverse set of housing market conditions. Data was collected for over 159,000 rental property listings, their characteristics, and their energy efficiency measures listed in rental housing postings across each city. Following an extensive data quality control process, over thirty different types energy efficient features were identified. The level of adoption was determined for each city, ranging from 5.3% to 21.6%. Efficient lighting and appliances were among the most common, with many features doubling as energy efficient and other desirable aesthetic or comfort improvements. Then using propensity score matching and conditional mean comparison methods, the relative impact on rent charged in each city was calculated, which ranged from a 6% to 14.1% increase in rent for properties with energy efficient features, demonstrating a positive economic impact of these features, particularly for property owners. This was further subdivided into five types of energy efficiency upgrade and three housing types. Single family homes generally demanded higher premiums with energy efficient features, however there was not a consistent pattern across the types of efficient upgrades. The results of this work demonstrate that investment in energy efficient technologies has quantifiable benefits for rental property owners in the U.S. beyond just energy savings. This methodology and results can also be used in other cities and by property owners, utility companies, or others, ultimately encouraging further investment and positive economic impact in residential energy efficiency and in turn improving energy and resource conservation in the building sector.

Abstract For 118 million residential housing units in the U.S., there is currently a gap between the potential energy savings that can be achieved through the use of existing energy efficiency technologies, and the actual level of energy savings realized, particularly for the 37% of housing units that are considered residential rental properties. Additional quantifiable benefits are needed beyond energy savings to help further motivate residential property owners to invest in energy efficiency upgrades. This research focuses on assessing the adoption of energy efficient upgrades in U.S. residential housing and the impact on rental prices. Ten U.S. cities are chosen for analysis; these cities vary in size across multiple climate zones, and represent a diverse set of housing market conditions. Data was collected for over 159,000 rental property listings, their characteristics, and their energy efficiency measures listed in rental housing postings across each city. Following an extensive data quality control process, over thirty different types energy efficient features were identified. The level of adoption was determined for each city, ranging from 5.3% to 21.6%. Efficient lighting and appliances were among the most common, with many features doubling as energy efficient and other desirable aesthetic or comfort improvements. Then using propensity score matching and conditional mean comparison methods, the relative impact on rent charged in each city was calculated, which ranged from a 6% to 14.1% increase in rent for properties with energy efficient features, demonstrating a positive economic impact of these features, particularly for property owners. This was further subdivided into five types of energy efficiency upgrade and three housing types. Single family homes generally demanded higher premiums with energy efficient features, however there was not a consistent pattern across the types of efficient upgrades. The results of this work demonstrate that investment in energy efficient technologies has quantifiable benefits for rental property owners in the U.S. beyond just energy savings. This methodology and results can also be used in other cities and by property owners, utility companies, or others, ultimately encouraging further investment and positive economic impact in residential energy efficiency and in turn improving energy and resource conservation in the building sector.

Abstract The field of energy harvesting holds the promise of making our buildings “smart” if effective energy sources can be developed for use in ambient indoor conditions. Photovoltaics (PV), especially in its thin flexible form for easy integration, become a prime candidate for the aim, if tailored for low-density artificial light. We designed a test system which enabled us to measure the performance of PV devices under compact fluorescent lamp (CFL) and light-emitting diode (LED) illumination at different illuminance levels and compared polycrystalline and amorphous silicon cells with our own flexible dye solar cells (DSCs). Whereas poly-Si cells, with 15% outdoor efficiency, delivered at 200 lux under CFL only 2.8 μW/cm2 power density (and an efficiency of 4.4%), a-Si specifically designed for indoors, gave 5.9 μW/cm2 and 9.2% efficiency under the same CFL conditions (and 7.5% efficiency under LED). However, we show that the customization of flexible DSCs, by simply formulating ad-hoc less-concentrated, more transparent electrolytes, enabled these devices to outperform all others, providing average power densities of 8.0 μW/cm2 and 12.4% efficiencies under 200 lux CFL (more than quadruple compared to those measured at 1 sun), and 6.6 μW/cm2 and 10% efficiency under 200 lux LED illumination.

