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Abstract The effect of high temperatures as a degrading factor of rock materials is investigated in this study. Valdieri Marble samples, collected in a quarry in North-western Italian Alps, were subjected to thermal cycles (ranging from 105° to 600 °C) and to subsequent non-destructive and destructive laboratory tests with the aim of evaluating the variation of physical and mechanical properties as a function of temperature variations. Physical and mechanical measurements were complemented with microscopic observations on thin sections. The increase of crack density with temperature and the consequent porosity increases were found to be the main causes of degradation of physical and mechanical properties. In general, density, ultrasonic pulse velocity, wet electrical resistivity, uniaxial compressive strength and Young's moduli decrease as temperature increases. By contrast, peak strain and porosity increase. Correlations between temperature and physical-mechanical properties were proposed and compared to other relationships already established in scientific literature. A damage parameter to quantify the degradation of mechanical properties with temperature is also proposed.

For layered oxide cathodes, aluminum doping has widely been shown to improve performance, particularly at high degrees of delithiation. While this has led to increased interest in Al-doped systems, including $\mathrm{LiNi_{0.8}Co_{0.15}Al_{0.05}O_{2}}$ (NCA), the aluminum surface environment has not been thoroughly investigated. Using hard x-ray photoelectron spectroscopy measurements of the Al 1s core region for NCA electrodes, we examined the evolution of the surface aluminum environment under electrochemical and thermal stress. By correlating the aluminum environment to transition metal reduction and electrolyte decomposition, we provide further insight into the cathode-electrolyte interface layer. A remarkable finding is that Al-O coatings in LiPF$_6$ electrolyte mimic the evolution observed for the aluminum surface environment in doped layered oxides. ECS transactions 80(10), 197 - 206 (2017). doi:10.1149/08010.0197ecst Published by Pennington, NJ

AbstractWe report a nickel complex for catalytic oxidation of ammonia to dinitrogen under ambient conditions. Using the aryloxyl radical 2,4,6‐tri‐tert‐butylphenoxyl (tBu3ArO⋅) as a H atom acceptor to cleave the N−H bond of a coordinated NH3 ligand up to 56 equiv of N2 per Ni center can be generated. Employing the N‐oxyl radical 2,2,6,6‐(tetramethylpiperidin‐1‐yl)oxyl (TEMPO⋅) as the H‐atom acceptor, up to 15 equiv of N2 per Ni center are formed. A bridging Ni‐hydrazine product identified by isotopic nitrogen (15N) studies and supported by computational models indicates the N−N bond forming step occurs by bimetallic homocoupling of two paramagnetic [Ni]−NH2 fragments. Ni‐mediated hydrazine disproportionation to N2 and NH3 completes the catalytic cycle.