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Abstract In this paper, energy and exergy analyses of the geothermal-based hydrogen production via thermochemical water decomposition using a new, four-step copper–chlorine (Cu–Cl) cycle are conducted, and the respective cycle energy and exergy efficiencies are examined. Also, a parametric study is performed to investigate how each step of the cycle and its overall cycle performance are affected by reference environment temperatures, reaction temperatures, as well as energy efficiency of the geothermal power plant itself. As a result, overall energy and exergy efficiencies of the cycle are found to be 21.67% and 19.35%, respectively, for a reference case.

Abstract Hydrogen is considered a potential game changer for world energy systems and a solution to climate change concerns, as it generates zero waste and it is suited for power generation and transportation. Despite its several advantages, there are significant technical challenges in deploying a stable hydrogen economy including improving its process efficiencies, lowering production costs, maintaining cost-effective transmission and distribution, and exploiting inexpensive and sustainable feedstocks. In this context, a detailed study was conducted to analyze the production sources, technologies, storage and transport systems, and global potential exportable feedstocks to produce hydrogen. A comprehensive analysis of current hydrogen production technologies with their energy efficiencies and hydrogen selling prices was reported in this study. Various hydrogen production technologies with their capital investments and CO2 emissions were also presented. Potential feedstocks for hydrogen production were identified and analyzed through a product space model, which characterizes a network of global exportable products based on their similarities and productive knowledge. It was established that the hydrogen production feedstocks and sources currently used are primarily available in six countries: the United States of America, France, Russia, Sweden, the Netherlands, and Spain. Broadly, the results revealed that the United States of America and Russia shared the highest hydrogen feedstock exports, indicating a higher probability of hydrogen production in these countries. Except for Russia, all the studied countries fell in the most desired quadrant, indicating that they can move in all product space directions to exploit unexplored hydrogen feedstocks for better sustainable economic growth.

Biomethane production from processed industrial food waste (IFW) in admixture with sewage sludge (primary and waste activated sludge: PS and WAS) was evaluated at a range of C:N ratios using a standard biochemical methane potential (BMP) test. IFW alone had a C:N of 30 whereas for WAS it was 5.4 and thus the C:N ratio of the blends fell in that range. Increasing the IFW content in mix improves the methane potential by increasing both the cumulative biogas production and the rate of methane production. Optimum methane yield 239 mL/g VSremoved occurred at a C:N ratio of 15 which was achieved with a blend containing 11 percent (w/w) IFW. As the fraction of IFW in the blend increased, volatile solids (VS) destruction was increased and this led to a reduction in methane yield and amount of production. The highest destruction of volatile solids of 93 percent was achieved at C:N of 20 followed by C:N 30 and 15. A shortened BMP test is adequate for evaluating optimum admixtures.

Abstract This paper presents a conceptual study of a solar PV integrated refrigeration system for a cold storage facility based on the conventional vapor compression system for banana fruit. In the first stage, the conventional system has been thoroughly analyzed. Mathematical modelling has shown that the condenser is oversized, while the evaporator was undersized. Furthermore, the air-conditioning compressor was also found to be oversized by approximately 12 kW after an evaluation at no-load and full-load conditions. In the second stage, the optimized system with reduced consumption was integrated to a solar PV field. The solar field sizing, and performance optimization of the proposed PV hybrid refrigeration system was accomplished in PV*SOL tool. The simulations demonstrated that with a 170 m2 solar field, an optimized PV hybrid refrigeration system can achieve 58.1% solar fraction at a performance ratio of 59.2%, under given climatic conditions. With net metering, the hybrid system shows a high economic feasibility with the payback period of 5.2 years. The comprehensive methodology and all-inclusive results are valuable to generate explicit recommendations for repowering along with renewable integration of cold storage facilities operating in the region.

