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Abstract Thermal energy storage (TES) systems are growing to a relevant role in solar cooling applications. Hence, high energy density is a desirable property of the TES system. Phase change materials (PCM) helps to increase this characteristic. A high temperature pilot plant able to test different types of TES systems and materials was designed and built at the University of Lleida (Spain). This pilot plant is composed mainly of three parts: heating system, cooling system, and different storage tanks. Two identical storage tanks based on the shell-and-tubes heat exchanger, one of them including 196 squared fins in the bundle of the tubes and the other without, were experimentally tested. Hydroquinone was selected as the storage material, having a latent heat of 205 kJ/kg and a phase change temperature between 168 and 173 °C. The aim of this paper is to test experimentally, and compare the average effectiveness of the TES systems analyzed using PCM for solar cooling and refrigeration applications. It was found out that for the same tank configurations (shell-and-tubes) even changing drastically the dimensions of the tank or the number and the diameter of the tubes, the average effectiveness curve proposed in the literature fits well with the results showed here.

In recent years, the portable technology is receiving a great interest and significant improvement due to the progresses in electronic technology development and energy storage solutions. The decrease in power requirements for working energy systems, due to the increased efficiency and to the reduction in components size, opens the access to new solutions for power supplying. In particular, alternative backup systems for battery charging or replacement could be designed taking advantage of unconventional technologies. It is the case of small photovoltaic portable panels or fuel cells technology: in these solutions different sources are used to produce limited electrical powers required to keep devices on. In this paper, a thermoelectric solution for the power generation has been considered: the generator has been designed and assembled starting from a catalytic combustor. Catalytic combustion allows safe control of the processes, and the choice of a hydrocarbon fuel ensures the power availability and a fast recharge. The size of the system is set to fit a volume close to the one of AA batteries. The electrical power output obtained is close to 1 W with a cold side temperature below 40 °C. The limited values of these physical parameters allow obtaining a portable and safe device. The generator has been fully characterized in different ranges of fuel flow rates and the performances have been thoroughly analysed for processes optimization and efficiency improvement.

Two studies conducted in Guadeloupe (West Indies) and Réunion (Indian Ocean) islands were designed to investigate the benefits of producing sugarcane as an energy crop and to assess the influence of agroclimatic factors on energy efficiency, respectively. In this context, it is essential to know the low heating value of the dry above-ground biomass (LHVd, MJ/kg) and its energy yield (EY, MJ/m2) in order to select the best varieties and set up a payment method for growers. Eighteen Poaceae (sugarcane and Erianthus) cultivars were compared under wet tropical environmental conditions in Guadeloupe. Three sugarcane cultivars were studied in four contrasting environments in Réunion. The partition sampling and biomass measurement procedures were identical at both locations. Low heating value (LHV) predictions were achieved using near-infrared reflectance spectroscopy (NIRS) after specific calibration (Guadeloupe), or arithmetically after lignocellulosic compound prediction (Réunion). In both studies, LHV variability was very low and slightly dependent on the site, cultivar and above-ground biomass components (millable stalks and tops, and green and dead leaves). Considering the overall dry above-ground biomass (DAB, kg/m2), the LHVd was calculated by averaging 159 samples (mean 16.65 MJ/kg) in Guadeloupe and 315 samples (mean 16.45 MJ/kg) for Réunion. An excellent linear relationship between the DAB and its EY, regardless of cultivar, age and environment, was found (n = 474 and R² = 0.99). Sugarcane energy content assessment could thus be simplified by measuring the DAB, while enabling development of a faster method of payment for growers based on the DAB measurement and the correlation between DAB and EY. Finally, the findings of this study should allow growers to rapidly determine the commercial value of their sugarcane crops, and also enable purchasers to assess the amount of recoverable energy. (Résumé d'auteur)

AbstractReview: 105 refs.

Abstract Orange Peel Waste (OPW) is a widely produced residue whose management is complicated by its physical and chemical properties. Anaerobic digestion (AD), which is commonly used for the treatment and exploitation of many biodegradable wastes, is inefficient on OPW due to the presence of essential oils (mainly d -Limonene) as well as the low pH, which cause the process to be unstable. Here we explore the effect of alkaline pre-treatment of OPW and of the addition of granular activated carbon (GAC) and Zero Valent Iron (ZVI) in improving AD in two semi-continuous reactors at a laboratory scale. The addition and pre-treatment of ZVI/GAC were shown to help process stability up to a loading of 3 kgVS·m−3·d−1 and to increase methane production even at a sub-optimal pH. The investigation of the bacterial community, by high-throughput sequencing, has also increased our insight on their involvement in AD in the presence of ZVI, including its biotic oxidation. In addition, direct interspecies electron transfer was shown to play a role in the reactor supplemented with ZVI.

