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This thesis examines the opposition to civil nuclear energy in France and West Germany during the 1970s, arguing that small-scale interactions among its diverse participants led to broad changes in their personal lives and political environments. Drawing extensively on oral history interviews with former activists as well as police reports, media coverage and protest ephemera, this thesis shows how individuals at the grassroots built up a movement that transcended national (and social) borders. They were able to do so in part because nuclear power was such a multivalent symbol at the time. Residents of towns near planned power stations felt that nuclear technology represented an intervention in their community by state and industry, a potential threat to their health, wealth and way of life. In the decade after 1968, concerns like these coalesced with criticisms of capitalism, the state, militarism and consumer society that were being made by a more politicised constituency. This made the anti-nuclear movement both broad-based and highly fragmented. Activist networks linked people across existing national, political and social boundaries, but the social world of activism was subject to its own divisions (such as between locals and outsiders or between militant and non-violent activists). By analysing both the transnational dimensions and internal divisions of the anti-nuclear movement, this thesis revises the homogenising concepts of social movements that are prevalent in much of the existing sociological and political science literature. At the same time, it situates the anti-nuclear movement historically within the decade of upheaval that was the 1970s, while moving individual activists from the margins to the centre of protest history.

Recent years have seen the emergence of stock exchange led initiatives which in various ways aim to enhance awareness and performance by listed companies and investors regarding environmental, social and governance (ESG) issues. This thesis explores issues of importance to understand the role of stock exchanges in promoting more sustainable company and market practices. First, the thesis establishes rationales for increased efforts by stock exchanges in this area by investigating the agenda of responsible investment and the debate about market dysfunctionalites which has intensified after the financial crisis. Second, the role, functions and institutional characteristics of stock exchanges are researched. The insights from these investigations are fed into a new framework designed to assess the potential stock exchanges have to contribute to more sustainable company and market practices, as well as impediments and enablers for this to happen. The findings suggest that stock exchanges have potential to make a positive impact on sustainability related matters, but are likely to face constraints. Realizing this, the thesis concludes that a case can be argued for including to a larger extent sustainability related issues in conventional financial market regulation to ensure long-term financial stability and well-functioning financial markets. However, this raises new questions. Different issues may hamper the effectiveness of such regulation, among others competition between financial centres and jurisdictional limitations of national regulation. This suggests that international standard setting bodies may have an important role to play.

This thesis is comprised of two closely related studies of fullerenes. The first part is an investigation of C60 and C70 nanocrystals using both experimental and simulated electron energy loss (EEL) spectra. Through a detailed comparison of particular features in EEL spectra collected from these materials in a transmission electron microscope, with simulated spectra, it is established that differences in spectra from different materials can be linked to particular aspects of the structural models. For example, in the case of C60 differences in experimental spectra from different samples can be linked to differences in the bond lengths within the molecules of different samples. In the case of C70, it is found that features within the spectrum which have previously been attributed to the ten equatorial atoms do not have this origin in a crystal. The second part is an experimental investigation of endohedral fullerenes Nd@C82 and Sc3N@C80. The effect of temperature on the EEL spectrum is investigated and, in the case of Nd@C82, the effect of the presence of different isomers is also investigated. Spectra are successfully obtained from the encapsulated atoms, and the importance of careful experiments in terms of avoiding contamination is highlighted.

This thesis shows how the Process Analysis Method (PAM) can be applied to assess technologies used to mitigate arsenic from drinking water in rural India, using a set of sustainability indicators. Stakeholder perspectives, gathered from a fieldwork survey of 933 households in West Bengal in 2012, played a significant role in this assessment. This research found that the ‘Most Important’ issues as specified by the technology users are cost, trust, distance from their home to the clean water source (an indicator of convenience), and understanding the health effects of arsenic. It was also found that none of the ten technologies evaluated are economically viable, as many do not charge user-fees, which creates reliance upon donations to meet recurring costs. Utilisation of a technology is strongly related to sociocultural capital, but in many cases, features that contribute to sociocultural value, like regular testing of the treated water, are not included in the financial budget. It is suggested that increased awareness might change attitudes to arsenic-rich waste and its disposal protocols. This waste is often currently discarded in an uncontrolled manner in the local environment, giving rise to the possibility of point-source recontamination. All technologies proved to have difficulties in dealing with waste, except the Tipot and Dug wells which produce no waste. Of the methods considered, the BESU technology scored highest, but still only with 47-62% of the maximum scores achievable within each domain. This explains the widespread failure of mitigation projects across the region. The indicators and metrics show where improvements can be made. A model scheme based on these findings is outlined which could be applied with the objective of increasing utilisation and improving sustainability. It can be concluded that a product stewardship approach should be taken in regard to design, implementation and operation of the technologies, including the creation of a regulated toxic waste collection and disposal industry.

