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The agro-livestock sector produces about one third of global greenhouse gas (GHG) emissions. Since more energy is needed to meet the growing demand for food and the industrial revolution in agriculture, renewable energy sources could improve access to energy resources and energy security, reduce dependence on fossil fuels, and reduce GHG emissions. Hydrogen production is a promising energy technology, but its deployment in the global energy system is lagging. Here, we analyzed the theoretical and practical application of green hydrogen generated by electrolysis of water, powered by renewable energy sources, in the agro-livestock sector. Green hydrogen is at an early stage of development in most applications, and barriers to its large-scale deployment remain. Appropriate policies and financial incentives could make it a profitable technology for the future.

The agro-livestock sector produces about one third of global greenhouse gas (GHG) emissions. Since more energy is needed to meet the growing demand for food and the industrial revolution in agriculture, renewable energy sources could improve access to energy resources and energy security, reduce dependence on fossil fuels, and reduce GHG emissions. Hydrogen production is a promising energy technology, but its deployment in the global energy system is lagging. Here, we analyzed the theoretical and practical application of green hydrogen generated by electrolysis of water, powered by renewable energy sources, in the agro-livestock sector. Green hydrogen is at an early stage of development in most applications, and barriers to its large-scale deployment remain. Appropriate policies and financial incentives could make it a profitable technology for the future.

Abstract Carbon dioxide (CO2) is becoming an important commercial and industrial working fluid as a potential replacement of the non-environmental friendly refrigerants. For refrigeration and power systems, the minichannel heat exchangers are becoming attractive for transcritical CO2 Rankine cycle and supercritical CO2 Brayton cycle, due to their highly compact construction, high heat transfer coefficient, high pressure capability and lower fluid inventory. This paper employs three-dimensional numerical models to investigate the heat transfer and pressure drop characteristics of supercritical CO2 in minichannels. The models consider real gas thermophysical properties and buoyancy effect and investigate the effect of cross-section geometry on the thermohydraulic characteristics. Six minichannel cross-section geometries with the same hydraulic diameter of 1.22 mm are considered. The geometries include circle, semicircle, square, equilateral triangle, rectangle (aspect ratio = 2) and ellipse (aspect ratio = 2). The inlet temperature, outlet pressure and wall heat flux are 35 °C/75 bar/100 kW/m2 and 35 °C/150 bar/300 kW/m2 for heating conditions and 120 °C/75 bar/-100 kW/m2 and 120 °C/150 bar/-300 kW/m2 for cooling conditions. Comparisons of local Nusselt number and friction factor with those employed empirical correlations are made and useful information and guidelines are provided for the design of compact heat exchangers for supercritical CO2 power system applications.

Abstract Carbon dioxide (CO2) is becoming an important commercial and industrial working fluid as a potential replacement of the non-environmental friendly refrigerants. For refrigeration and power systems, the minichannel heat exchangers are becoming attractive for transcritical CO2 Rankine cycle and supercritical CO2 Brayton cycle, due to their highly compact construction, high heat transfer coefficient, high pressure capability and lower fluid inventory. This paper employs three-dimensional numerical models to investigate the heat transfer and pressure drop characteristics of supercritical CO2 in minichannels. The models consider real gas thermophysical properties and buoyancy effect and investigate the effect of cross-section geometry on the thermohydraulic characteristics. Six minichannel cross-section geometries with the same hydraulic diameter of 1.22 mm are considered. The geometries include circle, semicircle, square, equilateral triangle, rectangle (aspect ratio = 2) and ellipse (aspect ratio = 2). The inlet temperature, outlet pressure and wall heat flux are 35 °C/75 bar/100 kW/m2 and 35 °C/150 bar/300 kW/m2 for heating conditions and 120 °C/75 bar/-100 kW/m2 and 120 °C/150 bar/-300 kW/m2 for cooling conditions. Comparisons of local Nusselt number and friction factor with those employed empirical correlations are made and useful information and guidelines are provided for the design of compact heat exchangers for supercritical CO2 power system applications.

Activated sludge from municipal wastewater treatment processes can be used directly for the production of biodegradable polyesters from the family of polyhydroxyalkanoates (PHAs). However, municipal activated sludge typically cannot accumulate PHAs to very high levels and often low yields of polymer produced on substrate are observed. In the present work, it was found that the presence of calcium promotes selective growth and enrichment of the PHA-storing biomass fraction and significantly improved both PHA contents and yields. Calcium addition resulted in PHA contents of 0.60 ± 0.03 gPHA/gVSS and average PHA yields on substrate of 0.49 ± 0.03 gCODPHA/gCODHAc compared to 0.35 ± 0.01 gPHA/gVSS and 0.19 ± 0.01 gCODPHA/gCODHAc without calcium addition. After 48 h, three times more PHA was produced compared to control experiments without calcium addition. Higher PHA content and selective biomass production is proposed to be a consequence of calcium dependent increased levels of passive acetate uptake. Such more efficient substrate uptake could be related to a formation of calcium acetate complexes. Findings lead to bioprocess methods to stimulate a short-term selective growth of PHA-storing microorganisms and this enables improvements to the techno-economic feasibility for municipal waste activated sludge to become a generic resource for industrial scale PHA production.

Activated sludge from municipal wastewater treatment processes can be used directly for the production of biodegradable polyesters from the family of polyhydroxyalkanoates (PHAs). However, municipal activated sludge typically cannot accumulate PHAs to very high levels and often low yields of polymer produced on substrate are observed. In the present work, it was found that the presence of calcium promotes selective growth and enrichment of the PHA-storing biomass fraction and significantly improved both PHA contents and yields. Calcium addition resulted in PHA contents of 0.60 ± 0.03 gPHA/gVSS and average PHA yields on substrate of 0.49 ± 0.03 gCODPHA/gCODHAc compared to 0.35 ± 0.01 gPHA/gVSS and 0.19 ± 0.01 gCODPHA/gCODHAc without calcium addition. After 48 h, three times more PHA was produced compared to control experiments without calcium addition. Higher PHA content and selective biomass production is proposed to be a consequence of calcium dependent increased levels of passive acetate uptake. Such more efficient substrate uptake could be related to a formation of calcium acetate complexes. Findings lead to bioprocess methods to stimulate a short-term selective growth of PHA-storing microorganisms and this enables improvements to the techno-economic feasibility for municipal waste activated sludge to become a generic resource for industrial scale PHA production.