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The fast decay in PEM fuel cells of a highly active, high performance, but unstable Fe/N/C catalyst like our NC_Ar + NH3 follows a chemical, not an electrochemical, demetallation mechanism for its ORR active FeN4 sites in the catalyst micropores.

AbstractCellulose and lignin nanoparticles are high‐value‐added products obtained from lignocellulosic biomasses through several steps of cellulose purification and lignin extraction. These steps drastically reduce the potential feedstock revenue when carried out as stand‐alone methodologies. To increase biomass yields, we describe here a strategy to design a biorefinery focused on producing cellulose and lignin nanoparticles as main products, but also aim to recover and benefit from other biomass components using only water‐based processes. Sequential pressurized liquid extractions and diluted acid and alkaline treatments were carried out to fractionate elephant grass biomass, yielding (for every 100 g of biomass): 30 g of cellulose pulp (converted to 9 g of cellulose nanocrystals and 9 g of cellulose nanofibers); 10 g of lignin (used to produce 8.5 g of stable colloidal lignin nanoparticles by probe‐sonication in water); 7.5 g of extractives (e.g. sterols and phenolics) and 23 g of xylose (converted to 4.1 g of furfural). Alternatively, to allow for the flexible use of the cellulose fraction in the proposed biorefinery, 22 g of glucose could be produced by enzymatic hydrolysis. The results demonstrate that water‐based processes are suitable for a holistic use of biomass, providing a comprehensive set of high‐value‐added co‐products that are renewable and cost‐effective chemical, cosmetic, food, polymer and pharmaceutical solutions.

Abstract This work presents a numerical study on the performance of a stand-alone adsorption cooling system based on the silica gel/water couple driven by hybrid photovoltaic/thermal (PVT) collectors. This system is intended for the conservation of perishable agricultural products which require air-conditioned premises to preserve them. The weather conditions are those of North Africa (Algiers). Considering the above, this paper aims at analyzing the PVT-Adsorption system with energy storage to guarantee a stabilized production and increase the solar coverage. trnsys was used to simulate the system taking into account hourly series of irradiation and ambient temperature covering one year. The performance study reveals that the DualSun PVT hybrid collectors used provide optimal annual production and that the adsorption cooling system offers more reliable production during summer. The temperature difference between the inside and outside of the cooled enclosure balances supply and demand. The loss analysis of the storage device indicates that losses depend, on the one hand, on the interior/exterior temperature difference of the storage tank with more significant values during the summer season. On the other hand, the losses also depend on the volume of the storage tank which was optimized in order to limit the heat exchange with the surroundings.

The solar energy produced by Scheffler parabola (10 m2) is not fully exploited by the solar distillation system of aromatic and medicinal plants. In this work, the optical losses in the primary and secondary reflectors, and the thermal losses at each part of this system (solar still, steam line, condenser) were determined. A thermal energetic and exergetic analysis were also performed for a solar distillation system of rosemary leaves. For average intensity radiation of 849.1W/m2 and 6 Kg of rosemary leaves during 4 h of distillation, exergy and optical efficiencies of the system achieved up to 26.62% and 50.97%, respectively. The thermal efficiency of the solar still, steam line, and condenser is about 94.80%, 94.30%, and 87.76%, respectively. The essential oil yield per unit of consumed energy and the total efficiency of the solar distillation system, taking into account the heat losses in the solar still, steam line, and condenser, as well as the optical losses in the two reflectors, is 6.18 mL/ kWh and 40.00%, respectively. The efficiency can be as high as 42.42 % if the steam line is insulated. Moreover, the comparison between the solar steam distillation and conventional steam distillation shows that solar distillation is much more efficient since it gives better results and especially it avoids the emission of 12.10 kg of CO2 during extraction.

Abstract With drastic fossil fuel depletion and environmental deterioration concerns, a move towards a more sustainable bioenergy-based economy is essential. Lately, the application of microwave (MW) irradiation for waste processing has been attracting interest globally. MW-assisted heating possesses several advantages such as the provision of high microwave energy into dielectric materials with deeper penetration for internal heat generation, showing beneficial features in improving the heating rate and reducing the reaction time. Consequently, the most recent literature regarding the applications of MW-assisted heating for biomass pretreatment as well as biofuel and bioenergy production was reviewed and consolidated in this study. An impressive increase in the product yield and improvement of the product properties are reported, with the use of MW-assisted heating in several conversion routes to produce biofuels. Despite being a promising technology for biofuel production, some major fundamental data of MW-assisted heating have not been comprehensively identified. Therefore, the feasibility of this technology for large-scale implementation is still subpar. Understanding the interaction between the feedstock and the microwave electromagnetic field, and the optimization of several operational and mechanical parameters are the two main keystones that would propel the industrialization of MW heating in the near future. This provides key insights leading to increased feasibility and more advanced application of MW heating.

The implementation of industrial-scale facilities for microalgae cultivation is limited due to the high operation costs. One of the main problems in obtaining an efficient and long-lasting microalgae culture system is biofouling. The particular issue when developing antibiofouling surfaces for microalgae cultures is that the material must be transparent. The main purpose of this work was to evaluate the antibiofouling efficiency of a non-toxic polydimethylsiloxane-based coating prepared with polyethylene glycol-based copolymer on different photobioreactors at the pilot-plant scale. The antifouling properties result from the development of a fouling-release coating utilizing hydrogel technology. Nannochloropsis gaditana and Chlorella sorokiniana were cultured outdoors for 3 months over the summer, when biofouling formation is at its highest due to environmental conditions, to test the coating's antibiofouling efficiency. Although biofouling was not completely prevented in either photobioreactor, the coating significantly reduced cell adhesion compared to the polydimethylsiloxane control (70% less adhesion). Therefore, this coating was shown to be a good alternative for constructing efficient closed-photobioreactors at the pilot-plant scale, at least for cultures lasting 3 months.

Char reactivity usually determines the overall efficiency of the entire gasification process, while the presence of the alkali and alkaline earth metals (AAEMs) has a catalytic effect on char gasification. In this study, the influence of inherent AAEMs in the gasification behaviour of char was investigated. The char sample was prepared through the pyrolysis of solid digestate derived from anaerobic co-digestion of silage and dairy cattle slurry. The raw char and HCl-washed char were characterized by elemental analyzer, ICP-OES, SEM and XRD to explore their structural changes. HCl-char loses weight in the temperature range of 440–620 °C, and the weight loss percentage is significantly higher than that of char. Ash content of char is reduced by half after a pickling process. AAEMs are largely removed after char acid pickling, resulting in an increase in activation energy of the gasification reaction and a decrease in gasification reactivity, resulting in the gasification reaction time of HCl-char longer than char. Water-soluble AAEM and ion-exchange AAEM affect the evolution of carbon structure, which directly lead to char reactivity during the gasification reaction. As the carbon is consumed, the carbon microcrystalline structure of the residual carbon tends to be ordered, resulting in fewer active free carbon sites for the gasification reaction. Kinetic analysis showed that the loss and deactivation of AAEMs after char acid washing increased the average activation energy E a by 115.76 KJ/mol compared with the original char.