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The fast decay in PEM fuel cells of a highly active, high performance, but unstable Fe/N/C catalyst like our NC_Ar + NH3 follows a chemical, not an electrochemical, demetallation mechanism for its ORR active FeN4 sites in the catalyst micropores.

AbstractConcrete is a valuable construction material with high mechanical strength and durability, used extensively in the construction industry. It is produced by mixing sand, stones, cement, and water in different proportions depending on the desired quality of the final product. Water reducers are additional chemical ingredients used in concrete to reduce the quantity of water required in the concrete mixture. When added to concrete, water reducers increase the workability and flowability of concrete in the freshly mixed state and improve the mechanical strength and durability of the final hardened product. This review paper describes the different types and applications of concrete water reducers used in the construction industry including their working mechanisms and fluidity effects on concrete properties. It discusses the production of synthetic and bio‐based concrete water reducers and reviews the present challenges involved in the preparation of bio‐based concrete water reducers from renewable resources. © 2023 Society of Industrial Chemistry and John Wiley & Sons Ltd.

AbstractCellulose and lignin nanoparticles are high‐value‐added products obtained from lignocellulosic biomasses through several steps of cellulose purification and lignin extraction. These steps drastically reduce the potential feedstock revenue when carried out as stand‐alone methodologies. To increase biomass yields, we describe here a strategy to design a biorefinery focused on producing cellulose and lignin nanoparticles as main products, but also aim to recover and benefit from other biomass components using only water‐based processes. Sequential pressurized liquid extractions and diluted acid and alkaline treatments were carried out to fractionate elephant grass biomass, yielding (for every 100 g of biomass): 30 g of cellulose pulp (converted to 9 g of cellulose nanocrystals and 9 g of cellulose nanofibers); 10 g of lignin (used to produce 8.5 g of stable colloidal lignin nanoparticles by probe‐sonication in water); 7.5 g of extractives (e.g. sterols and phenolics) and 23 g of xylose (converted to 4.1 g of furfural). Alternatively, to allow for the flexible use of the cellulose fraction in the proposed biorefinery, 22 g of glucose could be produced by enzymatic hydrolysis. The results demonstrate that water‐based processes are suitable for a holistic use of biomass, providing a comprehensive set of high‐value‐added co‐products that are renewable and cost‐effective chemical, cosmetic, food, polymer and pharmaceutical solutions.

Adverse socio-economic and environmental impacts of climate change on wetlands have enforced the international community and many nations to develop adaptive policies for wetland management, which require effective leadership to influence relevant stakeholders. This study identifies and prioritizes leadership functions and theories for climate change adaptation (CCA) in wetlands ecosystems, particularly in arid and semi-arid regions. A mixed qualitative-quantitative research methodology was applied through focus groups and a survey with a sample of national, sub-national, and local experts on wetlands management and climate change in Iran. The Analytic Hierarchy Processing (AHP) technique identified the political-administrative (weight = 0.245), adaptive (W = 0.244), and enabling (W = 0.237) functions for CCA, respectively, as three prioritized leadership functions, followed by the dissemination function (W = 0.102), which emphasizes the necessity of applying and enhancing leaders' social capacities, knowledge, communication skills, and personal networks to facilitate social learning and actions regarding CCA in local communities and among relevant organizations. It is necessary to overcome structural and functional barriers for leaders and their followers to information access and involvement in participatory decision-making platforms. Moreover, network and communication leadership theories (W = 0.368) and sustainable leadership perspectives (W = 0.362), respectively, have the highest priority among leadership theories and are crucial for establishing participatory decision-making among relevant stakeholders and applying adaptive strategies for wetlands governance under climate change conditions. The reconceptualization of leadership as a complex adaptive notion draws attention to the social complexities and emerging characteristics of leadership in contemporary societies and organizations. The understanding of leaders' and followers' networks and identifying the core role of leaders provides a foundation for developing leadership functions and theories beyond hierarchical, individualistic, and one-way concepts of leadership.

