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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Ayman Nafady; Rong-Lin Zhong; Jing-Mei Xu; Shun-Li Li; +10 Authors
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    Article . 2021 . Peer-reviewed
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      Article . 2021 . Peer-reviewed
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    Authors: Milchberg, H.; Skinner, C. H.; Suckewer, S.; Voorhees, D.;

    A CO/sub 2/ laser (approx.0.5 kJ energy, 70 nsec pulse width) was focussed onto the end of an axially oriented, thick (35 to 350 .mu.) carbon fiber with or without a magnetic field present along the laser-fiber axis. We present evidence for axial-to-transverse enhancement of the CVI 182A (n = 3 .-->. 2) transition, which is correlated with the appearance of a population inversion between levels n = 3 and 2. For the B = 0 kG, zero field case, the maximum gain-length product of kl approx. =3 (k approx. =6 cm/sup -1/) was measured for a carbon fiber coated with a thin layer of aluminum (for additional radiation cooling). The results are interpreted in terms of fast recombination due mostly to thermal conduction from the plasma to the cold fiber core.

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    Authors: Xiong, Wei; Kalyuzhnaya, Marina G.; Henard, Calvin;

    This article is an editorial on the research topic Microbial C1 Metabolism and Biotechnology. This special topic presents studies focused on the fundamental aspects of C1 metabolism in diverse microbial systems with the ability to convert anthropogenic greenhouse gases into valuable products.

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    Frontiers in Microbiology
    Article . 2021 . Peer-reviewed
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    Frontiers in Microbiology
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    Frontiers in Microbiology
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      Frontiers in Microbiology
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    Authors: Jiahong Chen; Ali Farajtabar; Abolghasem Jouyban; William E. Acree; +1 Authors

    By means of the saturation shake-flask technique, the saturation solubility data of 3,3′-diaminodiphenyl sulfone in 14 monosolvents (n-propanol, N,N-dimethylformamide, methanol, ethanol, ethylene g...

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    Journal of Chemical & Engineering Data
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    Authors: Ting-zhen Ming; Ting-zhen Ming; Yong-X. Tao; Zhong-Ren Peng; +3 Authors

    Abstract Urban renewal has become a key issue all through China's Transitional Period. The social, economic, political factors, and their correlations have been seriously considered. However, the effects of outdoor pedestrian thermal comfort and fluid ventilation effects as well as the residence living conditions in old city districts under urban reconstruction should, to some extent, be paid closer attention to. As an example, take an old city district in Wuhan where a comprehensive mathematical model describing the fluid flow and heat transfer characteristics has been presented. Considering the influences of ambient crosswind, solar radiation, and natural convection and radiation heat transfer, numerical analysis based on the original layout has been executed. By analyzing the temperature and velocity distributions of the old city district, a new planned layout has been presented in this research. By comparison, some basic rules have been advanced to achieve favorable thermal comfort and flow ventilation effects.

    image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Energy and Buildingsarrow_drop_down
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    Energy and Buildings
    Article . 2015 . Peer-reviewed
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      Energy and Buildings
      Article . 2015 . Peer-reviewed
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    Authors: Salmeron, Miquel; Schlogl, Robert;

