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Abstract— The odd nucleoside 4‐thiouridine, which is present in position 8 of 70% of E. coli tRNAs, possesses unusual spectroscopic properties which make it suitable for intramolecular energy transfer studies. Both its luminescence excitation spectrum and the action spectrum (230–380 nm) for the 8–13 link formation have been established in native E. coli tRNA at room temperature. The spectra are identical and present a new unexpected peak around 260 nm. At this wavelength, they are amplified by a factor of nine as compared with the absorption and excitation spectra of the free nucleoside in aqueous solution.The origin of this new peak is discussed and it is concluded that energy transfer does occur from the common nucleosides to the 4‐thiouridine residue. Using the values of the nucleosides to 4‐thiouridine distances inferred from the sets of atomic coordinates obtained on yeast tRNAphe crystals, a satisfactory account of our finding can be obtained assuming singlet‐singlet energy transfer. The efficiency of the mechanism is probably favoured by a good overlap between the emission spectra of the common nucleosides and the absorption spectrum of 4‐thiouridine.

Dans le stockage d’énergie, les alternatives aux énergies fossiles sont peu nombreuses. Le stockage d’énergie dans un condensateur, permet d’atteindre de grande puissances électriques, mais pour une densité d’énergie trop faible. La présente thèse à pour objectif la compréhension des nano-céramiques ferroélectriques afin d’augmenter leur densité d’énergie et de se diriger ainsi vers un super-condensateur céramique. Nous avons développé dans un premier temps un modèle par champs effectif moyen du système core-shell. Une fois introduit dans l’énergie libre de Landau, ce modèle donne une idée de la densité d’énergie d’un système ferroélectrique donné. Les calculs – sur quelques pérovskites courantes - indiquent que la densité d’énergie reste relativement faible. Néanmoins nos calculs montrent que l’on peu optimiser le stockage d’énergie dans de telles céramiques en enrobant des grains de forme allongée comme des disques ou des fils. En outre, ce modèle phénoménologique permet d’expliquer de nombreuses mesures expérimentales sur les céramiques, y compris dans le cas ou s’ajoute de la conductivité et de la relaxation de Maxwell-Wagner. Nous nous sommes tournés par la suite vers une modélisation ab-initio : l’Hamiltonien effectif. La modélisation de nano-système core-shell de BaTiO3 a montré la présence d’un paramètre d’ordre particulier : le moment toroïdale. Ce paramètre d’ordre peut impliquer un comportement diélectrique différent. Introduit dans une description phénoménologique de type Landau, ce dernier est responsable de la disparition de la phase orthorhombique dans BaTiO3. La synthèse de nanoparticules de BaTiO3 de formes cubiques et homogènes, nous a permis de faire une série de mesure. Les mesures MET, RAMAN, RX, diélectriques sur les poudres et les céramiques, suggèrent la présences de transitions de phases générées par la présence d’un paramètre d’ordre similaire à celui observé dans modélisation ab-initio. For energy storage applications, fossils energies are difficult to compete. By storing energy in capacitors, one can get a huge electric power. However the density of energy in a capacitor is too weak to be interesting in energy storage application. The present thesis aims to understand the well known core-shell system in ferroelectric nano-ceramics and the influence of the geometry of the grain in order to determine and optimize the density of energy in this kind of dielectric, going toward an ultra-capacitor of ceramics. We have first developed an effective-medium core-shell model. By introducing this model in the phenomenological Landau Free energy of several ferroelectrics, we can get quantitative information about of density of energy in these materials. Our calculation for common ferroelectrics has shown that the density of energy remains too weak to become interesting. However, the density of energy can be optimized by using nano-disks or nano-rods in a structured ceramic. Our model agrees well with experimental results, even with extrinsic phenomena like the Maxwell-Wagner relaxation. To go further, we have modeled the BaTiO3 core-shell system using an effective Hamiltonian. The model shows that a new order parameter is observed in the core-shell system namely the toroidal moment. This order affects the dielectrics behavior of coated dots, and for important coating can lead to significant differences with Landau predictions. Moreover, by introducing the toroidal moment in Landau formalism, we can predict the disappearance of the orthorhombic phase in BaTiO3.The synthesis of homogenized cubic BaTiO3 particles, allowed us to make experimental measurement. The combination of RX, Dielectric and Raman measurements lead to a phase diagram for BaTiO3 that can be explain by the presence of a toroidal moment.

In the context of Abstract geometrical computation, it has been proved that black hole model (and SAD computers) can be implemented. To be more physic-like, it would be interesting that the construction is reversible and preserves some energy. There is already a (energy) conservative and reversible two-counter automaton simulation. In the present paper, based on reversible and conservative stacks, reversible Turing machines are simulated. Then a shrinking construction that preserves these properties is presented. All together, a black hole model implementation that is reversible and conservative (both the shrinking structure and the universal Turing machine) is provided.

