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Nearly three billion people in low- and middle-income countries (LMICs) rely on polluting fuels, resulting in millions of avoidable deaths annually. Polluting fuels also emit short-lived climate forcers and greenhouse gases (GHGs). Liquefied petroleum gas (LPG) and grid-based electricity are scalable alternatives to polluting fuels but have raised climate and health concerns. Here, we compare emissions and climate impacts of a business-as-usual household cooking fuel trajectory to four large-scale transitions to gas and/or grid electricity in 77 LMICs. We account for upstream and end-use emissions from gas and electric cooking, assuming electrical grids evolve according to the 2022 World Energy Outlook’s “Stated Policies” Scenario. We input the emissions into a reduced-complexity climate model to estimate radiative forcing and temperature changes associated with each scenario. We find full transitions to LPG and/or electricity decrease emissions from both well-mixed GHG and short-lived climate forcers, resulting in a roughly 5 millikelvin global temperature reduction by 2040. Transitions to LPG and/or electricity also reduce annual emissions of PM2.5 by over 6 Mt (99%) by 2040, which would substantially lower health risks from Household Air Pollution. Primary input data was collected from the following sources: Baseline household fuel choices - WHO household energy database (https://www.nature.com/articles/s41467-021-26036-x) End-use emissions - US EPA lifecycle assessment of household fuels (https://cfpub.epa.gov/si/si_public_record_report.cfm?dirEntryId=339679&Lab=NRMRL&simplesearch=0&showcriteria=2&sortby=pubDate&timstype=Published+Report&datebeginpublishedpresented) Upstream emissions - Argonne National Labs GREET Model (https://greet.es.anl.gov/index.php) Current and future population estimates - UNECA (http://data.un.org/Explorer.aspx?d=EDATA) Input data was processed by defining household fuel choice scenarios, estimating national household fuel consumption based on these scenarios, and applying fuel-specific emission factors to create country-specific emission pathways. These emission pathways were input into the FaIR model (https://zenodo.org/record/5513022#.Yt_jfHbMLb0) which generated additional data for each scenario including time series of pollution concentrations, radiative forcing, and temperature changes. All data is provided in CSV format. Nothing proprietary is required. 

This dataset contains terrestrial fluxes of nitrous oxide (N2O), methane (CH4) and ecosystem respiration (carbon dioxide (CO2)) calculated from static chamber measurements in riparian buffers of oil palm plantations on mineral soil, in Riau, Sumatra, Indonesia. Measurements were made monthly, from January 2019 until September 2021, with a break from April 2019 to October 2019 to allow for felling and replanting, and another break from January 2021 to June 2021 due to Covid-19 restrictions. To help to reduce the environmental impact of oil palm plantations, riparian buffers are now required by regulations in many Southeast Asian countries. The experiments were conducted to investigate the impact of greenhouse gas emissions from the riparian buffers. Research was funded through NERC grant NE/R000131/1 Sustainable Use of Natural Resources to Improve Human Health and Support Economic Development (SUNRISE) Greenhouse gas concentrations were measured using static chambers, enclosed for 45 minutes. Multiple regressions (including linear and hierarchical multiple regression) were fitted to calculate the best fit flux, using the RCflux R package, written by Dr Peter Levy (UKCEH).

Variation in food resources can result in dramatic fluctuations in the body condition of animals dependent on those resources. Decreases in body mass can disrupt patterns of energy allocation and impose stress, thereby altering immune function. In this study we investigated links between changes in body mass of captive cane toads (Rhinella marina), their circulating white blood cell populations, and their performance in immune assays. Captive toads that lost weight over a 3-month period had increased levels of monocytes and heterophils and reduced levels of eosinophils. Basophil and lymphocyte levels were unrelated to changes in mass. Because individuals that lost mass had higher heterophil levels but stable lymphocyte levels, the ratio of these cell types was also higher, partially consistent with a stress response. Phagocytic ability of whole blood was higher in toads that lost mass, due to increased circulating levels of phagocytic cells. Other measures of immune performance were unrelated to mass change. These results highlight the challenges faced by invasive species as they expand their range into novel environments which may impose substantial seasonal changes in food availability that were not present in the native range. Individuals facing energy restrictions may shift their immune function towards more economical and general avenues of combating pathogens.

