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Sustainability of agro-food supply chains has recently become the subject of greater interest from consumers, firms, governmental organizations and academia as the environment continues to deteriorate. One of the most critical factors influencing the sustainability of an agro-food supply chain is its network design. A particularly challenging aspect in this context is the broad range of influencing indicators associated with the Triple Bottom Line (TBL) of sustainability that need to be considered. However, many of these indicators could not be fully integrated or measured by single-step optimization problems. This paper presents a critical literature review of operational research methods for the design of sustainable supply chains. A novel two-stage hybrid solution methodology is proposed. In the first stage, a partner selection is performed using a hybrid multi criteria decision making based on Analytic Hierarchy Process (AHP) method and the Ordered Weighted Averaging (OWA) aggregation method. The result obtained in the first stage is used in the second stage to develop a multi-objective mathematical model to optimize the design of the supply chain network. This approach allows the simultaneous consideration of all three dimensions of sustainability including carbon footprint, water footprint, number of jobs created and the total cost of the supply chain design. The proposed approach generates a Pareto frontier to aid users in making decisions. Numerical experiments are completed utilizing data from an agro-food company to demonstrate the efficiency and effectiveness of the proposed solution methodology. The analyzes of the numerical results provide important organizational, practical and policy insights on (1) the impact of financial and environmental sustainability on supply chain network design (2) the tradeoff analysis between environmental emission, water footprint, societal implications and associated cost for making informed decision on supply chain investment.

Abstract An international workshop was held in Richland, Washington, United States of America, in October, 1980 to discuss progress on development of the acid digestion process for treating combustible nuclear waste. The workshop was attended by participants from nine member countries of the Nuclear Energy Agency of the Organization for Economic Cooperation and Development (OECD/NEA). The status of the acid digestion development programs of various countries is discussed in this paper. The acid digestion process has been developed and demonstrated on an engineering scale in several countries and appears to be especially applicable to treatment of combustible wastes containing high levels of transuranic contamination, where there is potential for recovering the transuranic radionuclides. Because the process takes place at a relatively low temperature, the plutonium contained in the residue is in a form that can be readily recovered using standard leaching techniques. The process is adaptable to a wide variety of combustible wastes, such as cellulosics, plastics, rubber materials, and ion exchange resin. While the process has been developed and demonstrated on an engineering scale primarily for transuranic contaminated wastes, the process is also adaptable to beta-gamma wastes such as reactor ion exchange resins.

Biomethane is a flexible energy vector that can be used as a renewable fuel for both the heat and transport sectors. Recent EU legislation encourages the production and use of advanced, third generation biofuels with improved sustainability for future energy systems. The integration of technologies such as anaerobic digestion, gasification, and power to gas, along with advanced feedstocks such as algae will be at the forefront in meeting future sustainability criteria and achieving a green gas supply for the gas grid. This paper explores the relevant pathways in which an integrated biomethane industry could potentially materialise and identifies and discusses the latest biotechnological advances in the production of renewable gas. Three scenarios of cascading biomethane systems are developed.

Abstract During successive industrial revolutions, the objective has not only been for industry to improve and satisfy its direct needs, it has also been to improve society’s standard of living and make life easier for the consumer. Therefore, economic growth should always go hand in hand with each industrial revolution. The medical industry, energy conservation and, in particular, production technologies will be transformed through new value chain models. Globalization, urbanization, demographic change and energy transformation are the transforming forces estimating the technological impetus for a better identification of solutions for a world on the move. In recent years, successive revolutions have made remarkable contributions to a person’s quality of life, safety, industrial economy, comfort and health. This work aims at improving the energy consumption of buildings. To achieve this goal, we have created a Digital Twin that accurately reflects the behavior and characteristics of a future or existing building. To reproduce a copy of the future or existing building, we chose to use the Autodesk REVIT solution to meet several constraints. These have a significant influence on the energy behavior of the building.

Two studies conducted in Guadeloupe (West Indies) and Réunion (Indian Ocean) islands were designed to investigate the benefits of producing sugarcane as an energy crop and to assess the influence of agroclimatic factors on energy efficiency, respectively. In this context, it is essential to know the low heating value of the dry above-ground biomass (LHVd, MJ/kg) and its energy yield (EY, MJ/m2) in order to select the best varieties and set up a payment method for growers. Eighteen Poaceae (sugarcane and Erianthus) cultivars were compared under wet tropical environmental conditions in Guadeloupe. Three sugarcane cultivars were studied in four contrasting environments in Réunion. The partition sampling and biomass measurement procedures were identical at both locations. Low heating value (LHV) predictions were achieved using near-infrared reflectance spectroscopy (NIRS) after specific calibration (Guadeloupe), or arithmetically after lignocellulosic compound prediction (Réunion). In both studies, LHV variability was very low and slightly dependent on the site, cultivar and above-ground biomass components (millable stalks and tops, and green and dead leaves). Considering the overall dry above-ground biomass (DAB, kg/m2), the LHVd was calculated by averaging 159 samples (mean 16.65 MJ/kg) in Guadeloupe and 315 samples (mean 16.45 MJ/kg) for Réunion. An excellent linear relationship between the DAB and its EY, regardless of cultivar, age and environment, was found (n = 474 and R² = 0.99). Sugarcane energy content assessment could thus be simplified by measuring the DAB, while enabling development of a faster method of payment for growers based on the DAB measurement and the correlation between DAB and EY. Finally, the findings of this study should allow growers to rapidly determine the commercial value of their sugarcane crops, and also enable purchasers to assess the amount of recoverable energy. (Résumé d'auteur)

