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Experimental research of photocatalytical oxidation (PCO) of aqueous solutions of de‐icing agents (ethylene glycol and ethylene glycol monoethyl ether) and methyl tert‐butyl ether (MTBE) was undertaken. These chemicals are water‐soluble components of jet and motor fuels accidentally disposed to the environment. Titanium dioxide (Degussa P25) under near‐UV irradiation was selected as a photocatalyst. A slightly acidic medium was preferable for the process efficiency for MTBE, whereas a neutral medium was beneficial for de‐icing agents and jet fuel aqueous extracts. TiO2 suspension fractional composition was found to be dependent on pH and the presence of organic admixtures: the minimum size of TiO2 particles at their maximum uniformity was established in an acidic medium, where the efficiency of PCO of de‐icing agents was the poorest. On the other hand, neutral and slightly acidic media, beneficial for PCO efficiency, were favourable for particle agglomeration, which indicates a minimal role for photocatalyst particle size in PCO efficiency. PCO efficiency increased with increasing MTBE and icing inhibitor concentration. The biodegradability of aqueous solutions of oxygenated additives increased as PCO proceeded. The influence of mineral additives—sulphate, calcium, ferric and manganese ions—on the process efficiency was found to be complex. Special attention was paid to energy‐saving PCO with a photocatalyst attached to buoyant glass micro‐spheres and reduced intensity of stirring of the slurry.

Abstract There are instances in remote areas where heat is being wasted, e.g., in internal combustion, engines, etc. Some of this heat can be recovered to produce distilled water in solar stills. The solar still replaces the cooling tower, ponds, or radiators normally used to control the engine temperature. The diesel cooling water in such a system remains separate from the saline water in the solar still. The advantages of using such a system compared with a conventional solar still are: 1. (a) water costs are very much reduced 2. (b) the area occupied is much less, i.e., about 1 5 th 3. (c) production has much less seasonal variation 4. (d) the efficiency of the solar still is improved due to the higher operating temperatures. From experiments conducted at Highett using a Mk VI solar still fitted with a simple heat exchanger and a separate electrically-heated source of hot water to simulate the waste heat, design data are not available for application to working systems. The information required to match a solar still to a diesel's cooling requirement is: 1. (a) engine efficiency 2. (b) hourly fuel consumption 3. (c) hourly solar radiation 4. (d) hourly ambient temperatures. A by-product of this work has been the production of a “solar water heater” which costs less than that of the cheapest conventional system. This “solar” hot water system uses a heat exchanger similar to what is used to transfer the waste heat to the saline water. It is envisaged to have hot water productions approximately the same as the distilled water productions. The influence of hot water production on the output of the waste heat solar still is discussed.

Abstract Hybrid TiO2/SiO2 thin films deposited by material printing technique on flexible substrates were prepared, characterized and tested for solar photocatalytic disinfection. Effect of surface hydrophilicity/hydrophobicity of printed coatings on photocatalytic disinfection was studied by means of (i) drinking water contaminated with natural consortia of fecal bacteria (gram-negative: Escherichia coli and total coliforms; gram-positive: Enterococci), and (ii) seawater containing pathogenic gram-negative bacteria (Vibrio owensii, Vibrio alfacsensis and Vibrio harveyi). Inactivation of gram-negative bacteria in drinking water with fecal contamination by solar photocatalysis was slightly more efficient than solar disinfection, while for gram-positive bacteria similar efficiency was observed. These results, in combination with observed release of titanium from coatings (detected by means of inductively coupled plasma atomic emission spectrometer), indicate that TiO2/SiO2 needs further improvements for solar photocatalytic disinfection of drinking water. Efficiency of seawater disinfection towards gram-negative Vibrio spp. (Vibrio owensii, Vibrio alfacsensis and Vibrio harveyi) was significantly enhanced when TiO2/SiO2 coatings were used under natural solar light. Moreover, hydrophobic thin films led to faster Vibrio spp. inactivation as compared to hydrophilic ones, which was attributed to higher bacteria adhesion on hydrophobic coatings. However, decrease of photocatalytic activity of hydrophobic TiO2/SiO2 coatings was observed after ten experimental cycles mainly due to deposition of salts on the surface of photocatalyst. Generally, results of this study suggest that autochthonous bacteria such as Vibrio spp. in seawater are significantly more resistant to solar disinfection in comparison with not autochthonous bacteria such as Escherichia coli, total coliforms and Enterococci in contaminated drinking water.

Abstract Algae have been considered as a promising biodiesel feedstock. One of the major factors affecting large-scale algae technology application is poor wintering cultivation performance. In this study, an integrated approach is investigated combining freshwater microalgae Chlorella zofingiensis wintering cultivation in pilot-scale photobioreactors with artificial wastewater treatment. Mixotrophic culture with the addition of acetic acid (pH-regulation group) and autotrophic culture (control group) were designed, and the characteristics of algal growth, lipid and biodiesel production, and nitrogen and phosphate removal were examined. The results showed that, by using acetic acid three times per day to regulate pH at between 6.8 and 7.2, the total nitrogen (TN) and total phosphate (TP) removal could be increased from 45.2% to 73.5% and from 92.2% to 100%, respectively. Higher biomass productivity of 66.94 mg L−1 day−1 with specific growth rate of 0.260 day−1 was achieved in the pH-regulation group. The lipid content was much higher when using acetic acid to regulate pH, and the relative lipid productivity reached 37.48 mg L−1 day−1. The biodiesel yield in the pH-regulated group was 19.44% of dry weight, with 16–18 carbons as the most abundant composition for fatty acid methyl esters. The findings of the study prove that pH adjustment using acetic acid is efficient in cultivating C. zofingiensis in wastewater in winter for biodiesel production and nutrient reduction.