With the rising environmental problems there are international movements towards sustainability and greening the built environments in order to mitigate the negative environmental impacts of buildings and human activities on environment and human health. This paper presents a range of K-12 Green Schools that were intentionally designed to utilize school building as a 3D-text book for Environmental Education (EE). The aim of this paper is to examine the methods and strategies of designing green school as a teaching tool through case study analysis of the selected schools. The cases provide a diversity of geographic locations, climates, green strategies and coasts. The research depends on the descriptive analytical approach for literature review; multiple-case study analysis to investigate the attributes of green schools that teach. The results revealed a set of approaches for utilizing green schools as a 3D-textbook for EE EQA - International Journal of Environmental Quality, Vol 39 (2020)

The characteristic blood flow patterns through the major vessels can serve as indicator of cardiovascular health, where pathologies in the cardiovascular system express themselves in form of unphysiolocial flow conditions. Implantable sensor systems in conjunction with machine learning algorithms provide powerful tools to improve healthcare by long-term monitoring of crucial markers while reducing costs through automated diagnostic tasks. This thesis describes methods for blood flow measurement in large vessels and how these can be incorporated in wireless implants for long-term remote patient monitoring and postoperative care. The development process of an implantable magnetic blood flow sensor utilizing permanent magnets in a circular Halbach array configuration is outlined. This design enables fully batteryless and wireless operation using the user's smartphone for transcutaneous communication and power transfer. A machine learning framework is proposed which performs automated diagnostic tasks based on the sensor data without user interaction through unsupervised learning algorithms.

Diverse initiatives are being developed and implemented by universities across Europe to foster the uptake of the research data management (RDM) and FAIR data skills necessary to bring forward the transition to Open Science. Lessons can be learned from bringing together their experience in different legal, organisational and cultural contexts, providing inspiration and points for reflection for other universities transitioning to Open Science. The workshop will discuss with participants the analysis of good practices of universities across Europe that are being gathered by the FAIRsFAIR project. Preliminary results from this ongoing study will be presented, highlighting the drivers, impact and implementation steps behind the initiatives taken by institutions to integrate RDM and FAIR data skills in university curricula. The shift towards hybrid models of teaching data-related skills is also addressed in the analysis, showing how the COVID-19 pandemic created not only challenges but also surprising opportunities for the implementation of Open Science practices in universities. Findings will include information on legal, organisational and cultural differences between regional and national systems in Europe, which will allow to contextualise university initiatives. Comments and feedback from participants beyond Europe will be welcomed and will further improve the cross-border exchange of good practices. The workshop will be of interest to RDM and FAIR teachers, trainers and practitioners, as well as European and national policy makers. Participants will be invited to reflect on their own institutional experiences in an engaging and interactive way, through breakout rooms and a digital workspace set in Mural. This presentation is about supporting the implementation of FAIR data skills in university teaching

United Bank of India, 507 R. B. C. Road, Garifa, North 24-Parganas Department of Chemistry, University of Kalyani, Kalyani-741 235 Department of Chemistry, Vivekananda Mission Mahavidyalaya, Viveknagar, P.O. Chaitanyapur (Haldia)-721 645 Manuscript received 9 June 1992, revised 22 October 1992, accepted 2 December 1992 ln order to understand the nature of ion-solvent interactions and structural changes of the solvent mixtures associated with the addition of ions, conductance measurements of the tetraalkylammonium halides in ethanol + water mixtures were made. The results have been analysed using the Fuoss equations. In absence of transference number values, the single ion values of tetraalkylammonium ions at 16.4, 34.4, 54.1 and 76 wt% of ethanol have been calculated using reference electrolyte method taking Bu4NBPh4 as the electrolyte. The variation of \(\Lambda\)o and \(\Lambda\)oηo or \(\Lambda\)o±ηo With solvent composition has been interpreted in terms of structural changes associated with the addition of electrolytes. Most of the electrolytes can be regarded to be associated in the solvent mixtures.