Abstract The field of energy harvesting holds the promise of making our buildings “smart” if effective energy sources can be developed for use in ambient indoor conditions. Photovoltaics (PV), especially in its thin flexible form for easy integration, become a prime candidate for the aim, if tailored for low-density artificial light. We designed a test system which enabled us to measure the performance of PV devices under compact fluorescent lamp (CFL) and light-emitting diode (LED) illumination at different illuminance levels and compared polycrystalline and amorphous silicon cells with our own flexible dye solar cells (DSCs). Whereas poly-Si cells, with 15% outdoor efficiency, delivered at 200 lux under CFL only 2.8 μW/cm2 power density (and an efficiency of 4.4%), a-Si specifically designed for indoors, gave 5.9 μW/cm2 and 9.2% efficiency under the same CFL conditions (and 7.5% efficiency under LED). However, we show that the customization of flexible DSCs, by simply formulating ad-hoc less-concentrated, more transparent electrolytes, enabled these devices to outperform all others, providing average power densities of 8.0 μW/cm2 and 12.4% efficiencies under 200 lux CFL (more than quadruple compared to those measured at 1 sun), and 6.6 μW/cm2 and 10% efficiency under 200 lux LED illumination.

Abstract Bioproducts from biomass feedstocks and organic wastes have shown great potential to address challenges across food-energy-water systems. However, bioproducts production is at an early, nascent stage that requires new inventions and cost-reducing approaches to meet market needs. Biochar, a byproduct of the pyrolysis process, derived from nutrient-rich biomass feedstocks (e.g., cattle manure and poultry litter) is one of these bioproducts that has numerous applications, such as improving soil fertility and crop productivity. This study investigates the market opportunity and sustainability benefits of converting manure to biochar on-site, using a portable refinery unit. Techno-economic and environmental impact assessments are conducted on a real case study in Twin Falls, Idaho, USA. The techno-economic analysis includes a stochastic optimization model to calculate the total cost of biochar production and distribution. The environmental study employs a life cycle assessment method to evaluate the global warming potential of manure-to-biochar production and distribution network. The total cost of biochar production from cattle manure near the feedlots is approximately $237 per metric ton, and total emission is 951 kg CO2 eq. per metric ton. The on-site operation and manure moisture content are two key parameters that can reduce biochar unit price and carbon footprint of manure management. It is concluded that converting cattle manure, using the presented strategy and process near the collection sites can address upstream and midstream sustainability challenges and stimulate the biochar industry.

Abstract Bioproducts from biomass feedstocks and organic wastes have shown great potential to address challenges across food-energy-water systems. However, bioproducts production is at an early, nascent stage that requires new inventions and cost-reducing approaches to meet market needs. Biochar, a byproduct of the pyrolysis process, derived from nutrient-rich biomass feedstocks (e.g., cattle manure and poultry litter) is one of these bioproducts that has numerous applications, such as improving soil fertility and crop productivity. This study investigates the market opportunity and sustainability benefits of converting manure to biochar on-site, using a portable refinery unit. Techno-economic and environmental impact assessments are conducted on a real case study in Twin Falls, Idaho, USA. The techno-economic analysis includes a stochastic optimization model to calculate the total cost of biochar production and distribution. The environmental study employs a life cycle assessment method to evaluate the global warming potential of manure-to-biochar production and distribution network. The total cost of biochar production from cattle manure near the feedlots is approximately $237 per metric ton, and total emission is 951 kg CO2 eq. per metric ton. The on-site operation and manure moisture content are two key parameters that can reduce biochar unit price and carbon footprint of manure management. It is concluded that converting cattle manure, using the presented strategy and process near the collection sites can address upstream and midstream sustainability challenges and stimulate the biochar industry.

Abstract Efficient electric heat pumps have the potential to significantly reduce greenhouse gas emissions from heating and cooling buildings. However, heat pumps’ initial costs can be prohibitively high and their lifetime costs are only situationally competitive with incumbent technologies. Here we show that a business model based on heat purchase agreements could lower these barriers to heat pump adoption. In this business model, a user hosts a heat pump owned by an aggregator. The aggregator installs the heat pump at low or no initial cost to the user. The user buys the heat pump’s heat or cooling output from the aggregator. The aggregator buys the heat pump’s input electricity in the wholesale energy market and sells the flexibility of their aggregate electrical load in ancillary service markets. This paper presents the first economic analysis of heat purchase agreements as a third-party ownership model for electric heat pumps. We derive conditions under which a heat purchase agreement is mutually beneficial to the user and the aggregator. We also provide a method to fairly price heat and cooling. A case study of a typical United States home shows that a heat purchase agreement could more than double the value of a heat pump investment relative to the incumbent business model. The potential impact of this work is to reduce emissions both directly, by accelerating replacement of fossil-fueled or inefficient heating or cooling equipment, and indirectly, by helping power system operators reliably integrate wind and solar generation.