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Earth-abundant Cu2ZnSn(S,Se)4 (CZTSSe) thin film photovoltaic absorber layers are fabricated by annealing Cu2ZnSnS4 (CZTS) nanoparticle thin films in a selenium rich atmosphere. Systematic variation of the selenization time (5, 10, 20 and 40 min) and temperature (450, 500, 550 and 600 °C) provides insight into the kinetics of the selenization process and in particular recrystallization and grain growth. Se–S anion exchange is found to follow Avrami׳s model in which the CZTS selenization is controlled by an irregular one-dimensional process limited by metal cation re-ordering and grain boundary migration. CZTSSe grain growth is observed to follow a normal relation with a grain growth exponent close to the ideal case of equiaxed grains and the grain boundary migration energy is calculated to be 85.38 kJ/mol. These selenization variables have a fundamental influence on the quality of the resulting CZTSSe thin film and consequently the device performance. A peak device solar energy conversion efficiency of 5.4% was obtained for selenization at 500 °C for 20 min. The device efficiency was found to be highly sensitive to these variables and it is critical to obtain an appropriate balance between grain growth and thin film quality.

Owners of power systems incur high costs and investments to transfer the electrical power to customers in the distribution network. Hence, the reliability of the distribution network is particularly important in the lives of customers. Natural disasters such as hurricane and earthquake or sudden faults may threaten the reliability of the distribution network. Therefore, the focus of this study is to provide a new formulation for the distribution system resilience and voltage security. To improve the mentioned objectives in the automated distribution system, the concept of distribution feeder reconfiguration (DFR) is used in this study. Due attention of distribution network resilience and voltage security issues, energy not supplied and voltage stability index along with power loss are considered as objective functions. According to the increase of distributed generators in the distribution network, the effect of these units is considered in the DFR problem. An improved particle swarm optimization is presented to solve the complex and non-convex DFR problem. The proposed algorithm is tested into two distribution systems including IEEE 33 and 70-node.

The use of ionic liquid (IL) electrolytes promises to improve the energy density of electrochemical capacitors (ECs) by allowing for operation at higher voltages. Several studies have also shown that the pore size distribution of materials used to produce electrodes is an important factor in determining EC performance. In this research the capacitative, energy and power performance of ILs 1-ethyl-3-methylimidazolium tetrafluoroborate (EMImBF4), 1-ethyl-3-methylimidazolium dicyanamide (EMImN(CN)2), 1,2-dimethyl-3-propylimidazolium bis(trifluoromethylsulfonyl)imide (DMPImTFSI), and 1-butyl-3-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate (BMPyT(F5Et)PF3) were studied and compared with the commercially utilised organic electrolyte 1 M tetraethylammonium tetrafluoroborate solution in anhydrous propylene carbonate (Et4NBF4–PC 1 M). To assess the effect of pore size on IL performance, controlled porosity carbons were produced from phenolic resins activated in CO2. The carbon samples were characterised by nitrogen adsorption–desorption at 77 K and the relevant electrochemical behaviour was characterised by cyclic voltammetry, galvanostatic charge–discharge and electrochemical impedance spectroscopy. The best capacitance performance was obtained for the activated carbon xerogel with average pore diameter 3.5 nm, whereas the optimum rate performance was obtained for the activated carbon xerogel with average pore diameter 6 nm. When combined in an EC with IL electrolyte EMImBF4 a specific capacitance of 210 F g−1 was obtained for activated carbon sample with average pore diameter 3.5 nm at an operating voltage of 3 V. The activated carbon sample with average pore diameter 6 nm allowed for maximum capacitance retention of approximately 70% at 64 mA cm−2.

This study estimates the combined direct and indirect rebound effects from energy efficiency improvements in the delivery of six energy services to UK households, namely: heating; lighting; cooking; refrigeration and clothes washing; entertainment and computing; and private vehicle travel. We use a unique database on the price and quantity demanded of these energy services over the past half century. We estimate a two-stage almost ideal demand system for household expenditure, using these energy services as expenditure categories. We estimate rebound effects in terms of carbon emissions and only include the ‘direct’ emissions associated with energy consumption. Our results suggest direct rebound effects of 70% for heating, 54% for private vehicle travel and ∼90% for the other energy services. However, these effects are offset by negative indirect rebound effects—that is, indirect rebounds contribute additional emission savings. As a result, our estimates of combined rebound effects are generally smaller, namely 54% for lighting, 55% for heating, 41% for refrigeration and clothes washing, -12% for entertainment and computing, 44% for cooking and 69% for vehicle travel. We also find some evidence that rebound effects have declined over time. We provide some important caveats to these results, and indicate priorities for future research.