    Progress in science often follows or parallels the development of new techniques. The optical microscope helped convert medicine and biology from a speculative activity in old times to today's sophisticated scientific disciplines. The telescope changed the study and interpretation of heavens from mythology to science. X-ray diffraction enabled the flourishing of solid state physics and materials science. The technique object of this review, Ambient Pressure Photoelectron Spectroscopy or APPES for short, has also the potential of producing dramatic changes in the study of liquid and solid surfaces, particularly in areas such as atmospheric, environment and catalysis sciences. APPES adds an important missing element to the host of techniques that give fundamental information, i.e., spectroscopy and microscopy, about surfaces in the presence of gases and vapors, as encountered in industrial catalysis and atmospheric environments. APPES brings electron spectroscopy into the realm of techniques that can be used in practical environments. Decades of surface science in ultra high vacuum (UHV) has shown the power of electron spectroscopy in its various manifestations. Their unique property is the extremely short elastic mean free path of electrons as they travel through condensed matter, of the order of a few atomic distances in the energy rangemore » from a few eV to a few thousand eV. As a consequence of this the information obtained by analyzing electrons emitted or scattered from a surface refers to the top first few atomic layers, which is what surface science is all about. Low energy electron diffraction (LEED), Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS), Ultraviolet photoelectron spectroscopy (UPS), and other such techniques have been used for decades and provided some of the most fundamental knowledge about surface crystallography, composition and electronic structure available today. Unfortunately the high interaction cross section of electrons with matter also prevents them from traveling long distances unscattered in gas environments. Above the millibar pressure range this distance is reduced to less that a millimeter, effectively preventing its use in the most relevant environments, usually between millibars and atmospheric pressures. There is therefore a large gap of several orders of magnitude where information about surfaces is scarce because these powerful electron spectroscopies cannot operate. One characteristic of surfaces in ambient pressure environments is that they are covered by dense layers of molecules, even when their binding energy is weak. Water for example is known to form layers several molecules thick at room temperature in humid environments. Metals readily form oxide films several layers thick in oxygen atmospheres. Dense layers of adsorbed molecules can also be produced in ultra high vacuum, often by the simple and expedient method of cooling the sample to cryogenic temperatures. A large amount of data has been obtained in the past in UHV by surface scientists using this method. While this has provided valuable information it begs the question of whether the structures formed in this manner represent equilibrium structures or metastable ones, kinetically trapped due to high activation energies that cannot be overcome at low temperature. From a thermodynamic point of view is interesting to consider the entropic contribution to the Gibbs free energy, which we can call 'the pressure factor', equal to kT.logP. This factor amounts to a sizeable 0.3 eV difference at room temperature between UHV (<10{sup -8} Pascal) and atmospheric pressures. Such change if free energy can definitely result in changes in surface structure and stability. Entire areas of the phase diagram are out of reach due to the pressure gap. Even when cooling is not necessary, many surface treatments and most chemical reactions necessitate the presence of gases at pressures ranging from millibar to bars. What is the structure and chemical nature of the species formed on the surface in equilibrium with such gases? As we shall illustrate in this review, APPES provides a much needed electron spectroscopy to analyze surface electronic structure and composition in equilibrium with gases.« less

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    Surface Science Reports
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      Surface Science Reports
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    Authors: Amundson, S. A.; Chen, D. J.;

    We have observed significant differences in the response to ionizing radiation of two closely related human cells lines, and now compare the effects on these lines of both low and intermediate LET radiation. Compared to TK6, WTK1 has an enhanced X-ray survival, and is also more resistant to cell killing by alpha-particles. The hprt locus is more mutable in WTK1 than in TK6 by both X-rays and alpha-particles. WTK1 is also more mutable by alpha-particles than by X-rays at the hprt locus. X-ray-induced mutation at the heterozygous tk locus in WTK1 is about 25 fold higher than in TK6, while alpha-particle-induced mutation is nearly 50 fold higher at this locus. Also, the slowly growing tk- mutants, which comprise the majority of spontaneous and X-ray-induced tk- mutants of TK6, were not induced significantly by alpha-particles. Previously, we showed that TK6 has a reduced capacity for recombination compared with WTK1, and therefore, these results indicate that recombinational repair may contribute to both cell survival and mutation-induction following exposure to ionizing radiation. Such a mechanism may aid cell survival, but could also result in increased deleterious effects such as the unmasking of recessive mutations in cancer suppresser genes.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Advances in Space Re...arrow_drop_down
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    Advances in Space Research
    Article . 1996 . Peer-reviewed
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      Advances in Space Research
      Article . 1996 . Peer-reviewed
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Vay, J. L.; Adam, J. C.; Heron, A.;

    We present an extension of the B erenger Perfectly Matched Layer with additional terms and tunable coecien ts which introduce some asymmetry in the absorption rate. We show that the discretized version of the new PML oers superior absorption rates than the discretized standard PML under a plane wave analysis. Taking advantage of the high rates of absorption of the new PML, we have devised a new strategy for introducing the technique of Mesh Renemen t into electromagnetic Particle-In-Cell plasma simulations. We present the details of the algorithm as well as a 2-D example of its application to laser-plasma interaction in the context of fast ignition.

