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Abstract In this work, we intend to solve the equations governing two laminar isothermal or non-isothermal coaxial plane jets with variable density in an ambient fluid at rest in order to study the initial conditions influence (i.e. the nozzles ejection conditions) on the jet characteristic parameters. A finite difference method is developed to solve the dimensionless Navier–Stokes and energy equations resulting from some assumptions. The discussion about the results relates primarily to the concentration core length according to the nozzles thicknesses ratios. The influences of the gas velocity and temperature resulting from the external nozzle are also examined. This made it possible to deduce correlations of practical use between these parameters in order to apply them in engineering processes.

AbstractSome cases of occurrence of matrix effects (mostly ion suppression) in protein‐precipitated plasma samples, and their influence on the validity of plasma concentrations and pharmacokinetic parameters, are discussed. The comparison of matrix effects using either electrospray (TurboIonspray, TISP) or atmospheric pressure chemical ionization (APCI) indicated that APCI is less prone to matrix effects. Nevertheless, TISP is usually the first choice of ionization technique since unknown thermally labile metabolites might be present in the plasma samples causing erroneous results. A high impact of ion suppression on the plasma concentrations after intravenous (i.v.) administration was found, depending on the drug formulation (vehicle). Since ion suppression caused significantly lower plasma concentrations (by a factor of up to 5.5) after i.v. dosing, the area under the curve (AUC) was underestimated and the plasma clearance was consequently erroneously high, with an impact on drug candidate selection. By simple stepwise dilution (e.g. 10‐fold and 50‐fold) of the supernatant of protein‐precipitated plasma samples, including all calibration and quality control samples, the matrix effects were recognized and eliminated. Copyright © 2003 John Wiley & Sons, Ltd.

Endocrinological research on wild animals inhabiting remote areas has been hampered by the need to store plasma samples at subzero temperatures. In an attempt to remedy this logistical issue, we here investigate the use of ethanol as an alternative to freezing for the preservation of steroid and indoleamine hormones in avian plasma. Known quantities of the steroids 5alpha-dihydrotestosterone (DHT), testosterone, 17beta-estradiol, corticosterone, and the indoleamine melatonin were added to a stripped pool of chicken plasma. Samples were either immediately frozen at -40 degrees C, or treated with pure ethanol. Ethanol-treated samples were either immediately frozen, or-to simulate storage conditions at various field locations-left sitting at room temperature for one to two months, or incubated at 36 degrees C for one month before all treatment groups were frozen at -40 degrees C. All samples were then analyzed by radioimmunoassay. For DHT and estradiol there were no differences among treatment groups suggesting that ethanol-treatment is as effective as immediate freezing in preserving plasma steroid concentrations. For testosterone, corticosterone and melatonin ethanol-treated samples differed significantly from immediately frozen samples suggesting that caution is needed when comparing absolute concentrations of hormones between samples preserved in different ways. However, differences among ethanol-treated samples in general were small, demonstrating the feasibility of this preservation method in the field at remote locations.

Abstract Amorphous and microcrystalline silicon single layers and p–i–n solar cells were produced dynamically using an inline deposition system called “line source”. A highly uniform deposition of thin-film silicon layers with layer-thickness variations of less than ±5% was achieved. Amorphous and microcrystalline silicon single junction solar cells were dynamically fabricated with initial efficiencies of 8.3% and 6.3%, respectively. The dynamic deposition rate of these solar cells is 6.75 nm m/min in case of a-Si:H and 3.3 nm m/min for μc-Si:H. In this work it will be shown that an enhancement of the deposition rate up to 15.6 nm m/min during the i-layer deposition of a-Si:H solar cells has only a weak negative influence on the initial efficiencies of the cells. Further on, the effect of substrate velocity on solar cell characteristics of a-Si:H solar cells is investigated. Finally, a productivity estimation of the line source concept is presented.

Abstract Solutions containing hydrofluoric acid (HF), hydrochloric acid (HCl), and hydrogen peroxide (H2O2) were investigated as novel acidic, NOx-free etching mixtures for texturing of monocrystalline silicon wafers. High etch rates of up to 13.3 nm s−1 were observed at room temperature, which are comparable to the etch rates of KOH-IPA solutions. The silicon surface was investigated by scanning electron microscopy (SEM) and confocal laser scanning microscopy (CLSM), indicating pyramidal textures for diamond wire and SiC-slurry sawn as well as saw-damage etched (polished) wafers. Non-stirred baths generate random pyramidal structures while constantly stirred solutions generate novel random inverted pyramidal surface structures. The light trapping efficiency of wafers etched by the HF-HCl-H2O2 solutions was compared by UV/vis-reflectivity measurements to KOH/i-propanol specimens indicating lower reflectivities for the HF-HCl-H2O2-treated samples. Using the ‘wafer ray tracer’ (pvlighthouse.com) the light absorption properties of monomodal and random inverted pyramid structures were simulated and compared to well-known random and monomodal textures for PERC solar cells, clearly indicating the best performance for random inverted pyramids. Besides, simulation of a PERC solar cell on a roof top at our university was performed, indicating improved performance, especially for random inverted pyramid textures.