Heavy metal emission is a great environmental concern for the development of municipal solid waste (MSW) thermal treatment techniques. In this study, both experimental investigations and theoretical simulations are carried out to identify the partitioning of heavy metals between the gaseous phase and solid fractions during pyrolysis, gasification, and incineration of simulated MSW. Two types of incinerators are used. A tubular furnace is applied to evaluate the evaporation of metals from residues, whereas the metal distribution among bottom ash, cyclone fly ash, and filter fly ash is further examined in a fluidized bed. Six target metals (Cd, Pb, Zn, Cu, Cr, and Ni) are studied. Results show that a reductive atmosphere favors the evaporation of Cd and Zn but refrains Cu, Ni, and Cr volatilization, because metals are mainly reduced to their elemental form or sulfide, according to thermodynamic equilibrium calculation. Oxides are the dominant species under oxidizing condition due to the abundance of alkalis...

Abstract Purpose Investigating potential social and socio-economic impacts should play a key role for the development of sustainable mobility alternatives. Social life cycle assessment (S-LCA) is becoming increasingly important to ensure holistic sustainability assessments. The present work aims at identifying and evaluating social and socio-economic impact subcategories in S-LCA. A novel participatory approach implying all concerned stakeholders is proposed to select relevant impact subcategories and thus contribute to a thorough interpretation of S-LCA results. It is applied to assess electric and conventional vehicles. Methodology This paper describes a comprehensive step-by-step S-LCA framework. The innovation of this work consists in defining a structured S-LCA framework integrating a systematic approach based on two stages: (1) a sectorial risk analysis for the identification of impact subcategories and (2) a participatory approach for their prioritization. The proposed participatory approach considers all concerned stakeholders to enable the selection of the most relevant impact subcategories. A set of social inventory indicators is attributed to subcategories that were perceived as the most relevant. These are used to perform the social evaluation and carry out a full analysis in the result interpretation allowing thus to integrate a multi-actor perspective to the materiality assessment. Results The defined S-LCA framework is implemented to compare two mobility scenarios, corresponding to electric and conventional vehicle technologies. A new set of mobility-related impact subcategories is proposed for users’ stakeholder. Following the new designed participatory approach, subcategories for all stakeholders are prioritized according to different actors’ perceptions. For example, “safe and healthy living conditions,” “local employment,” and “delocalization and migration” were perceived for local communities as the most relevant subcategories by the different consulted stakeholders (industrial, academic, and public actors and users). These results also showed that social significance varies depending on the consulted actors and on the geographical area of the study. Using PSILCA database, we have investigated the subcategories that were perceived as the most relevant. Results for the evaluation and interpretation phases are presented for both transportation technologies. Conclusions This approach aims at increasing local relevance of S-LCA results and their representativeness. Results for the considered mobility scenarios have demonstrated the need to extend the scope of the materiality assessment, generally used for determining subcategories’ social significance from a single stakeholder perspective, by involving other stakeholders into the prioritization stage. Moreover, the proposed comprehensive S-LCA framework integrating the participatory approach is general enough to be applied to other product systems and sectors.

Abstract Biogas is a valuable renewable energy that can be used as a fuel or as raw material for the production of hydrogen, synthesis gas and chemicals. Apart from its main constituent of CH 4 and CO 2 , it also contained various undesirable contaminants. The removal of these contaminants such as H 2 S will significantly improve the quality of the biogas for further use. This work involved the valorization of calcium carbonate (CaCO 3 )-based solid wastes for the removal of H 2 S from the biogas stream. The solid wastes were analyzed by different physicochemical methods CaCO 3 was found as the main component of both solid wastes, while trace amounts of other elements such as Mg, Al, etc. were also present. The solid wastes were dispersed in water and the resulted suspensions were tested for the removal of H 2 S from the gas phase, using a triphasic gas/liquid/solid glass reactor at room temperature and pressure. A commercial activated carbon (AC) and a pure commercial calcite were also used for comparison purpose. In addition, mixtures of AC with CaCO 3 waste in different ratios were also tested. The influence of the matrix of gas (air or biogas) on the removal of H 2 S was evaluated. Both solid wastes showed higher performance compared to the pure commercial calcite for H 2 S removal. The coupling of a CaCO 3 waste and AC allowed improving the sorption performance compared to pure commercial CaCO 3 and AC used alone. The results obtained open a new promising way for the valorization of CaCO 3 -based wastes for H 2 S removal from biogas.