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Biomass plays an important role in the world primary energy supplies, currently providing ∼14% of the world's primary energy needs and being the fourth largest contributor following coal, oil and natural gas. Over the past decade, domestic biomass heating has received more governmental and public supports than ever before in many developed countries, such as the UK. Although biomass combustion releases some combustion pollutants, biomass is renewable and produces little net CO 2 emissions to the atmosphere. Owing to the low sulphur and low nitrogen contents of many biomass materials, substituting biomass for fossil fuels, particularly coal, can reduce SO x and NO x emissions. This study investigated flue gas emissions, particularly carbon monoxide and nitrogen oxides, of a domestic biomass boiler under various operating conditions. The biomass boiler used in this study satisfies the current EU regulation (EN 303-05) on emissions of domestic biomass boilers. Emissions of the boiler had been measured not only under normal combustion conditions, but also under 'idle' combustion conditions when the boiler was not in but was ready for full operation. The experimental results are analysed and presented in this paper. Copyright The Author 2010. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oxfordjournals.org, Oxford University Press.

A worldwide increase in tree decline and mortality has been linked to climate change and, where these represent foundation species, this can have important implications for ecosystem functions. This study tests a combined approach of phylogeographic analysis and species distribution modelling to provide a climate change context for an observed decline in crown health and an increase in mortality in Eucalyptus wandoo, an endemic tree of south-western Australia.Phylogeographic analyses were undertaken using restriction fragment length polymorphism analysis of chloroplast DNA in 26 populations across the species distribution. Parsimony analysis of haplotype relationships was conducted, a haplotype network was prepared, and haplotype and nucleotide diversity were calculated. Species distribution modelling was undertaken using Maxent models based on extant species occurrences and projected to climate models of the last glacial maximum (LGM).A structured pattern of diversity was identified, with the presence of two groups that followed a climatic gradient from mesic to semi-arid regions. Most populations were represented by a single haplotype, but many haplotypes were shared among populations, with some having widespread distributions. A putative refugial area with high haplotype diversity was identified at the centre of the species distribution. Species distribution modelling showed high climatic suitability at the LGM and high climatic stability in the central region where higher genetic diversity was found, and low suitability elsewhere, consistent with a pattern of range contraction.Combination of phylogeography and paleo-distribution modelling can provide an evolutionary context for climate-driven tree decline, as both can be used to cross-validate evidence for refugia and contraction under harsh climatic conditions. This approach identified a central refugial area in the test species E. wandoo, with more recent expansion into peripheral areas from where it had contracted at the LGM. This signature of contraction from lower rainfall areas is consistent with current observations of decline on the semi-arid margin of the range, and indicates low capacity to tolerate forecast climatic change. Identification of a paleo-historical context for current tree decline enables conservation interventions to focus on maintaining genetic diversity, which provides the evolutionary potential for adaptation to climate change.

AbstractEuropean climate is associated with variability and changes in the mid-latitude atmospheric circulation. In this study, we aim to investigate potential future change in circulation over Europe by using the EURO-CORDEX regional climate projections at 0.11° grid mesh. In particular, we analyze future change in 500-hPa geopotential height (Gph), 500-hPa wind speed and mean sea level pressure (MSLP) addressing different warming levels of 1 °C, 2 °C and 3 °C, respectively. Simple scaling with the global mean temperature change is applied to the regional climate projections for monthly mean 500-hPa Gph and 500-hPa wind speed. Results from the ensemble mean of individual models show a robust increase in 500-hPa Gph and MSLP in winter over Mediterranean and Central Europe, indicating an intensification of anticyclonic circulation. This circulation change emerges robustly in most simulations within the coming decade. There are also enhanced westerlies which transport warm and moist air to the Mediterranean and Central Europe in winter and spring. It is also clear that, models showing different responses to circulation depend very much on the global climate model ensemble member in which they are nested. For all seasons, particularly autumn, the ensemble mean is much more correlated with the end of the century than most of the individual models. In general, the emergence of a scaled pattern appears rather quickly.

