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Purpose This study aims to consider environmental sustainability, a global challenge under the preview of sustainable development goals, highlighting the significance of knowledge economy in attaining sustainable aggregate demand behavior globally. For this purpose, 155 countries that have data available from 1995 to 2021 were selected. The purpose of selecting these countries is to test the global responsibility of the knowledge economy to attain environmental sustainability. Design/methodology/approach Results are estimated with the help of panel quantile regression. The empirical existence of aggregate demand-based environmental Kuznets curve (EKC) was tested using non-linear tests. Moreover, principal component analysis has been incorporated to construct the knowledge economy index. Findings U-shaped aggregate demand-based EKC at global level is validated. However, environmental deterioration increases with an additional escalation after US$497.945m in aggregate demand. As a determinant, the knowledge economy is reducing CO2 emissions. The knowledge economy has played a significant role in global responsibility, shifting the EKC downward and extending the CO2 reduction phase for every selected country. Further, urbanization, energy intensity, financial development and trade openness significantly deteriorate the environmental quality. Originality/value This study contains the empirical existence of aggregate demand-based EKC. The role of the knowledge economy is examined through an index which is calculated by using four pillars of the knowledge economy (technology, innovations, education and institutions). This study is based on a combined panel of all the countries for which the data was available.

AbstractThe presented synthesis of the title compounds (II), (IV), (VI) and (VIII) is extremely simple and highly efficient without the use of any chromatographic purification.

Abstract Hybrid energy storage is a multi-modal approach to store and supply different forms of energy (electricity, heat, cold) simultaneously. This is an important sector coupling approach and enables large scale flexibility for a deep decarbonization of energy systems. Two different proposed energy storages – power-to-heat-to-X energy storage (PHXES) and pumped thermal energy storage (PTES) – are investigated in detail in this work towards their potential towards a hybrid deployment. The techno-economic analysis includes thermodynamic flowsheet simulations and unified cost estimations based on the used equipment. It is shown that the main input data set (e.g. working fluid selection, turbomachinery efficiency, pinch temperatures) has a strong influence on storage roundtrip efficiency in the thermodynamic simulations, but also on storage costs. Cost decrease and performance increase can be conflicting development targets, and it is not clear if future energy systems rather require technologies with the highest storage efficiencies or if low cost is an important prerequisite. PHXES and three variants of PTES are implemented into a simplified energy system model of the city of Hamburg that comprises the electric load and heat demand of the district heating system. Two scenarios (fossil benchmark and 80% decarbonization) are used to select the technologies and their capacities that allow the most cost-effective energy supply solution by a linear-programming optimization procedure. Large scale renewable power generation and hybrid energy storage play the major roles in the decarbonization scenario. PHXES with a storage capacity of 69 GWh, hot water storage (3.6 GWh) and a battery system (430 MWh) are part of the cost-optimal solution. A cost sensitivity analysis shows that a total cost reduction of 60–80% is required for PTES to become competitive in this model scenario.

Bioplastics are alternatives of conventional petroleum-based plastics. Bioplastics are polymers processed from renewable sources and are biodegradable. This study aims at conducting an environmental impact assessment of the bioprocessing of agricultural wastes into bioplastics compared to petro-plastics using an LCA approach. Bioplastics were produced from potato peels in laboratory. In a biochemical reaction under heating, starch was extracted from peels and glycerin, vinegar and water were added with a range of different ratios, which resulted in producing different samples of bio-based plastics. Nevertheless, the environmental impact of the bioplastics production process was evaluated and compared to petro-plastics. A life cycle analysis of bioplastics produced in laboratory and petro-plastics was conducted. The results are presented in the form of global warming potential, and other environmental impacts including acidification potential, eutrophication potential, freshwater ecotoxicity potential, human toxicity potential, and ozone layer depletion of producing bioplastics are compared to petro-plastics. The results show that the greenhouse gases (GHG) emissions, through the different experiments to produce bioplastics, range between 0.354 and 0.623 kg CO2 eq. per kg bioplastic compared to 2.37 kg CO2 eq. per kg polypropylene as a petro-plastic. The results also showed that there are no significant potential effects for the bioplastics produced from potato peels on different environmental impacts in comparison with poly-β-hydroxybutyric acid and polypropylene. Thus, the bioplastics produced from agricultural wastes can be manufactured in industrial scale to reduce the dependence on petroleum-based plastics. This in turn will mitigate GHG emissions and reduce the negative environmental impacts on climate change.