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    Computer Physics Communications
    Article . 2004 . Peer-reviewed
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      Computer Physics Communications
      Article . 2004 . Peer-reviewed
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Nieman, C.; Tauschwitz, A.; Penache, D.; Neff, S.; +6 Authors

    High current discharge channels can neutralize both current and space charge of very intense ion beams. Therefore, they are considered an interesting solution for final focus and beam transport in a heavy ion beam fusion reactor. At the Gesellschaft fuer Schwerionenforschung accelerator facility, 50 cm long, free-standing discharge channels were created in a 60 cm diameter metallic chamber. Discharges with currents of 45 kA in 2 to 25 mbar ammonia (NH3) gas are initiated by a CO2 laser pulse along the channel axis before the capacitor bank is triggered. Resonant absorption of the laser, tuned to the v2 vibration of the ammonia molecule, causes strong gas heating. Subsequent expansion and rarefaction of the gas prepare the conditions for a stable discharge to fulfill the requirements for ion beam transport. The influence of an electric prepulse on the high current discharge was investigated. This article describes the laser–gas interaction and the discharge initiation mechanism. We found that channels are magnetohydrodynamic stable up to currents of 45 kA, measured by fast shutter and streak imaging techniques. The rarefaction of the laser heated gas is studied by means of a one-dimensional Lagrangian fluid code (CYCLOPS) and is identified as the dominant initiation mechanism of the discharge.

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    Journal of Applied Physics
    Article . 2002 . Peer-reviewed
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      Journal of Applied Physics
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    Authors: Yu Song; Hamid Hashemi; Jakob Munkholt Christensen; Chun Zou; +2 Authors

    Abstract Ammonia oxidation experiments were conducted at high pressure (30 bar and 100 bar) under oxidizing and stoichiometric conditions, respectively, and temperatures ranging from 450 to 925 K. The oxidation of ammonia was slow under stoichiometric conditions in the temperature range investigated. Under oxidizing conditions the onset temperature for reaction was 850–875 K at 30 bar, while at 100 bar it was about 800 K, with complete consumption of NH3 at 875 K. The products of reaction were N2 and N2O, while NO and NO2 concentrations were below the detection limit even under oxidizing conditions. The data were interpreted in terms of a detailed chemical kinetic model. The rate constant for the reaction of the important intermediate H2NO with O2 was determined from ab initio calculations to be 2.3 × 102 T2.994 exp(−9510 K/T) cm3 mol−1 s−1. The agreement between experimental results and model work was satisfactory. The main oxidation path for NH3 at high pressure under oxidizing conditions is NH3 ⟶ + OH NH2 ⟶ + HO 2 , NO 2 H2NO ⟶ + O 2 HNO ⟶ + O 2 NO ⟶ + NH 2 N2. The modeling predictions are most sensitive to the reactions NH2 + NO = NNH + OH and NH2 + HO2 = H2NO + OH, which promote the ammonia consumption by forming OH radicals, and to NH2 + NO = N2 + H2O and NH2 + NO2 = N2O + H2O, which are the main chain-terminating steps.

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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Ayman Nafady; Rong-Lin Zhong; Jing-Mei Xu; Shun-Li Li; +10 Authors
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    Article . 2021 . Peer-reviewed
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      Article . 2021 . Peer-reviewed
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Milchberg, H.; Skinner, C. H.; Suckewer, S.; Voorhees, D.;

    A CO/sub 2/ laser (approx.0.5 kJ energy, 70 nsec pulse width) was focussed onto the end of an axially oriented, thick (35 to 350 .mu.) carbon fiber with or without a magnetic field present along the laser-fiber axis. We present evidence for axial-to-transverse enhancement of the CVI 182A (n = 3 .-->. 2) transition, which is correlated with the appearance of a population inversion between levels n = 3 and 2. For the B = 0 kG, zero field case, the maximum gain-length product of kl approx. =3 (k approx. =6 cm/sup -1/) was measured for a carbon fiber coated with a thin layer of aluminum (for additional radiation cooling). The results are interpreted in terms of fast recombination due mostly to thermal conduction from the plasma to the cold fiber core.

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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Xiong, Wei; Kalyuzhnaya, Marina G.; Henard, Calvin;

    This article is an editorial on the research topic Microbial C1 Metabolism and Biotechnology. This special topic presents studies focused on the fundamental aspects of C1 metabolism in diverse microbial systems with the ability to convert anthropogenic greenhouse gases into valuable products.

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    Frontiers in Microbiology
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    Authors: Jiahong Chen; Ali Farajtabar; Abolghasem Jouyban; William E. Acree; +1 Authors

    By means of the saturation shake-flask technique, the saturation solubility data of 3,3′-diaminodiphenyl sulfone in 14 monosolvents (n-propanol, N,N-dimethylformamide, methanol, ethanol, ethylene g...