The EU has, for a long time, portrayed itself as an international leader on climate change. Previous studies have tended to focus on the characteristics of EU leadership, but have failed to examine the extent to which EU leadership generates “followership”. Going beyond these existing approaches, this dissertation analyzes not just EU attempts at leadership but also the response of two potential followers: China and India. Based on extensive fieldwork, the dissertation explains the pattern of EU engagement and the response to engagement in each case, and makes three key arguments. First, EU engagement was driven by a desire to build the international role of the EU, but also from 2000 onwards in particular by growing normative concern and material interest within the EU regarding combating climate change. The development of engagement was also conditioned by the broader development of EU relations with China and India. Second, EU engagement took the form of institutionalized dialogue and capacity-building projects. These were generally more extensive in the EU-China case; the EU-India relationship was significantly more limited. Both cases were characterized by a lack of EU capacity—particularly the EU-India case and to some extent by inconsistency and incoherence. Third, the Chinese Government responded through limited normative emulation and limited but growing lesson-drawing through bilateral cooperation in specific sectors. While the Indian Government also responded through limited normative emulation, the principal Indian response was resistance. Moreover, both the Chinese and Indian Governments resisted the EU approach to the international climate change negotiations. This pattern of engagement and significant resistance stemmed partly from the EU’s failure to develop sufficient capacity for effective engagement, but also partly due to significant differences in the way each side has framed the issue of climate change. Based on these findings, the dissertation concludes that while the EU was not entirely a leader without followers, it has acted as a highly restricted leader in its relations with China and India on climate change.

Climate north of the Atlas Mountain belt in NW Africa is dominated by extratropical disturbances. However, climatic controls to the south, where climate transitions from extratropical to tropical regimes, are poorly understood due to a paucity of both instrumental and palaeoclimate data. In this thesis past climate change between the High Atlas Mountains and Sahara Desert is reconstructed using the stable isotopic composition and radiometric dating of speleothems. A high-resolution record from the mid-Holocene and a discontinuous record covering the past 400,000 years are developed. Supplemented by U-Th dating of a further four samples, these records indicate increased humidity in this area concomitant with the wider African Humid Period, and indicate a link between the West African Monsoon and humidity north of 30°N. Reconstructed glacial-interglacial scale increases in humidity overlap with "green Sahara" conditions and evidence a recurrent humid corridor connecting NW Africa and the central Sahara that is highly relevant to discussions of prehistoric human migrations. Evidence for a strong influence of high-latitude and solar forcing on decadal to millennial time- scales in this area is also presented. Further to this work, the potential of cadmium-to-calcite ratios as a novel proxy for palaeo-hydrology is confirmed using an annually-resolved trace element, stable isotope and calcite fabric dataset from a North Moroccan stalagmite. The first measurements of cadmium-to-calcite ratios in natural speleothem are here presented, and the palaeoclimatic significance and potential of this proxy for aiding the quantitative reconstruction of changes in calcite precipitation behaviour are demonstrated.

A policy mechanism known as REDD+ (‘Reducing Emissions from Deforestation and forest Degradation, and enhancing forest carbon stocks and conservation’) is designed to contribute to climate change mitigation efforts and simultaneously support developing countries’ national development agendas. This is effected by providing REDD+ host countries with financial incentives to produce measurable reductions in carbon emissions beyond what would have occurred without REDD+. Indonesia is a key target of the REDD+ mechanism for several reasons, eg: (i) its forests support 10% of the world's remaining tropical rain forests and represent the fourth largest forest carbon stock globally, (ii) 80% of its GHG emissions result from deforestation and forest degradation, and (iii) it has the potential to reduce up to 120 million tons of CO2 per year. Consequently, to date Indonesia has received donor’s commitments of nearly US$2 billion for REDD+ development. Given this profile, Indonesia’s success in implementing REDD+ can contribute significantly to the efficacy of REDD+ globally. However, achieving this potential is undermined by a set of long-standing problems inherent within Indonesia’s forest institutions, including issues of corruption, coordination, uncertainty in the forests’ legal system, capacity to manage forests at multiple levels of government, and the use of forest concessions to consolidate political power. This thesis asks the primary research question: “How do REDD+ institutions effect governance reform within Indonesia’s existing national and sub-national forest institutions?” 'Institutionalism', in particular the concept of 'institutional interplay' is the main conceptual framework deployed and grounded in the context of the vertical interplay between the internationally-formulated REDD+ mechanism and Indonesia's forest institutions. Guided by the themes that emerged from the data collected, this research explored and expanded certain analytical approaches within the perspectives of institutionalism and governance, namely ‘historical institutionalism’, ‘clientelism’, 'critical juncture', ‘policy networks’ and ‘social learning’. This thesis adopted the ‘four paper route’ and employed mixed methods of data collection (ie interview, shadowing, and policy document review). It found that during the process of institutional interplay as REDD+ institutions deployed the principles of good governance, advanced a robust system of measurement, reporting and verification of reductions in carbon emission, attracted large funding, and involved a broad range and multi-scale of actors, the REDD+ mechanism produced 'collateral benefits'. The tangible form of these benefits was the production of new policy instruments, eg the 'national REDD+ strategy' (paper 2), 'one map initiative' (paper 3), and ‘village agreement’ (paper 4) through which a significant body of evidence showed the capability of REDD+ to effect governance reform within and beyond Indonesia's forestry sector. Paper 1, revealed how policy actors perceived REDD+ and as such provides the basis of these three papers. The positive results of institutional interplay that occurred were determined not only by the characteristic of REDD+ institutions themselves but also by the existence of domestic reformists and the national reform agenda.