Abstract Agricultural practice is facing multiple challenges under volatile commodity markets, inevitable climate change, mounting pest pressure and various other environment-related constraints. The objective of this research is to present a dynamic optimization model of crop rotations and farm management and show its suitability for economic analysis over a 30 year time period. In this model, we include management practices such as fertilization, fungicide treatment and liming, and apply it in a region in Southwestern Finland. Results show that (i) growing pest pressure favours the cultivation of wheat-oats and wheat-oilseeds combinations, while (ii) market prices largely determine the crops in the rotation plan and the specific management practices adopted. The flexibility of our model can also be utilized in evaluating the value of other management options such as new cultivars under different projections of future climate and market conditions.

AbstractEcologists are increasingly aware of the importance of environmental variability in natural systems. Climate change is affecting both the mean and the variability in weather and, in particular, the effect of changes in variability is poorly understood. Organisms are subject to selection imposed by both the mean and the range of environmental variation experienced by their ancestors. Changes in the variability in a critical environmental factor may therefore have consequences for vital rates and population dynamics. Here, we examine ≥90‐year trends in different components of climate (precipitation mean and coefficient of variation (CV); temperature mean, seasonal amplitude and residual variance) and consider the effects of these components on survival and recruitment in a population of Eurasian beavers (n = 242) over 13 recent years. Within climatic data, no trends in precipitation were detected, but trends in all components of temperature were observed, with mean and residual variance increasing and seasonal amplitude decreasing over time. A higher survival rate was linked (in order of influence based on Akaike weights) to lower precipitation CV (kits, juveniles and dominant adults), lower residual variance of temperature (dominant adults) and lower mean precipitation (kits and juveniles). No significant effects were found on the survival of nondominant adults, although the sample size for this category was low. Greater recruitment was linked (in order of influence) to higher seasonal amplitude of temperature, lower mean precipitation, lower residual variance in temperature and higher precipitation CV. Both climate means and variance, thus proved significant to population dynamics; although, overall, components describing variance were more influential than those describing mean values. That environmental variation proves significant to a generalist, wide‐ranging species, at the slow end of the slow‐fast continuum of life histories, has broad implications for population regulation and the evolution of life histories.

Sugarcane biorefineries, despite their contribution to sustainable transportation fuels and mitigation of carbon emissions in the mobility sector, produce a large amount of carbon dioxide in their conversion processes. According to the Paris climate agreement, a carbon neutral energy system has to be launched in the years to come, and in this scenario, greenhouse gases emission free industrial processes and alternative carbon sources will be needed. Therefore, this paper presents the evaluation of carbon mass balance of a typical Brazilian ethanol mill to better understand its potential for energy and carbon yield improvement. Due to the fact that Brazilian sugarcane mills are evolving from first generation to integrated first and second generation plant, four different scenarios were analysed. For a first generation plant without (S-I) and with conversion of straw to electricity (S-II) and for the integrated plant (S-III), results of carbon mass balance showed that the harvested sugarcane carbon was mainly converted into CO2 and in a smaller proportion into ethanol. In the modelled cases S-I to S-III the conversion of sugarcane carbon into CO2 and ethanol ranged from 41% to 53% and 17%-22%, respectively. Because this carbon amount in the CO2 flows provides an interesting platform to both increase the bioenergy produced and the harvested carbon-to-fuels ratio, a fourth scenario (S-IV) that studies the integration of power-to-gas (PtG) technologies into the mill was also considered. PtG can increase the sugarcane fuels energy content from 9.3 kW/ha to 33.6 kW/ha using 1361.3 MWe of electricity, increasing the amount of sugarcane carbon transformed into sugarcane based fuels to 54% and converting CO2 into a high value added product.

Abstract In the context of climate change, global industrialised nations are grappling with transforming energy networks to support a low carbon future. Using an energy justice framework this work aims to understand holistic outcomes of one low-carbon energy network intervention: demand-side response enacted on domestic heat pumps. By exploring participants’ lived experience of a pilot project, from recruitment to installation and use, this work reveals how injustices were reduced, introduced and amplified. Choice, consent, cost, comfort, disruption, and control are highlighted as key aspects of interest when considering the distributive, procedural, and recognition implications of this domestic innovation. For a net reduction of energy injustices to be realised, we highlight the need for project designers to work in partnership with end users to optimise the benefits for the household and the electricity system. Whilst this is a UK study, the themes and findings are internationally applicable for interventions that aim to harness the flexibility of heating, the largest global energy end-use.