Abstract Hydrogen fuel cells are received increasingly wide attention in order to develop green ships and reduce greenhouse gas emissions in the field of waterway transportation. Metal hydrides (MHs) can be used to store hydrogen for green ships due to their high volumetric storage capacity and safety. Various measures should be considered in the design and manufacture process of the MH reactor to strengthen its performance of heat and mass transfer and obtain an acceptable hydrogen storage capacity. In this work, LaNi5 hydride is used as the hydrogen storage material and packed in the reactor. A basic axisymmetric numerical model for the hydrogen storage system without a heat exchanger has been developed and proved to be effective through the comparison between its simulation results and the published data during dehydriding. A hybrid heat exchanger, which is consisted of a phase change material (PCM) jacket and a coiled-tube, has been applied into the hydrogen storage system to relieve the thermal effect of MH in the dehydriding process on system performance. Effects of the heat transfer coefficient between the circulating heating water in the coil-tube and the MH bed, the temperature of circulating heating water and the pressure at the outlet on the dehydriding performance have been investigated. Based on parametric study, the relationships among the average dehydriding rate, the heat transfer coefficient, the heating water temperature and the outlet pressure have been found and fitted as simple equations. These fitted equations can be considered as a reference, which provides an important method to effectively control the dehydriding rate in order to satisfy the fuel requirement of the power unit and ensure the safe navigation of green ships in the future.

SummaryEnvironmentally extended multiregional input‐output (EE MRIO) tables have emerged as a key framework to provide a comprehensive description of the global economy and analyze its effects on the environment. Of the available EE MRIO databases, EXIOBASE stands out as a database compatible with the System of Environmental‐Economic Accounting (SEEA) with a high sectorial detail matched with multiple social and environmental satellite accounts. In this paper, we present the latest developments realized with EXIOBASE 3—a time series of EE MRIO tables ranging from 1995 to 2011 for 44 countries (28 EU member plus 16 major economies) and five rest of the world regions. EXIOBASE 3 builds upon the previous versions of EXIOBASE by using rectangular supply‐use tables (SUTs) in a 163 industry by 200 products classification as the main building blocks. In order to capture structural changes, economic developments, as reported by national statistical agencies, were imposed on the available, disaggregated SUTs from EXIOBASE 2. These initial estimates were further refined by incorporating detailed data on energy, agricultural production, resource extraction, and bilateral trade. EXIOBASE 3 inherits the high level of environmental stressor detail from its precursor, with further improvement in the level of detail for resource extraction. To account for the expansion of the European Union (EU), EXIOBASE 3 was developed with the full EU28 country set (including the new member state Croatia). EXIOBASE 3 provides a unique tool for analyzing the dynamics of environmental pressures of economic activities over time.

Abstract Geological sequestration of CO 2 is an immediately available and technologically feasible means of reducing CO 2 emissions into the atmosphere, which is particularly suited to landlocked sedimentary basins. Geoscience, engineering, economic and public issues need addressing by governments and industry before proceeding with full scale implementation. Specific site selection should be based on a suitability analysis, a proper inventory of potential sites, an assessment of the fate of the injected CO 2 and a capacity determination, together with surface criteria such as CO 2 capture and transport. The suitability analysis, both at the basin and regional scales, is based on geological, geothermal, hydrodynamic, basin maturity, economic and societal criteria. The inventory of sequestration sites needs also identification of major CO 2 point sources and a cost benefit analysis. The potential for CO 2 escape and migration is a deciding factor in screening out unsafe sites. Site capacity should be determined based on in situ conditions and CO 2 properties and behavior. Transforming the geological space into the CO 2 space is an important step along the road map for selection of suitable CO 2 injection sites that allows the identification of safe large capacity sites. An example of application from the Alberta basin is presented.

Results-based financing (RBF) programmes in the clean cooking sector have gained increasing donor interest over the last decade. Although the risks and advantages of RBF have been discussed quite extensively for other sectors, especially health services, there is limited research-documented experience of its application to clean cooking. Due to the sheer scale of the important transition from ‘dirty’ to clean cooking for the 4 billion people who lack access, especially in the Global South, efficient and performance-proven solutions are urgently required. This paper, undertaken as part of the work of the UKAid-funded Modern Energy Cooking Services (MECS) programme, aims to close an important research gap by reviewing evidence-based support mechanisms and documenting essential experiences from previous and ongoing RBF programmes in the clean cooking and other sectors. On this basis, the paper derives key strategic implications and learning lessons for the global scaling of RBF programmes and finds that qualitative key performance indicators such as consumer acceptance as well as longer-term monitoring are critical long-term success factors for RBF to ensure the continued uptake and use of clean cooking solutions (CCS), however securing the inclusion of these indicators within programmes remains challenging. Finally, by discussing the opportunities for the evolution of RBF into broader impact funding programmes and the integration of energy access and clean cooking strategies through multi-sector approaches, the paper illustrates potential steps to enhance the impact of RBF in this sector in the future.