O setor das telecomunicações encontra-se em transição para a quinta geração de redes sem fios. Esta transição vem acompanhada de novos desafios, nomeadamente o aumento do número de dispositivos conectados. O facto de haver mais dispositivos a consumir mais largura de banda aumentará inevitavelmente o consumo de energia e, consequentemente, a pegada de carbono das redes sem fios, a menos que se aumente a eficiência energética. Face a este desafio, este trabalho tem como objetivo contribuir para o aumento da eficiência energética de antenas altamente dirigidas e flexíveis, na forma de agregados de antenas. As estratégias exploradas neste trabalho centram-se na manipulação dos sinais radiados, o que significa que estes sinais são substancialmente diferentes do sinal a ser transmitido. O sinal transmitido é, contudo, devidamente reconstruido no campo distante. Foram investigadas duas abordagens para gerar os sinais radiados. A primeira abordagem consiste em dividir a antena em duas partes, cada uma das quais radia um sinal modulado em fase, uma vez que estes sinais permitem operar os amplificadores com eficiência máxima. A segunda abordagem consiste em radiar sinais intermitentes (burst signals, em inglês), de modo a que cada burst seja um sinal modulado em fase. Embora a primeira abordagem não tenha vingado, a segunda abordagem permite reduzir o consumo de energia entre 12% e 44% e a potência dissipada entre 73% e 84%, desde que os amplificadores possam ser desligados durante os períodos de inatividade dos sinais intermitentes. The telecommunications sector is currently transiting towards the fifth generation wireless networks. Such a transition comes with new challenges, in particular the growth of the number of connected devices. Having more devices consuming more bandwidth shall unavoidably increase the power consumption of wireless networks, and thus its carbon footprint, unless energy efficiency is increased. For this reason, this work aims to contribute to increasing the energy efficiency of highly directive and flexible antenna transmitters: phased array antennas. The strategies explored in this work focus on manipulating the radiated signals, which means that such signals are substantially different from the signal to be transmitted. The signal to be transmitted is nonetheless correctly reconstructed in the far field. Two approaches for generating the radiated signals were investigated. The first approach consists in partitioning the antenna in two halves, each of which radiates a phased modulated signal, since such signals allow to operate the power amplifiers at maximum efficiency. The second approach consists in radiating burst signals, such that each burst is a phased modulated signal. Although the first approach proved ineffective, the second approach allows reducing power consumption between 12% and 44% and the dissipated power between 73% and 84%, provided that power amplifiers can be switched off during the idle periods of the bursts. Mestrado em Engenharia Física

This paper addresses the study of vibrations induced by turbulent boundary layers (TBLs) flowing over plate-like structures. The aim is here to propose a predictive method in order to evaluate the vibroacoustical behaviour of a plate excited by TBL pressure fluctuations. The ultimate goal is to develop tools for predicting internal cabin noise in an aircraft during flight. Hence TBL is considered. Different TBL models are discussed and compared. A prediction method well suited for mid-high frequencies is also presented. The method called simplified energy method (SEM) is based on local energetic considerations and extends the well-known statistical energy analysis (SEA). Two different SEM formulations are presented. The first one is of heat conduction type, whilst the second is radiative. The TBL source model was integrated in the local energy proposed formulations. When applied to a simple Kirchhoff-Love simply supported plate, SEM allows prediction of averaged energy quantities. Comparisons are drawn between heat and radiative formulations. Good concordance was observed between energy results and pure analytical calculations of the structural response under TBL excitation over a wide frequency range.

Abstract An international workshop was held in Richland, Washington, United States of America, in October, 1980 to discuss progress on development of the acid digestion process for treating combustible nuclear waste. The workshop was attended by participants from nine member countries of the Nuclear Energy Agency of the Organization for Economic Cooperation and Development (OECD/NEA). The status of the acid digestion development programs of various countries is discussed in this paper. The acid digestion process has been developed and demonstrated on an engineering scale in several countries and appears to be especially applicable to treatment of combustible wastes containing high levels of transuranic contamination, where there is potential for recovering the transuranic radionuclides. Because the process takes place at a relatively low temperature, the plutonium contained in the residue is in a form that can be readily recovered using standard leaching techniques. The process is adaptable to a wide variety of combustible wastes, such as cellulosics, plastics, rubber materials, and ion exchange resin. While the process has been developed and demonstrated on an engineering scale primarily for transuranic contaminated wastes, the process is also adaptable to beta-gamma wastes such as reactor ion exchange resins.

Cu(In,Ga)Se-2-based solar cells buffered with indium sulfide grown by numerous techniques have reached efficiencies comparable to those achieved by standard devices buffered with (CBD)CdS. The present paper firstly recalls some of the properties of the indium sulfide single crystal and Points Out the disagreements concerning the thin films properties inventoried in the literature. Secondly, the influence of the presence of some "foreign elements" within file indium sulfide on its properties is presented. It is shown that these "foreign elements", even at low concentration levels, are possibly at the origin or the thin films properties deviations compared to the single crystal. The impact of these contaminants on the solar cells performance is finally discussed.

The movement of the powdery material occurs in a multi-phase non-uniform electrostatic field at determined values of the voltage and the frequency, using travelling wave technique. This technique was applied for very small particles such as bacteria and other similar particle size. The objective of this work is to analyze the movement of PVC micronized particles and the feasibility of the separation of PVC/copper granular mixture of average size 100 μm. Two-phase and three-phase conveyors, which are supplied by high voltage amplifiers controlled by digital function generators, have been the subject of a parametric experimental investigation. Several factors were analyzed such as the voltage level up to 1400 V, the frequency, the phase shift and the number of phases of the conveyor. The obtained results showed that depending on the values of the above factors: i) the micronized particles can move instantly right after switching the conveyor, ii) the particles move towards one direction or the other of the conveyor iii) the separation of a granular mixture of plastic and copper micronized particles is possible.