Earth observation (EO) data are useful tools to analyse geomorphological processes, among which slow-moving landslides triggered by rainfall. EO data are also used to evaluate climate change and to assess its impact on geomorphological processes and geo-hydrological phenomena. The latter is the topic of the Project OT4Clima (Innovative Earth Observation technologies to study Climate Change and its impact on the environment) joined by CNR-IRPI within a consortium that includes other CNR institutes, universities and private companies. The OT4CLIMA project moves from the awareness that the impacts of climate change on the environment need to be better observed, understood, and modelled, especially at a regional scale, in order to put in place appropriate and effective risk mitigation strategies. Within the project, the CNR-IRPI group works on the development of rigorous methods and procedures for evaluating the impact of climate and its change on landslides, in particular on those characterized by a slow cinematic, at a regional scale. The test site is represented by four catchments located in the Basilicata region, southern Italy, namely the basins of the Bradano, Basento, Agri, and Sinni rivers. Long-term rainfall series gathered from 22 rain gauges located in the four catchments are analysed to evaluate the presence of temporal trends. To this aim, non-parametric and statistical tests are applied to the series. Historical landslide information is gathered from the analysis of the IFFI (Inventario dei Fenomeni Franosi in Italia) database, the Idrogeo platform (https://idrogeo.isprambiente.it/app/) and the AVI (Aree Vulnerate in Italia) catalogue. Only some types of landslide movements are considered, namely rotational-translational slides, slow slides/flows, complex movements. Moreover, Copernicus Sentinel-1 images are employed to detect the spatial and temporal distribution of slow earth surface deformations. The obtained results are used for checking the completeness of the landslide inventories. More in detail, the deformation maps of the test site are obtained by means of the application of the SBAS (Small BAseline Subset) technique to three datasets of Sentinel-1 images: t146 ascending orbit and t51 and t124 descending orbits, for the period 2015-2020. Then, a comparative analysis of rainfall data with displacement series is carried out with the aim of identifying clusters of satellite measurements with homogeneous behaviour likely correlated to variations in the rainfall regime. In particular, only the points with a mean velocity in the observation higher than 0.1 cm/year are considered to be moving. Moreover, only the displacement series of points located in areas mapped as landslides - as for the historical inventories - and sited within the influence regions of each rain gauge in the study area are analysed. A 10-km circular buffer centred in the stations are used to define the influence region of each station. The displacement series are analysed and compared to the rainfall series to search for correlations and to evaluate the effects of climate drivers on slow moving landslides.

The building and construction sector is a large contributor to anthropogenic greenhouse gas emissions and consumes vast natural resources. Improvements in this sector are of fundamental importance for national and global targets to combat climate change. In this context, vertical greenery systems (VGS) in buildings have become popular in urban areas to restore green space in cities and be an adaptation strategy for challenges such as climate change. However, only a small amount of knowledge is available on the different VGS environmental impacts. This paper discusses a comparative life cycle assessment (LCA) between a building with green walls, a building with green facades and a reference building without any greenery system in the continental Mediterranean climate. This life cycle assessment is carried according to ISO 14040/44 using ReCiPe and GWP indicators. Moreover, this study fills this gap by thoroughly tracking and quantifying all impacts in all phases of the building life cycle related to the manufacturing and construction stage, maintenance, use stage (operational energy use experimentally tested), and final disposal. The adopted functional unit is the square meter of the facade. Results showed that the operational stage had the highest impact contributing by up to 90% of the total environmental impacts during its 50 years life cycle. Moreover, when considering VGS, there is an annual reduction of about 1% in the environmental burdens. However, in summer, the reduction is almost 50%. Finally, if the use stage is excluded, the manufacturing and the maintenance stage are the most significant contributors, especially in the green wall system.

(Abstract) This paper proposes a new power line communication (PLC) architecture for monitoring and remote control of Distributed Generators (DG) and Energy Storage Systems (ESS) connected to low voltage distribution networks. The final aim is to improve the performance of the PLC link in terms of robustness and efficiency in devices addressing. The proposed solution is based on a concentrator, to be installed in secondary substation, and a new PLC bridge, to be linked both to inverters and interface protection systems of DGs or ESSs. In this way, a communication link is obtained between distribution system operator (DSO) and DG or ESS owners. The proposed system is able to provide advanced functions for the remote control of DGs and ESSs inverters, not only in terms of remote disconnection but also in terms of adjusting the inverter operating modes.

This study adopts a life cycle approach to analyse the principal critical elements, opportunities and limits of biogas production's socio-economic aspects and environmental implications. From this perspective, the biogas supply chain sustainability and the opportunity for a closed-loop approach have been assessed starting from existing studies. The analysis revealed that the biogas sector could play a strategic role in making energy systems more resilient in a context characterised by sudden changes, such as the current scenario. In particular, the research is focused on this sector's potential to support the energy transition in Italy, which presents a structural vulnerability related to fossil resource scarcity. The paper contributes to the literature on the sustainable assessment of the biogas supply chain and paves the way for future researchers to understand the complex issues involved in the biogas sector sustainable development process. Furthermore, it provides policy, managerial and social implications, showing that the complete diffusion of biogas - a renewable, scalable and flexible resource - can foster security and decarbonisation of the energy system. It can also create new business opportunities at the local level, promoting a circular and bio-based economy.

The electrodissolution of p-Ge in aqueous NaOH solutions (pH 12-13) has been investigated with steady-state and impedance techniques. In the potential region where the process is under kinetic control, the impedance patterns are characterised by a high frequency capacitive loop, associated with the space charge, largely merged with another due to charge transfer resistance and double layer capacitance, and two low frequency loops changing from inductive to capacitive upon increasing the potential. At larger potential, under mixed control, the same high frequency features are observed, while a convection diffusion impedance dominates the low frequency response. The data relevant to pure kinetic control are interpreted with a simplified kinetic model, based on the classical scheme of Beck and Gerischer [Z. Electrochem., Ber. Bunsenges. Physik. Chem. 63 (1959) 500], neglecting transport effects and assuming only three electrochemical steps: (i) oxidation, involving water molecules, of Ge(0) to dihydroxylated Ge(II) by two holes; (ii) oxidation by one hole of Ge(II)-Ge(III) in a step requiring OH-; (iii) oxidative dissolution of Ge(III) proceeding either by hole capture or electron injection, leaving behind a surface Ge(0) species. Diagrams calculated for the limiting cases of pure depletion layer control reproduce the essential features of the experimental ones.