With the rising population, environmental pollution, and social development, potable water is reducing and being contaminated day by day continually. Thus, several researchers have focused their studies on seas and oceans in order to get potable fresh water by desalination of their saltwater. Solar still of basin type is one of the available technologies to purify water because of free solar energy. The computational fluid dynamic CFD model of the solar still can significantly improve means for optimization of the solar still structure because it reduces the need for conducting large amount of experiments. Therefore, the main purpose of this study is presenting a multi-phase, three-dimensional CFD model, which predicts the performance of the solar still without using any experimental measurements, depending on the CFD solar radiation model. Simulated results are compared with experimental values of water and glass cover temperatures and yield of fresh water in climate conditions of Sheben El-Kom, Egypt (latitude 30.5° N and longitude 31.01° E). The simulation results were found to be in acceptable agreement with the experimental measured data. The results indicated that the daily simulated and experimental accumulated productivities of the single-slope solar still were found to be 1.982 and 1.785 L/m2 at a water depth of 2 cm. In addition, the simulated and experimental daily efficiency were around 16.79% and 15.5%, respectively, for the tested water depth.

Abstract Water supply and wastewater services incur a large amount of energy and GHG emissions. It is therefore imperative to understand the link between water and energy as their availability and demand are closely interrelated. This paper presents a literature review and assessment of knowledge gaps related to water–energy–greenhouse gas (GHG) nexus studies in an urban context from an ‘energy for water’ perspective. The review comprehensively surveyed various studies undertaken in various regions of the world and focusing on individual or multiple subsystems of an urban water system. The paper also analyses the energy intensity of decentralized water systems and various water end-uses together with the major tools and models used. A major gap identified from this review is the lack of a holistic and systematic framework to capture the dynamics of multiple water–energy–GHG linkages in an integrated urban water system where centralized and decentralized water systems are combined to meet increased water demand. Other knowledge gaps identified are the absence of studies, peer reviewed papers, data and information on water–energy interactions while adopting a ‘fit for purpose water strategy’ for water supply. Finally, based on this review, we propose a water–energy nexus framework to investigate ‘fit-for-purpose’ water strategy.

This work presents a pathway for Saudi Arabia to transition from the 2015 power structure to a 100% renewable energy-based system by 2050 and investigates the benefits of integrating the power sector with the growing desalination sector. Saudi Arabia can achieve 100% renewable energy power system by 2040 while meeting increasing water demand through seawater reverse osmosis (SWRO) and multiple effect distillation (MED) desalination plants. The dominating renewable energy sources are PV single-axis tracking and wind power plants with 243 GW and 83 GW, respectively. The levelised cost of electricity (LCOE) of the 2040 system is 49 €/MWh and decreases to 41 €/MWh by 2050. Corresponding levelised cost of water (LCOW) is found to be 0.8 €/m3 and 0.6 €/m3. PV single-axis tracking dominates the power sector. By 2050 solar PV accounts for 79% of total electricity generation. Battery storage accounts for 41% of total electricity demand. In the integrated scenario, due to flexibility provided by SWRO plants, there is a reduced demand for battery storage and power-to-gas (PtG) plants as well as a reduction in curtailment. Thus, the annual levelised costs of the integrated scenario is found to be 1–3% less than the non-integrated scenario.

Pretreatment of lignocellulosic biomass is a prerequisite to overcome recalcitrance and allow enzyme accessibility to cellulose and maximize product recovery for improved economics of second-generation lignocellulosic bio-refineries. Recently, the three US-DOE funded Bioenergy Research Centers (Joint Bioenergy Institute (JBEI), Great Lakes Bioenergy Research Center (GLBRC), and BioEnergy Science Center (BESC)) compared ionic liquid (IL), dilute sulfuric acid (DA), and ammonia fiber expansion (AFEXTM) pretreatments and published comparative data on mass balance, total sugar yields, substrate accessibility, and microbial fermentation (Biotechnology for Biofuels 7: 71; 72 (2014)). In this study, corn stover solids from IL, DA, and AFEX pretreatments were compared to gain comprehensive, in-depth understanding of induced morphological and chemical changes incorporated to corn stover, and how they overcome the biomass recalcitrance. These studies reveal that biomass recalcitrance is overcome by combination of structural and chemical changes to carbohydrates and lignin after pretreatment. Thermal analysis indicates that AFEX and IL pretreated corn stover showed a lower thermal stability while DA pretreated corn stover showed the opposite. The surface roughness variations measured by SANS were correlated to the removal and redistribution of biomass components and was consistent with compositional analysis, AFM and confocal fluorescence imaging results. With AFM and confocal fluorescent microscopy, lignin was found to be re-deposited on cellulose surface with average cellulose fiber width significantly decreased for DA pretreated corn stover (one third of IL and AFEX). HSQC NMR spectra revealed a ~17.9% reduction of β-aryl ether units after AFEX, ~59.8% reduction after DA and >98% reduction after IL. Both NMR and SEC showed similar patterns of lignin depolymerization with highest degree of depolymerization observed for IL followed with DA and AFEX.