In assessing the impact of global tourism on climate change, emissions from transport receive the most attention although emissions associated with accommodation account for more than 20% of the total. A plethora of hotel certification schemes have been established worldwide that assess various environmental performance indicators, among them energy use. However, none explicitly quantify CO2 emissions, and in many, energy is poorly accounted for, or other non-energy related factors are weighted so that the overall impact of energy use (and hence CO2 emission) is weak. The main thrust of the research is to ascertain the effect of certification on CO2 emissions. The research questions whether the certification schemes are robust and rigorous and whether the results are credible. First, four widely used certification schemes are compared Nordic Swan (Scandinavia), Green Globe (Worldwide), EU Flower (European) and Green Hospitality Award (Ireland). The key issues are identified such as performance and process related criteria, use of benchmarks, and the weighting of different categories. A comparison is made with LEED-EB, a well-established environmental certification scheme, not dedicated to the hotel sector. Secondly, the way in which emissions from electricity, including so-called green electricity and carbon offsetting, are accounted for is examined since it is found that in obtaining certification, this often plays an important part. Actual annual energy use data is desperately needed as feedback to designers, managers and owners in order to give confidence that certification schemes have true validity. Results are presented from large multi-hotel data samples and for detailed results from the quality, illustrative in-depth studies which provided invaluable insight into the technical realities of a multitude of causes and effects which can often be masked in large data samples. An analysis was carried out for four In-depth studies located in Sweden (Nordic Swan), Maldives (Green Globe), Malta (EU Flower) and Ireland (Green Hospitality Award). Global CO2 emissions were compared and calculated from the delivered electricity and fuels consumption data from seventy selected certified hotels worldwide. No corrections were made in the calculations for climate, quality of services, existence of services etc. The performance indicator used is kgCO2 per guest night. The analyses shows no clear pattern. CO2 emissions show a wide variance in performance for 8 hotels certified under different schemes, as well as for 28 hotels certified under the same scheme. In some cases emissions reduced after certification in others no change. Certified hotels do not necessarily have lower emissions than uncertified hotels and a comparison of before – and after – certification shows no significant improvement prior to certification. Most dramatically emissions from certified hotels widely vary by a factor of 7. Although it is arguable a number of corrections should be made to account for different climates, the research highlights that hotels with high CO2 emissions are being awarded certification and it questions what message‘certification’ gives to guests and other stakeholders. At worst it appears ‘business as usual’ can achieve certification with no obvious improvement in performance. The overall conclusion is that existing certification schemes do not properly account for CO2 emissions and do not produce more energy efficient (or less CO2 intensive) buildings. Hotel accommodation was found to be more CO2 intensive than domestic emissions. The findings also uncovered inconsistencies in current methods of certification and indicate a vital need for improved methods. The results also challenge prevailing aesthetic stereotypes of sustainable hotels. The author concludes a simple CO2 accounting method is needed as the first step of a diagnostic process leading to a solution i.e. reduced emissions, to the problem i.e. high energy consumption and/or emissions, thus reducing the environmental impact (in terms of emissions reduction) of the hotel. This method of accounting can be adopted universally by using a Regional, European (O.475 kgCO2/kWh) or Universal (0.55 kgCO2/kWh) conversion factor. In relation to the proper calculation of energy and CO2 emission, sub-metering is a key factor, and with current technological developments, realistic and affordable. Furthermore, apart from certification itself, an essential quality with any monitoring system is that the user can obtain results easily and understandably, in order to get feedback from their actions. This could be facilitated by incorporating sub-metering as part of the building environmental management system software. This ensures that the certification activity is not simply a benchmark, but is also part of a diagnostic and educational process, which will continue to drive emissions down. Only then should it be ethically justified to use as a marketing tool providing diagnostic support in existing buildings, and design and operational guidance for new designs. No page 475 due to incorrect pagination - dissertation complete.

It has been increasingly aware to the world today that reserves of fossil fuels are limited and their use has serious environmental side effects. Encouraged by this realization was the evolution of the use of cleaner alternative energy, among which Dye-sensitized solar cells (DSCs) are potentially attractive candidates for the lower cost of producing devices which convert an abundant amount of energy from the sun into electricity. Dye-sensitizer in DSCs plays a crucial role as the chlorophyll in plants; to harvest solar light and transfer the energy via electron transfer to a suitable material (TiO2 in this case) to produce electricity. The topic of interest for this thesis is to further enhance the photovoltaic performance and the robustness of DSCs by tuning the optical properties of the dye-sensitizer (Ruthenium complex, in this case) using several strategies including an extension of the π-conjugation system, an introduction of antenna molecules and a modification of the Ru-complex structure. This work focuses on the DSC device fabrication and photovoltaic characterization in order to investigate more insight into structure-property-device performance relationship. New benchmarks for high performance DSCs with ruthenium complex sensitizers with π-extension in their ancillary ligands were presented. The overall conversion efficiency of 9.6% and 8.5% have been achieved with Ru-based sensitizer containing ethylenedioxythiophene, using low-volatile electrolyte and solvent-free electrolyte, respectively. The Rusensitizer functionalized with hexylthio-bithiophene unit exhibited a conversion efficiency of 9.4% with low-volatile electrolyte. All these devices showed good stability under prolonged light soaking at 60 °C. Extending π-conjugation of the anchoring ligand with thiophene units in monoleptic Ru-sensitizer also yields an impressive conversion efficiency of 6.1% using 3-µm-thin mesoporous TiO2 film in corporate with low-volatile electrolyte. DSC devices based on ruthenium sensitizers functionalized with thienothiophene- and EDOT-conjugated bridge, together with carbazole moiety on the ancillary ligands were found efficient with conversion efficiencies of 9.4% and 9.6%, respectively, in presence of a volatile electrolyte. The carbazole-functionalized ruthenium-based DCSs also performed excellently in the stability test using a low-volatile electrolyte. Furthermore, the Ru-complexes synthesized by click-chemistry in association with triazole-derivative moieties were successfully used as DCS sensitizers. DSC devices sensitized with these dyes provided the overall conversion efficiency close to 10% with volatile electrolyte. Further studies with solvent-free electrolyte showed notable device stability under extending full sunlight intensity at 60 °C. The results presented here provide a fertile base for further investigation, which will focus on improving the spectral response of ruthenium dye-sensitizer to full sunlight by searching for new strategies to modify the sensitizer with more efficient functional groups. The target is to reach higher conversion efficiency of DSC devices while retaining their stability under standard reporting conditions.