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The first dynamic modeling study of CO2 geological storage in the Baltic Sea basin is presented. The focus has been on the southern part of the Dalders Monocline. The objective is to get order-of-magnitude estimates of the behavior of the formations during potential industrial scale CO2 injection and subsequent storage periods, with an emphasis on two important aspects of CO2 storage: the injection-induced pressure impact and the long-term upslope migration. In order to maximize the confidence in the model predictions, this work employs a set of different modeling approaches of varying complexity, including a semi-analytical model, a sharp-interface vertical equilibrium (VE) model and a TOUGH2-ECO2N model. The semi-analytical model provides fast estimation of the pressure buildup as well as its sensitivity to variation of the reservoir parameters. Given a certain pressure threshold, a maximum injection rate is estimated from the semi-analytical model and is then fed to the numerical models. The pressure buildup predicted by the numerical models fall close to that by the semi-analytical solution. Extensive modeling of the post-injection upslope migration and trapping evolution together with sensitivity analysis suggests that it is unlikely for CO2 to leak through the north end of the formation. Under the currently considered scenario, the dominant constraint for the storage capacity is the pressure buildup. The pressure limited capacity (Cp) of the southern Dalders Monocline for the scenario studied here is estimated to be about 100 Mt for a 50-year injection duration. Cp is found to increase with permeability as Cp ∼ k0.926. Given the knowledge of the dominant constraint for capacity, storage optimization can be specifically targeted on the injectivity issue and operational strategies can be designed to relieve the pressure buildup (e.g., by adding brine production wells, using horizontal wells).

Abstract In order to evaluate chemical impacts of SO2 impurity on reservoir rock during CO2 capture and storage in deep saline aquifers, several batch reactor experiments were performed on laboratory scale using core rock samples from the pilot CO2 injection site in Heletz. In this experiment, the samples were exposed to pure N2(g), pure CO2(g), and CO2(g) with an impurity of 1.5% SO2(g) under reservoir conditions for pressure and temperature (14.5 MPa, 60 °C). Based on the set-up and the obtained experimental results, a batch chemical model was established using the numerical simulation program TOUGHREACT V3.0-OMP. Comparing laboratory and simulation data provides a better understanding of the rock-brine-gas interactions. In addition, it offers an evaluation of the capability of the model to predict chemical interactions in the target injection reservoir during exposure to pure and impure CO2. The best match between the geochemical model and experimental data was achieved when the reactive surface area of minerals in the model was adjusted in order to calibrate the kinetic rates of minerals. The simulations indicated that SO2(g) tends to dissolve rather quickly and oxidizes under a kinetic control. Hence, it has a stronger effect on the acidity of the brine than pure CO2(g) and as a result, increased mineral dissolution and caused the precipitation of sulfate and sulfide minerals. Ankerite, dolomite, and siderite, the most abundant carbonates in the sandstone rock sample, are subject to stronger dissolution in the presence of SO2 gas. The performed simulations confirmed a slower dissolution rate for ankerite and siderite than for dolomite. The model reproduced the precipitation of pyrite and anhydrite as observed in the laboratory. The dissolution of dolomite observed in the batch reaction test with pure N2 is assumed to be due to slight contamination with oxygen and modelling supported this. The inclusion of SO2 increased the porosity over that of the pure CO2 case, and is thus considered to increase the permeability and injectivity of the reservoir as well. Exposure to SO2 also increased the concentration of trace elements. The calibrated kinetic parameters determined in this study will be used to model the injection and long-term behavior of CO2 at the Heletz field site, and may be used for similar geologic reservoirs.

Industrial CO2 emissions to the atmosphere can be reduced through geological storage, where the gas is injected into the subsurface and trapped by several mechanisms. Residual and solubility trappi ...