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    Journal of Chemical & Engineering Data
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    Authors: Ting-zhen Ming; Ting-zhen Ming; Yong-X. Tao; Zhong-Ren Peng; +3 Authors

    Abstract Urban renewal has become a key issue all through China's Transitional Period. The social, economic, political factors, and their correlations have been seriously considered. However, the effects of outdoor pedestrian thermal comfort and fluid ventilation effects as well as the residence living conditions in old city districts under urban reconstruction should, to some extent, be paid closer attention to. As an example, take an old city district in Wuhan where a comprehensive mathematical model describing the fluid flow and heat transfer characteristics has been presented. Considering the influences of ambient crosswind, solar radiation, and natural convection and radiation heat transfer, numerical analysis based on the original layout has been executed. By analyzing the temperature and velocity distributions of the old city district, a new planned layout has been presented in this research. By comparison, some basic rules have been advanced to achieve favorable thermal comfort and flow ventilation effects.

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    Energy and Buildings
    Article . 2015 . Peer-reviewed
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      Energy and Buildings
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    Authors: Salmeron, Miquel; Schlogl, Robert;

    Progress in science often follows or parallels the development of new techniques. The optical microscope helped convert medicine and biology from a speculative activity in old times to today's sophisticated scientific disciplines. The telescope changed the study and interpretation of heavens from mythology to science. X-ray diffraction enabled the flourishing of solid state physics and materials science. The technique object of this review, Ambient Pressure Photoelectron Spectroscopy or APPES for short, has also the potential of producing dramatic changes in the study of liquid and solid surfaces, particularly in areas such as atmospheric, environment and catalysis sciences. APPES adds an important missing element to the host of techniques that give fundamental information, i.e., spectroscopy and microscopy, about surfaces in the presence of gases and vapors, as encountered in industrial catalysis and atmospheric environments. APPES brings electron spectroscopy into the realm of techniques that can be used in practical environments. Decades of surface science in ultra high vacuum (UHV) has shown the power of electron spectroscopy in its various manifestations. Their unique property is the extremely short elastic mean free path of electrons as they travel through condensed matter, of the order of a few atomic distances in the energy rangemore » from a few eV to a few thousand eV. As a consequence of this the information obtained by analyzing electrons emitted or scattered from a surface refers to the top first few atomic layers, which is what surface science is all about. Low energy electron diffraction (LEED), Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS), Ultraviolet photoelectron spectroscopy (UPS), and other such techniques have been used for decades and provided some of the most fundamental knowledge about surface crystallography, composition and electronic structure available today. Unfortunately the high interaction cross section of electrons with matter also prevents them from traveling long distances unscattered in gas environments. Above the millibar pressure range this distance is reduced to less that a millimeter, effectively preventing its use in the most relevant environments, usually between millibars and atmospheric pressures. There is therefore a large gap of several orders of magnitude where information about surfaces is scarce because these powerful electron spectroscopies cannot operate. One characteristic of surfaces in ambient pressure environments is that they are covered by dense layers of molecules, even when their binding energy is weak. Water for example is known to form layers several molecules thick at room temperature in humid environments. Metals readily form oxide films several layers thick in oxygen atmospheres. Dense layers of adsorbed molecules can also be produced in ultra high vacuum, often by the simple and expedient method of cooling the sample to cryogenic temperatures. A large amount of data has been obtained in the past in UHV by surface scientists using this method. While this has provided valuable information it begs the question of whether the structures formed in this manner represent equilibrium structures or metastable ones, kinetically trapped due to high activation energies that cannot be overcome at low temperature. From a thermodynamic point of view is interesting to consider the entropic contribution to the Gibbs free energy, which we can call 'the pressure factor', equal to kT.logP. This factor amounts to a sizeable 0.3 eV difference at room temperature between UHV (<10{sup -8} Pascal) and atmospheric pressures. Such change if free energy can definitely result in changes in surface structure and stability. Entire areas of the phase diagram are out of reach due to the pressure gap. Even when cooling is not necessary, many surface treatments and most chemical reactions necessitate the presence of gases at pressures ranging from millibar to bars. What is the structure and chemical nature of the species formed on the surface in equilibrium with such gases? As we shall illustrate in this review, APPES provides a much needed electron spectroscopy to analyze surface electronic structure and composition in equilibrium with gases.« less

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    Surface Science Reports
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      Surface Science Reports
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    Authors: Amundson, S. A.; Chen, D. J.;

