• Energy Research
• Open Access close
• Restricted close
• Embargo close
• engineering and technology close
• CH close
• FI close

Abstract Secondary concentrators are used in solar concentrating systems to redirect solar beams reflected by the primary concentrators to the focal point or line. These components allow to increase the concentrated solar flux density and hence to lower thermal radiation losses. Solar reflectors for secondary concentrators are permanently exposed to environmental conditions, high radiation fluxes and elevated temperatures that potentially cause stress and degradation throughout the time. Therefore, analyzing solar reflectors of secondary concentrators by simulating these conditions is crucial. No previous research works about the durability of solar reflector materials for secondary concentrators have been reported. The present work is focused on studying the degradation of the reflector materials by simulating accelerated aging, caused by several ambient parameters and the effect of concentrated radiation. Both cooled and uncooled systems for secondary concentrators are included in this study. According to results obtained, aluminum reflectors and thin silvered-glass reflectors glued to an aluminum structure showed minimum reflectance losses and structural degradation under the operation conditions of cooled 3D secondary concentrators (tower systems). Following critical aspects to avoid reflector degradation were identified: to select a suitable adhesive material to glue the thin silvered-glass reflector to the support aluminum structure, to properly protect reflectors edges, to design a suitable cooling system and to avoid the combination of high radiation fluxes with mechanical stress. In addition, laminated silvered-glass reflectors have shown to be suitable for uncooled 2D secondary concentrators (Fresnel collectors). Furthermore, a comparison with naturally aged secondary concentrators using silvered-glass reflectors glued to an aluminum structure revealed that the simulated degradation under accelerated conditions performed in this work did reproduce the most frequent degradation patterns suffered in real operating conditions.

Laboratory corrosion and scaling testing of metallic materials exposed in high temperature and pressure environments generally involves complex, multi-instrument measurement setups. Here, we present a setup including an autoclave that is instrumented for in-situ electrochemical testing and that contains a ZrO2-based solid-state pH electrode and devices for temperature control and solution stirring. We show results highlighting the importance of adequate pre-calibration of the pH measurement, due to the hysteresis depending on temperature sweep. Additionally, we illustrate how interfacing the autoclave and the electrochemical cell to measuring and controlling instruments, using different data communication interfaces, can create ground loops. These ground loop interferences can introduce significant errors in the measurement, such as a potential shift of >100 mV. In complex, multi-instrument setups, a complete understanding of ground loops may often be difficult. Thus, we recommend systematic checks to identify the ground loops and we propose measures to avoid them. Measurement, 155 ISSN:0263-2241 ISSN:1873-412X

The syntheses of 4,4′-bis(4-dimethylaminophenyl)-6,6′-dimethyl-2,2′-bipyridine (1), 4,4′-bis(4-dimethylaminophenylethynyl)-6,6′-dimethyl-2,2′-bipyridine (2), 4,4′-bis(4-diphenylaminophenyl)-6,6′-dimethyl-2,2′-bipyridine (3), and 4,4′-bis(4-diphenylaminophenylethynyl)-6,6′-dimethyl-2,2′-bipyridine (4) are reported along with the preparations and characterisations of their homoleptic copper(I) complexes [CuL2][PF6] (L = 1–4). The solution absorption spectra of the complexes exhibit ligand-centred absorptions in addition to absorptions in the visible region assigned to a combination of intra-ligand and metal-to-ligand charge-transfer. Heteroleptic [Cu(5)(Lancillary)]+ dyes in which 5 is the anchoring ligand ((6,6′-dimethyl-[2,2′-bipyridine]-4,4′-diyl)bis(4,1-phenylene))bis(phosphonic acid) and Lancillary = 1–4 have been assembled on fluorine-doped tin oxide (FTO)-TiO2 electrodes in dye-sensitized solar cells (DSCs). Performance parameters and external quantum efficiency (EQE) spectra of the DSCs (four fully-masked cells for each dye) reveal that the best performing dyes are [Cu(5)(1)]+ and [Cu(5)(3)]+. The alkynyl spacers are not beneficial, leading to a decrease in the short-circuit current density (JSC), confirmed by lower values of EQEmax. Addition of a co-absorbent (n-decylphosphonic acid) to [Cu(5)(1)]+ lead to no significant enhancement of performance for DSCs sensitized with [Cu(5)(1)]+. Electrochemical impedance spectroscopy (EIS) has been used to investigate the interfaces in DSCs; the analysis shows that more favourable electron injection into TiO2 is observed for sensitizers without the alkynyl spacer and confirms higher JSC values for [Cu(5)(1)]+.

Demand-Side Management systems aim to modulate energy consumption at the customer side of the meter using price incentives. Current incentive schemes allow consumers to reduce their costs, and from the point of view of the supplier play a role in load balancing, but do not lead to optimal demand patterns. In the context of charging fleets of electric vehicles, we propose a centralised method for setting overnight charging schedules. This method uses evolutionary algorithms to automatically search for optimal plans, representing both the charging schedule and the energy drawn from the grid at each time-step. In successive experiments, we optimise for increased state of charge, reduced peak demand, and reduced consumer costs. In simulations, the centralised method achieves improvements in performance relative to simple models of non-centralised consumer behaviour.

Micro hydro power plants (µHPP) are typically used to supply electric energy to microgrids outside the national power grids taking care of the frequency control of the isolated system. A conventional way to maintain the load balance in the system is to use thyristor switched AC-AC converters controlled dump loads. A disadvantage of the AC-AC converters is their reactive power consumption decreasing the power factor at the generator output. To avoid this problem the authors have earlier proposed two converter topologies utilizing symmetrical switching scheme resulting to zero reactive power consumption. The objective of this paper is to evaluate the frequency regulation loop performance of the dump load controlled single generator system by using the symmetrically switched converter structures. Evaluation is carried out by analyzing the performances of different converter structures in a simulator representing the operation of a Cuban µHPP “Los Gallegos”. The results showed that the frequency regulation loop performance using each proposed converter structure satisfied the Cuban standard of frequency regulation, but with the symmetrically switched structures reactive power consumption was reduced resulting to reduced losses and improved effective current delivery capacity of the generator.

We have developed a method that enables better taking into account of need of space of actions of moving objects in a building when Building Information Modeling (BIM) is used. The 3D spatial objects for real space requirements of actions created with our method can be used with various design tools as such in dimensioning or to generate video game colliders defining the need of space. Together with the gamified model of the structure from BIM they enable dimensioning in designs and simulations. We can dimension spatial objects for example related to safety. There are a lot of needs and applications for our methods. It is possible to design buildings and other structures that fit their purpose well.

Most of the existed works on the radio resource allocation (RRA) problem commonly assume the channel-state information (CSI) can be perfectly obtained by the transmission source. However, such assumption is not practical in the realistic wireless systems. In this work, we consider the practical implementation issues of resource allocation in orthogonal frequency division multiple access (OFDMA) two-way relay networks: the inaccuracy of channel-state information (CSI) available to the source. Instead, only the estimated channel status is known by the source. In this context, a joint optimization of subcarrier pairing and allocation, relay selection, and transmit power allocation is formulated in OFDMA two-way amplify-and-forward relay networks. Moreover, the objective of this work is to minimize the energy consumption of the overall system. Further, to ensure the quality of service (QoS) or data rate requirement, the energy consumption must be minimized without compromising the QoS. Therefore, by applying convex optimization techniques, energy-efficient algorithms are developed with the objective to minimize the total transmit power with guaranteeing the required data rates. Through simulation studies, energy consumption performance of the systems under the proposed schemes is investigated. It can be observed that our proposed scheme can improve the energy consumption performance of the considered system.