Abstract This work presents a numerical study on the performance of a stand-alone adsorption cooling system based on the silica gel/water couple driven by hybrid photovoltaic/thermal (PVT) collectors. This system is intended for the conservation of perishable agricultural products which require air-conditioned premises to preserve them. The weather conditions are those of North Africa (Algiers). Considering the above, this paper aims at analyzing the PVT-Adsorption system with energy storage to guarantee a stabilized production and increase the solar coverage. trnsys was used to simulate the system taking into account hourly series of irradiation and ambient temperature covering one year. The performance study reveals that the DualSun PVT hybrid collectors used provide optimal annual production and that the adsorption cooling system offers more reliable production during summer. The temperature difference between the inside and outside of the cooled enclosure balances supply and demand. The loss analysis of the storage device indicates that losses depend, on the one hand, on the interior/exterior temperature difference of the storage tank with more significant values during the summer season. On the other hand, the losses also depend on the volume of the storage tank which was optimized in order to limit the heat exchange with the surroundings.

The solar energy produced by Scheffler parabola (10 m2) is not fully exploited by the solar distillation system of aromatic and medicinal plants. In this work, the optical losses in the primary and secondary reflectors, and the thermal losses at each part of this system (solar still, steam line, condenser) were determined. A thermal energetic and exergetic analysis were also performed for a solar distillation system of rosemary leaves. For average intensity radiation of 849.1W/m2 and 6 Kg of rosemary leaves during 4 h of distillation, exergy and optical efficiencies of the system achieved up to 26.62% and 50.97%, respectively. The thermal efficiency of the solar still, steam line, and condenser is about 94.80%, 94.30%, and 87.76%, respectively. The essential oil yield per unit of consumed energy and the total efficiency of the solar distillation system, taking into account the heat losses in the solar still, steam line, and condenser, as well as the optical losses in the two reflectors, is 6.18 mL/ kWh and 40.00%, respectively. The efficiency can be as high as 42.42 % if the steam line is insulated. Moreover, the comparison between the solar steam distillation and conventional steam distillation shows that solar distillation is much more efficient since it gives better results and especially it avoids the emission of 12.10 kg of CO2 during extraction.

AbstractAutotrophs play an essential role in the cycling of carbon and nutrients, yet disease‐ecosystem relationships are often overlooked in these dynamics. Importantly, the availability of elemental nutrients like nitrogen and phosphorus impacts infectious disease in autotrophs, and disease can induce reciprocal effects on ecosystem nutrient dynamics. Relationships linking infectious disease with ecosystem nutrient dynamics are bidirectional, though the interdependence of these processes has received little attention. We introduce disease‐mediated nutrient dynamics (DND) as a framework to describe the multiple, concurrent pathways linking elemental cycles with infectious disease. We illustrate the impact of disease–ecosystem feedback loops on both disease and ecosystem nutrient dynamics using a simple mathematical model, combining approaches from classical ecological (logistic and Droop growth) and epidemiological (susceptible and infected compartments) theory. Our model incorporates the effects of nutrient availability on the growth rates of susceptible and infected autotroph hosts and tracks the return of nutrients to the environment following host death. While focused on autotroph hosts here, the DND framework is generalizable to higher trophic levels. Our results illustrate the surprisingly complex dynamics of host populations, infection patterns, and ecosystem nutrient cycling that can arise from even a relatively simple feedback between disease and nutrients. Feedback loops in disease‐mediated nutrient dynamics arise via effects of infection and nutrient supply on host stoichiometry and population size. Our model illustrates how host growth rate, defense, and tissue chemistry can impact the dynamics of disease–ecosystem relationships. We use the model to motivate a review of empirical examples from autotroph–pathogen systems in aquatic and terrestrial environments, demonstrating the key role of nutrient–disease and disease–nutrient relationships in real systems. By assessing existing evidence and uncovering data gaps and apparent mismatches between model predictions and the dynamics of empirical systems, we highlight priorities for future research intended to narrow the persistent disciplinary gap between disease and ecosystem ecology. Future empirical and theoretical work explicitly examining the dynamic linkages between disease and ecosystem ecology will inform fundamental understanding for each discipline and will better position the field of ecology to predict the dynamics of disease and elemental cycles in the context of global change.