Points out that sustainability as such does not provide a clearcut guide to policy. First one has to decide what is to be sustained. If this is agreed, it must be in an operational from. However, difficulties may still emerge since opinions may differ about how to achieve. This is illustrated by differences in the views of economists about how sustainable development is to be achieved. Orthodox economists stress the importance of the accumulation of man-made capital to achieve this end whereas neo-Malthusians stress the importance of conserving natural resource and environmental capital. Both take an anthropocentric point of view. For political reasons the neo-Malthusian has had little support but it may eventually turn out to be correct. Economics is concerned with reducing economic scarcity and economists have traditionally suggested four main ways of doing this of which economic growth is one. However, neo-Malthusian economists believe that this may not be a sustainable strategy – it may result in future poverty. It should be noted that economic systems are embedded in social and natural systems and depend on these. Economic sustainability depends on the sustainability of these other systems. So from this point of view, it is just one of several bottom lines. Values must be considered in relation to sustainability. Economics is completely anthropocentric in its approach. Therefore, economic approaches to conservation and sustainability can be at odds with the values of deep ecologists or those willing to accord rights to other sentient beings or ecosystems independent of human wishes, or those who want to make use of value judgments other than those based on the measuring rod of money. Consequently economics evaluation is sometimes ineffective in resolving social conflict, including conflict about what should be sustained. As a rule economics alone should not be the final arbiter of social decisions. It is a part (often an important part) of the social evaluation process but not the bottom line, or just one of many lines.

Abstract This paper aims to present a feasibility study of the innovative plant for methanol synthesis from carbon dioxide-sequestered by fossil fuel power plant and hydrogen, which is produced by water electrolyzer employing the over-production on the electrical grid. The thermo-economic analysis is performed in the framework of the MefCO2 H2020 EU project and it is referred to the German economic scenario, properly taking into account the real market costs and cost functions for different components of the plant. Three different plant capacities for methanol production (4000 10,000 and 50,000 ton/year) have been investigated, assuming an average cost for electrical energy to feed electrolysers and analyzing the influence of the most significant parameters (oxygen selling option, methanol selling price and electrolysers’ capital cost) on the profitability of the plant. The analysis has been performed in W-ECoMP, software for the thermo-economic analysis and plant optimization developed by the University of Genoa.

Biofuels have been identified as a mid-term GHG emission abatement solution for decarbonising the transport sector. This study examines the techno-economic analysis of biofuel production via biomass fast pyrolysis and subsequent bio-oil upgrading via zeolite cracking. The aim of this study is to compare the techno-economic feasibility of two conceptual catalyst regeneration configurations for the zeolite cracking process: (i) a two-stage regenerator operating sequentially in partial and complete combustion modes (P-2RG) and (ii) a single stage regenerator operating in complete combustion mode coupled with a catalyst cooler (P-1RGC). The designs were implemented in Aspen Plus® based on a hypothetical 72 t/day pine wood fast pyrolysis and zeolite cracking plant and compared in terms of energy efficiency and profitability. The energy efficiencies of P-2RG and P-1RGC were estimated at 54% and 52%, respectively with corresponding minimum fuel selling prices (MFSPs) of £7.48/GGE and £7.20/GGE. Sensitivity analysis revealed that the MFSPs of both designs are mainly sensitive to variations in fuel yield, operating cost and income tax. Furthermore, uncertainty analysis indicated that the likely range of the MFSPs of P-1RGC (£5.81/GGE  £11.63/GGE) at 95% probability was more economically favourable compared with P-2RG, along with a penalty of 2% reduction in energy efficiency. The results provide evidence to support the economic viability of biofuel production via zeolite cracking of pyrolysis-derived bio-oil.

Abstract A biomass oil/diesel blend was prepared using an emulsion method and combusted in a diesel engine. An injector was then removed and the morphology, composition, and structure of the carbonaceous deposits on the pintle-type nozzle were characterized using a combination of HRTEM, SEM/EDAX, Raman and XRD. Results showed that the carbon deposition of the emulsified fuel with high crystallinity was greater than that of diesel. The agglomerated particulate diameters of the deposited carbon from diesel and emulsified fuel were approximately 10–30 μm and 50 μm, respectively. The carbon deposition mechanism from the emulsified fuel was attributed to the high oxygen content of the groups leading to increased polymerization and subsequent condensation on the nozzle surfaces that was then carbonised.