The aim of this thesis is to develop a deeper understanding and the technology in the nascent field of solid-state organic-inorganic perovskite solar cells. In recent years, perovskite materials have emerged as a low-cost, thin-film technology with efficiencies exceeding 16% challenging the quasi-paradigm that high efficiency photovoltaics must come at high costs. This thesis investigates perovskite solar cells in more detail with a focus on incorporating plasmonic nanostructures and perovskite film formation. Chapter 1 motivates the present work further followed by Chapter 2 which offers a brief background for solar cell fabrication and characterisation, perovskites in general, perovskite solar cells in specific, and plasmonics. Chapter 3 presents the field of plasmonics including simulation methods for various core-shell nanostructures such as gold-silica and silver-titania nanoparticles. The following Chapters 4 and 5 analyze plasmonic core-shell metal-dielectric nanoparticles embedded in perovskite solar cells. It is shown that using gold@silica or silver@titania NPs results in enhanced photocurrent and thus increased efficiency. After photoluminescence studies, this effect was attributed to an unexpected phenomenon in solar cells in which a lowered exciton binding energy generates a higher fraction of free charge. Embedding thermally unstable silver NPs required a low-temperature fabrication method which would not melt the Ag NPs. This work offers a new general direction for temperature sensitive elements. In Chapters 6 and 7, perovskite film formation is studied. Chapter 6 shows the existence of a previously unknown crystalline precursor state and an improved surface coverage by introducing a ramped annealing procedure. Based on this, Chapter 7 investigates different perovskite annealing protocols. The main finding was that an additional 130°C flash annealing step changed the film crystallinity dramatically and yielded a higher orientation of the perovskite crystals. The according solar cells showed an increased photocurrent attributed to a decrease in charge carrier recombination at the grain boundaries. Chapter 8 presents on-going work showing noteworthy first results for silica scaffolds, and layered, 2D perovskite structures for application in solar cells.

Can rural renewable energy projects simultaneously meet the multiple goals of sustainable development, climate change mitigation and climate change adaptation? If so, under what conditions? Rural communities throughout Latin America have increasingly suffered the impacts of climate change and few policies exist to help them adapt to these impacts. The basic infrastructure and services that they frequently lack can be provided by low carbon technologies, potentially funded by international carbon finance flows that could enable the Millennium Development Goals of economic growth and poverty alleviation to be met while minimizing carbon emissions. This research will focus on this interrelationship among development, climate change mitigation and climate change adaptation policies and practices using political ecology to analyse community renewable energy projects in rural Central America. I assess fifteen community-owned renewable energy projects in Guatemala and Nicaragua to analyse whether current renewable energy projects are achieving these goals in an integrated way. The projects were established primarily as development, emissions reductions, climate change adaptation and disaster relief. The projects are evaluated on economic, development and climate change indicators that include sustainable development, poverty alleviation, emissions reductions, and climate vulnerability. I examine how the type of common property governance, local historical and environmental background and project implementation process influence the project success in meeting multiple objectives of climate adaptation, mitigation and development. Research methods include participatory poverty assessment techniques, semi-structured interviews, stakeholder analysis, and a combination of rapid and participatory methods. The analysis of sustainable development and vulnerability used the Sustainable Livelihoods Approach methodologies and emissions reductions were calculated using standard carbon reduction methodologies. The results show that, under certain conditions, renewable energy projects can simultaneously meet these three objectives, and thus that responses to climate change can be integrated with poverty alleviation and sustainable development. Small scale hydroelectric and solar systems can reduce emissions, enable adaptation and help local livelihoods although there are numerous problems that limit the success of projects including poor design, inequitable distribution of benefits, and poorly designed governance and maintenance structures.

The December 2009 summit on climate change in Copenhagen was remarkable not because it ended in an ambitious deal to curb greenhouse gas emissions but because of the unprecedented number of journalists, delegates, NGOs and scientists present.Analysis of more than 400 articles published in two print media in 12 countries has produced a detailed analysis of the coverage of the summit across the globe, revealing that articles written principally about the science of climate change represented less than 10 per cent of all those surveyed.The study makes extensive use of official UN figures to produce the first detailed assessment of who actually attended Copenhagen. It also includes a survey of over 50 environmental journalists and scientists across the 12 target countries post-Copenhagen to ascertain how they think climate change science might be best communicated.