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The fast decay in PEM fuel cells of a highly active, high performance, but unstable Fe/N/C catalyst like our NC_Ar + NH3 follows a chemical, not an electrochemical, demetallation mechanism for its ORR active FeN4 sites in the catalyst micropores.

Developing high capacity yet stable cathodes is key to advancing Li-ion battery technologies. Now, a new metal oxide cathode that is rich in Li with a gradient in Li concentration is shown to be stable to O2 release leading to long cycle life and high capacity.

Atmospheric concentrations of the greenhouse gas nitrous oxide (N(2)O) have increased significantly since pre-industrial times owing to anthropogenic perturbation of the global nitrogen cycle, with animal production being one of the main contributors. Grasslands cover about 20 per cent of the temperate land surface of the Earth and are widely used as pasture. It has been suggested that high animal stocking rates and the resulting elevated nitrogen input increase N(2)O emissions. Internationally agreed methods to upscale the effect of increased livestock numbers on N(2)O emissions are based directly on per capita nitrogen inputs. However, measurements of grassland N(2)O fluxes are often performed over short time periods, with low time resolution and mostly during the growing season. In consequence, our understanding of the daily and seasonal dynamics of grassland N(2)O fluxes remains limited. Here we report year-round N(2)O flux measurements with high and low temporal resolution at ten steppe grassland sites in Inner Mongolia, China. We show that short-lived pulses of N(2)O emission during spring thaw dominate the annual N(2)O budget at our study sites. The N(2)O emission pulses are highest in ungrazed steppe and decrease with increasing stocking rate, suggesting that grazing decreases rather than increases N(2)O emissions. Our results show that the stimulatory effect of higher stocking rates on nitrogen cycling and, hence, on N(2)O emission is more than offset by the effects of a parallel reduction in microbial biomass, inorganic nitrogen production and wintertime water retention. By neglecting these freeze-thaw interactions, existing approaches may have systematically overestimated N(2)O emissions over the last century for semi-arid, cool temperate grasslands by up to 72 per cent.

Abstract In this paper, we explore the use of a frequency domain (FD) modeling and simulation approach to perform statistical studies of switching overvoltages (SSSOV) due to open-ended line energization, as an alternative to the use of time-domain (TD) EMTP-type tools. We analyze the potential advantages of such an approach in terms of accuracy and computational efficiency. We also utilize the FD approach to evaluate the effect of the type of network equivalent used when performing SSSOVs on open-ended lines as part of a network. Our results indicate that applying an FD method for SSSOVs requires substantially lower computer time than an EMTP-type tool to achieve accurate and meaningful statistical results. In addition, the use of constant-lumped-parameter Thevenin equivalents to approximate the rest of the network can result in a considerable deviation from the actual statistical switching behavior of a transmission system. Therefore, equivalents that preserve the rest of the grid's detailed frequency-dependent characteristics are critical for accurate statistical switching overvoltage studies.

Abstract A high-flux solar simulator is essential for evaluating solar thermal components under controlled and adjustable flux input conditions. This study presents a newly built high-flux solar simulator composed of 19 individual units. Each unit includes a xenon short-arc lamp (each consuming up to 6 kW electricity power) coupled with a truncated ellipsoidal reflector, a cooling blower, and a power module. The power module yields a current in the range of 50–160 A. The number of lamps in use is flexible, which allows for a wide range of radiation flux (10%–100%) on the focal plane. The radiation power, peak value, flux distribution on the circular target plane, and conversion efficiency are evaluated based on a flux mapping method. The results indicate that the proposed solar simulator is capable of achieving thermal power of 23.3 kW, peak flux in excess of 1.78 MW/m2, a stagnation temperature exceeding 2360 °C, and average irradiance of 773.4 kW/m2 on the focal plane (diameter of 260 mm). The electro-thermal conversion efficiency of the simulator is 35.7%. A ray-tracing method was employed, and the simulation results were found to be in good agreement with those in the experiments. An experimental test of a volumetric ceramic receiver was conducted, and the results indicate the availability and applicability of the high-flux solar simulator when carrying out studies about solar receivers.

Abstract One approach to creating physics-based reduced-order models (ROMs) of battery-cell dynamics requires first generating linearized Laplace-domain transfer functions of all cell internal electrochemical variables of interest. Then, the resulting infinite-dimensional transfer functions can be reduced by various means in order to find an approximate low-dimensional model. These methods include Pade approximation or the Discrete-Time Realization algorithm. In a previous article, Lee and colleagues developed a transfer function of the electrolyte concentration for a porous-electrode pseudo-two-dimensional lithium-ion cell model. Their approach used separation of variables and Sturm–Liouville theory to compute an infinite-series solution to the transfer function, which they then truncated to a finite number of terms for reasons of practicality. Here, we instead use a variation-of-parameters approach to arrive at a different representation of the identical solution that does not require a series expansion. The primary benefits of the new approach are speed of computation of the transfer function and the removal of the requirement to approximate the transfer function by truncating the number of terms evaluated. Results show that the speedup of the new method can be more than 3800.

A big surplus of power supply, especially during the off-peak period, causes operation problems to the present Taiwan Power Company (Taipower) system. Taipower is facing the difficulties of committing a large amount of nuclear generation at a low base load level.

With the discovery that fluorocarbons may have a profoundly detrimental effect on the earth's atmosphere, it has become necessary to find a suitable replacement for a fluorocarbon-based refrigeration cycle. Such a replacement must perform comparably to current refrigerants, be economically feasible, and significantly reduce the possibility of a negative environmental impact compared with current refrigerants. A review of the literature on the first vapor compression refrigeration cycles indicate that carbon dioxide was used as the working fluid prior to and after the turn of the century. Moreover, recent literature has suggested that carbon dioxide will work for certain air conditioning applications. Initial investigation of the heat transfer properties of carbon dioxide and subsequent modeling of a transcritical carbon dioxide vapor compression cycle suggest potential performance comparable to that of existing refrigeration systems. This paper will present a detailed literature review of carbon dioxide's role in refrigeration cycles and what has been investigated so far to find a suitable application for carbon dioxide as a refrigerant. In addition, two thermodynamic models for transcritical carbon dioxide cycles with and without an expansion turbine have been developed. Both models contain an internal suction-to-supercritical line heat exchange. The efficiencies of the transcritical carbon dioxide cycles will be compared with the ones of conventional HCFC-22 cycles. A second law analysis on both carbon dioxide and HCFC-22 cycles will be included.