In a former study, a German lignite extract exhibited toxicity to Danio rerio and Caenorhabditis elegans and was shown to have mutagenic and dioxin-like activity. Besides the comparatively low content of known toxic polycyclic aromatic hydrocarbons (PAH), highly intensive peaks of m/z 274 and m/z 324 were observed during the chromatographic analysis. These compounds are assumed to be alkylated chrysenes and picenes (3,3,7-trimethyl-1,2,3,4-tetrahydrochrysene, 1,2-(1'-isopropylpropano)-7-methylchrysene and an isomer of the latter, 1,2,9-trimethyl-1,2,3,4-tetrahydropicene and 2,2,9-trimethyl-1,2,3,4-tetrahydropicene). These compounds are intermediates in the diagenetic formation of chrysene and picene from triterpenoids. Due to their general high abundance in lignites and the toxicity observed for the lignite extract, the mechanism-specific toxicity and bioavailability of these compounds were investigated in the present study using the approach of effect-directed analysis. After the separation of the compounds from other PAH, their mutagenic activity (Ames Fluctuation test) and dioxin-like activity (EROD activity) were studied. Both, mutation induction factor (up to 2.9±2.7) and dioxin-like activity (Bio-TEQ of 224±75 pg/g; represents the amount (pg) 2,3,7,8-tetrachlorodibenzo-p-dioxin per g coal that would provoke the same toxic effect) were rather low. Bioavailability estimated by the bioaccumulation test with Lumbriculus variegatus was also very limited. Based on the obtained results, the environmental risk of the highly abundant alkylated chrysenes and picenes in lignites is concluded to be low.

Abstract Hybrid energy storage is a multi-modal approach to store and supply different forms of energy (electricity, heat, cold) simultaneously. This is an important sector coupling approach and enables large scale flexibility for a deep decarbonization of energy systems. Two different proposed energy storages – power-to-heat-to-X energy storage (PHXES) and pumped thermal energy storage (PTES) – are investigated in detail in this work towards their potential towards a hybrid deployment. The techno-economic analysis includes thermodynamic flowsheet simulations and unified cost estimations based on the used equipment. It is shown that the main input data set (e.g. working fluid selection, turbomachinery efficiency, pinch temperatures) has a strong influence on storage roundtrip efficiency in the thermodynamic simulations, but also on storage costs. Cost decrease and performance increase can be conflicting development targets, and it is not clear if future energy systems rather require technologies with the highest storage efficiencies or if low cost is an important prerequisite. PHXES and three variants of PTES are implemented into a simplified energy system model of the city of Hamburg that comprises the electric load and heat demand of the district heating system. Two scenarios (fossil benchmark and 80% decarbonization) are used to select the technologies and their capacities that allow the most cost-effective energy supply solution by a linear-programming optimization procedure. Large scale renewable power generation and hybrid energy storage play the major roles in the decarbonization scenario. PHXES with a storage capacity of 69 GWh, hot water storage (3.6 GWh) and a battery system (430 MWh) are part of the cost-optimal solution. A cost sensitivity analysis shows that a total cost reduction of 60–80% is required for PTES to become competitive in this model scenario.

The primary photovoltaic (PV) system investment decision‐making criteria are economics. These criteria are focused on system efficiency and cost, which is reasonable in the context of generous financial support schemes. However, when financial support is phased out, the PV market becomes technologically diversified. Environmental concerns and other qualitative issues become significant, whereas efficiency and costs may fail to describe PV systems properly. This study presents the first application of outranking techniques for PV technologies within an overall framework that includes qualitative, economic, technical and environmental criteria. The multi‐criteria analysis method, ELECTRE III, identifies optimal investment decisions from a pre‐determined set of investment alternatives. A case study based on a grid‐connected household PV system in the United Kingdom illustrates the methodology. The results suggest emerging excitronic PV technologies such as organic PV to lead the ranking when compared with inorganic technologies. These results have to be taken in the context of a number of assumptions and estimates as well as free market, no financial support schemes and promising future technology developments. The overall decision‐making framework provides comprehensive mathematical evaluations that assist PV owners, policy makers and the business community decide on technology, financial support schemes or business strategies.

The energy transition and the expansion of renewable energies are central challenges to planning. In view of tightened climate protection targets and the associated rise in installation capacity, planning conflicts are likely to intensify further in the coming years. At the same time, democratic institutions are under increasing pressure. The expansion of wind energy must proceed swiftly while democratic participation must be ensured. Based on planning conflicts over wind turbines in Mecklenburg-West Pomerania and Brandenburg, this paper addresses the extent to which research on planning conflicts can benefit from a justice perspective, both in theoretical-conceptual and empirical terms. Drawing on concepts from research on spatial justice, energy justice, and planning justice, the paper uses a three-dimensional conception of justice to identify access points for dealing constructively with conflicts. First, conflicts have to be recognized as such and their productive potential has to be acknowledged. Second, strategies have to be established that allow conflicts to be dealt with constructively. In doing so, several dimensions of justice must be taken into account: distributive justice and the question of what is to be distributed according to which criteria, recognition justice and the reflexion on difference and needs beyond hegemonic majority opinion, and finally procedural justice, which is intended to ensure that recognition and fair distribution can be implemented. In this way, a proactive attitude towards planning conflicts can make a central contribution to sustainable and democratic planning.