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In recent years, the rapid development of the rare earth industry has had a serious impact on the environment. Some enterprises have taken measures to improve the production process. In order to explore the sustainability of this industry and these improvements’ environmental benefits, this paper combines emergy analysis and lifecycle assessment to evaluate and compare the production process of rare-earth oxides considering the three aspects of emergy flow, pollutant emissions, and emergy-based indicators. Changes in the emergy of pollutant emissions before and after improvement of the production process are discussed. The results show that the greatest inputs in the mining and beneficiation stage and smelting separation stage are labor force and service and non-renewable resources, respectively. These two production stages are highly dependent on external input and have weak competitiveness. Both stages place great pressure on the environment, so the bastnasite production process would be unsustainable in the long term. After the improvement, the environmental impact of the production process for bastnaesite changed significantly, indicating that the improvement effect of the wastewater treatment facilities and the change of fuel from coal to natural gas is remarkable.

© 2020 Elsevier Ltd Free cooling of buildings uses the nocturnal outdoor air as a heat sink via a ventilation process. This could be performed by storing the night coolness for use during the daytime as appropriate. Due to the latent heat capacity, phase change material (PCM) could play anessential role in the effective operation of the free cooling systems by shifting the daytime peak load to the night. However, there is a scarceness on the technology application in hot climates. This paper presents results of a parametric investigation into the application of PCMs as thermal energy storage (TES) to provide sustainable cooling to buildings in hot arid climate by making use of the night-time free cooling. The proposed TES medium comprises an arrangement of metallic modules filled with RT28HC PCM. Numerous geometrical configurations and operational parameters have been assessed. A transient CFD simulation has been employed using ANSYS Fluent software. Validation of the numerical results with experimental data has shown a good agreement. The results have demonstrated that the temperature difference between the PCM and the air, at appropriate air flow rate would have a significant impact on the performance of the system. A free cooling system based on the proposed arrangement has the potential to meet around 42% of a typical building cooling load and has the ability to save up to 67% of building cooling energy load in summer season compared to conventional air-conditioning systems in hot arid climates.

Decarbonizing the building sector is extremely important to mitigating climate change as the sector contributes 40% of the overall energy consumption and 36% of the total greenhouse gas emissions in the world. Net-zero energy buildings are one of the promising decarbonization attempts due to their potential of decreasing the use of energy and increasing the total share of renewable energy. To achieve a net-zero energy building, it is necessary to decrease the energy demand by applying efficiency enhancement measures and using renewable energy sources. Net-zero energy buildings can be classified into four models (Net-Zero Site Energy buildings, Net-Zero Emissions buildings, Net-Zero Source Energy buildings, and Net-Zero Cost Energy buildings). A variety of technical, financial, and environmental factors should be considered during the decision-making process of net-zero energy building development, justifying the use of multi-criteria decision analysis methods for the design of net-zero energy buildings. This paper also discussed the contributions of renewable energy generation (hydropower, wind energy, solar, heat pumps, and bioenergy) to the development of net-zero energy buildings and reviewed its role in tackling the decarbonization challenge. Cost-benefit analysis and life cycle assessment of building designs were reviewed to shape the priorities of future development. It is important to develop a universal decision instrument for optimum design and operation of net-zero energy buildings.

Environment-friendly treatment of sewage sludge has become tremendously important. Conversion of sewage sludge into energy products by environment-friendly conversion process, with its energy recovery and environmental benefits, is being paid significant attention. Direct liquefaction of sewage sludge into bio-oils with supercritical water (SCW) was therefore put forward in this study, as de-water usually requiring intensive energy input is not necessary in this direct liquefaction. Supercritical water may act as a strong solvent and also a reactant, as well as catalyst promoting reaction process. Experiments were carried out in a self designed high-pressure reaction system with varying operating conditions. Through orthogonal experiments, it was found that temperature and residence time dominated on bio-oil yield compared with other operating parameters. Temperature from 350 to 500°C and reaction residence time of 0, 30, 60min were accordingly investigated in details, respectively. Under supercritical conversion, the maximum bio-oil yield could achieve 39.73%, which was performed at 375°C and 0min reaction residence time. Meanwhile, function of supercritical water was concluded. Fuel property analysis showed the potential of bio-oil application as crude fuel.