Abstract Passivated emitter and rear cells (PERC) are considered to be the next generation of industrial-type screen-printed silicon solar cells. Deposition methods for rear passivation layers have to meet both the high-throughput and low-cost requirements of the PV industry in combination with high-quality surface passivation properties. In this paper, we evaluate and optimise a novel deposition technique for AlO x passivation layers by applying an inductively coupled plasma (ICP) plasma-enhanced chemical vapour deposition (PECVD) process. The ICP AlO x deposition process enables high deposition rates up to 5 nm/s as well as excellent surface recombination velocities below 10 cm/s after firing. A fixed negative charge of −4×10 12 cm −2 is measured for ICP AlO x single layers with an interface state density of 11.0×10 11 eV −1 cm −2 at midgap position. When applied to PERC solar cells the ICP AlO x layer is capped with a PECVD SiN y layer. We achieve independently confirmed conversion efficiencies of up to 20.1% for large-area (15.6×15.6 cm 2 ) PERC solar cells with screen-printed metal contacts and ICP AlO x /SiN y rear side passivation on standard boron-doped Czochralski-grown silicon wafers. The internal quantum efficiency reveals an effective rear surface recombination velocity S rear of (90±30) cm/s and an internal rear reflectance R b of (91±1)% which demonstrates the excellent rear surface passivation of the ICP AlO x /SiN y layer stack.

Capture of trace amounts (parts per trillion or ppt level) of 90Sr from highly Na+-rich (5 M or 115 000 parts per million) liquid wastes produced from reprocessing of spent nuclear fuel rods is crucial for continuous operation of nuclear power plants.

Phosphogypsum (PG) is the solid waste product of phosphate fertilizer production and is characterized by high concentrations of salts, heavy metals, and certain natural radionuclides. The work reported in this paper examined the influence of PG amendment on soil physicochemical proprieties, along with its potential impact on several physiological traits of sunflower seedlings grown under controlled conditions. Sunflower seedlings were grown on agricultural soil substrates amended with PG at rates of 0, 2.5, and 5 %. The pH of the soil decreased but electrical conductivity and organic matter, calcium, phosphorus, sodium, and heavy metal contents increased in proportion to PG concentration. In contrast, no variations were observed in magnesium content and small increases were recorded in potassium content. The effects of PG on sunflower growth, leaf chlorophyll content, nutritional status, osmotic regulator content, heavy metal accumulation, and antioxidative enzymes were investigated. Concentrations of trace elements in sunflower seedlings grown in PG-amended soil were considerably lower than ranges considered phytotoxic for vascular plants. The 5 % PG dose inhibited shoot extension and accumulation of biomass and caused a decline in total protein content. However, chlorophyll, lipid peroxidation, proline and sugar contents, and activities of antioxidant enzymes such as superoxide dismutase and catalase increased. Collectively, these results strongly support the hypothesis that enzymatic antioxidation capacity is an important mechanism in tolerance of PG salinity in sunflower seedlings.

Boron (B) toxicity symptoms are visible in the form of necrotic spots and may worsen the oxidative stress caused by salinity. Hence, the interactive effects of combined salinity and B toxicity stress on antioxidative activities (TAC, LUPO, SOSA, CAT, and GR) were investigated by novel luminescence assays and standard photometric procedures. Wheat plants grown under hydroponic conditions were treated with 2.5 μM H₃BO₃ (control), 75 mM NaCl, 200 μM H₃BO₃, or 75 mM NaCl + 200 μM H₃BO₃, and analysed 6 weeks after germination. Shoot fresh weight (FW), shoot dry weight (DW), and relative water content (RWC) were significantly reduced, whereas the antioxidative activity of all enzymes was increased under salinity compared with the control. High B application led to necrotic leaf spots but did not influence growth parameters. Following NaCl + B treatment, shoot DW, RWC, SOSA, GR, and CAT activities remained the same compared with NaCl alone, whereas the TAC and LUPO activities were increased under the combined stress compared with NaCl alone. However, shoot FW was significantly reduced under NaCl + B compared with NaCl alone, as an additive effect of combined stress. Thus, we found an adjustment of antioxidative enzyme activity to the interactive effects of NaCl and high B. The stress factor "salt" mainly produced more oxidative stress than that of the factor "high B". Furthermore, addition of higher B in the presence of NaCl increases TAC and LUPO demonstrating that increased LUPO activity is an important physiological response in wheat plants against multiple stresses.