    We have observed significant differences in the response to ionizing radiation of two closely related human cells lines, and now compare the effects on these lines of both low and intermediate LET radiation. Compared to TK6, WTK1 has an enhanced X-ray survival, and is also more resistant to cell killing by alpha-particles. The hprt locus is more mutable in WTK1 than in TK6 by both X-rays and alpha-particles. WTK1 is also more mutable by alpha-particles than by X-rays at the hprt locus. X-ray-induced mutation at the heterozygous tk locus in WTK1 is about 25 fold higher than in TK6, while alpha-particle-induced mutation is nearly 50 fold higher at this locus. Also, the slowly growing tk- mutants, which comprise the majority of spontaneous and X-ray-induced tk- mutants of TK6, were not induced significantly by alpha-particles. Previously, we showed that TK6 has a reduced capacity for recombination compared with WTK1, and therefore, these results indicate that recombinational repair may contribute to both cell survival and mutation-induction following exposure to ionizing radiation. Such a mechanism may aid cell survival, but could also result in increased deleterious effects such as the unmasking of recessive mutations in cancer suppresser genes.

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    Advances in Space Research
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      Advances in Space Research
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    Authors: Vay, J. L.; Adam, J. C.; Heron, A.;

    We present an extension of the B erenger Perfectly Matched Layer with additional terms and tunable coecien ts which introduce some asymmetry in the absorption rate. We show that the discretized version of the new PML oers superior absorption rates than the discretized standard PML under a plane wave analysis. Taking advantage of the high rates of absorption of the new PML, we have devised a new strategy for introducing the technique of Mesh Renemen t into electromagnetic Particle-In-Cell plasma simulations. We present the details of the algorithm as well as a 2-D example of its application to laser-plasma interaction in the context of fast ignition.

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    Computer Physics Communications
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      Computer Physics Communications
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    Authors: Nieman, C.; Tauschwitz, A.; Penache, D.; Neff, S.; +6 Authors

    High current discharge channels can neutralize both current and space charge of very intense ion beams. Therefore, they are considered an interesting solution for final focus and beam transport in a heavy ion beam fusion reactor. At the Gesellschaft fuer Schwerionenforschung accelerator facility, 50 cm long, free-standing discharge channels were created in a 60 cm diameter metallic chamber. Discharges with currents of 45 kA in 2 to 25 mbar ammonia (NH3) gas are initiated by a CO2 laser pulse along the channel axis before the capacitor bank is triggered. Resonant absorption of the laser, tuned to the v2 vibration of the ammonia molecule, causes strong gas heating. Subsequent expansion and rarefaction of the gas prepare the conditions for a stable discharge to fulfill the requirements for ion beam transport. The influence of an electric prepulse on the high current discharge was investigated. This article describes the laser–gas interaction and the discharge initiation mechanism. We found that channels are magnetohydrodynamic stable up to currents of 45 kA, measured by fast shutter and streak imaging techniques. The rarefaction of the laser heated gas is studied by means of a one-dimensional Lagrangian fluid code (CYCLOPS) and is identified as the dominant initiation mechanism of the discharge.

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    Authors: Yu Song; Hamid Hashemi; Jakob Munkholt Christensen; Chun Zou; +2 Authors

    Abstract Ammonia oxidation experiments were conducted at high pressure (30 bar and 100 bar) under oxidizing and stoichiometric conditions, respectively, and temperatures ranging from 450 to 925 K. The oxidation of ammonia was slow under stoichiometric conditions in the temperature range investigated. Under oxidizing conditions the onset temperature for reaction was 850–875 K at 30 bar, while at 100 bar it was about 800 K, with complete consumption of NH3 at 875 K. The products of reaction were N2 and N2O, while NO and NO2 concentrations were below the detection limit even under oxidizing conditions. The data were interpreted in terms of a detailed chemical kinetic model. The rate constant for the reaction of the important intermediate H2NO with O2 was determined from ab initio calculations to be 2.3 × 102 T2.994 exp(−9510 K/T) cm3 mol−1 s−1. The agreement between experimental results and model work was satisfactory. The main oxidation path for NH3 at high pressure under oxidizing conditions is NH3 ⟶ + OH NH2 ⟶ + HO 2 , NO 2 H2NO ⟶ + O 2 HNO ⟶ + O 2 NO ⟶ + NH 2 N2. The modeling predictions are most sensitive to the reactions NH2 + NO = NNH + OH and NH2 + HO2 = H2NO + OH, which promote the ammonia consumption by forming OH radicals, and to NH2 + NO = N2 + H2O and NH2 + NO2 = N2O + H2O, which are the main chain-terminating steps.

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