Abstract This study investigates the non-linear relationship between urbanization paths and CO2 emissions in selected South, South-East, and East Asian countries over the period 1971–2014. Based on the STIRPAT (Stochastic Impacts by Regression on Population, Affluence, and Technology) framework, we applied the advanced and robust methods of dynamic seemingly unrelated regression (DSUR), dynamic OLS (DOLS), and fully modified OLS (FMOLS) to estimate the long-term effects. The empirical findings revealed the inverted U-shaped effects of urbanization and urban agglomeration and the U-shaped impact of the largest city ratio on CO2 emissions. Urbanization and urban agglomerations improve environmental quality in the long-run and support ecological modernization theory. However, excessive concentration in the largest cities have severely affected the environmental quality and violates the notion of compact-city efficiencies. Moreover, energy intensity and economic growth positively affect CO2 emissions, while trade openness negatively influences CO2 emissions. Our robustness analysis at the country-level applies the augmented mean group (AMG) panel ARDL technique, which further supports the non-linear effect of urbanization paths on CO2 emissions except for a few countries. The results of the panel Granger non-causality approach unveil bidirectional causality of energy efficiency, economic growth, urbanization, and largest city ratio with CO2 emissions. In contrast, unidirectional causality runs from urban agglomeration to CO2 emissions. Our findings have important policy implications as we suggest green urban infrastructures, eco-friendly dwellings, smart cities, country-specific trade policies, and renewable energy options to improve the environmental quality.

In this study, levulinic acid (LA) was produced from rice straw biomass in co-solvent biphasic reactor system consisting of hydrochloric acid and dichloromethane organic solvent. The modified protocol achieved a 15% wt LA yield through the synergistic effect of acid and acidic products (auto-catalysis) and the designed system allowed facile recovery of LA to the organic phase. Further purification of the resulting extractant was achieved through traditional column chromatography, which yielded a high purity LA product while recovering ∼85% wt. Upon charcoal treatment of the resultant fraction generated an industrial grade target molecule of ∼99% purity with ∼95% wt recovery. The system allows the solvent to be easily recovered, in excess of 90%, which was shown to be able to be recycled up to 5 runs without significant loss of final product concentrations. Overall, this system points to a method to significantly reduce manufacturing cost during large-scale LA preparation.

Abstract As a burgeoning theoretical framework, energy justice has been mostly focused on the energy transition in Western countries, where socio-political settings are largely featured by liberalism and democracy, leaving an obvious gap in its application in other socio-political contexts. As a major energy consumer and a leader of the global low-carbon transition, China is characterized by a distinctive socio-political regime. An array of grand strategies to transform its coal-dominant energy structure have been initiated to ameliorate deteriorating environmental crises in particular and materialize a low-carbon transition in general. Based on extensive evidence, this article incorporates the energy justice framework into the analysis of an ongoing energy transition project in rural Northern China. It contributes to the related research in three dimensions. First, empirically, it demonstrates that the coal-to-gas heating transition project has been swamped with social injustices; the absence of measures to address these would lead this mega-project to profound failure. Second, theoretically, it illustrates that the concerns of justice are even more paramount in an authoritarian context where policy processes are characterized by strong political-administrative intervention and the pursuit of efficiency at all cost. In light of this, it stresses the indispensable role of restorative justice as a core tenet in achieving energy justice in authoritarian socio-political contexts, such as China. Third, this study advocates expanding the evaluation parameters of authoritarian environmentalism to include social consequences.

Recycled polylactic acid (PLAr) was reinforced with treated nanocellulosic hemp fibers for biocomposite fabrication. Cellulosic fibers were extracted from hemp fibers chemically and treated enzymatically. Treated nanocellulosic fibers (NCF) were analyzed by Fourier-transform infrared spectroscopy, X-ray diffraction, and scanning electron microscopy. Biocomposite fabrication was done with PLAr and three concentrations of treated NCF (0.1%, 0.25%, and 1% (v/v)) and then studied for thermal stability and mechanical properties. Increased thermal stability was observed with increasing NCF concentrations. The highest value for Young’s modulus was for PLAr + 0.25% (v/v) NCF (250.28 ± 5.47 MPa), which was significantly increased compared to PLAr (p = 0.022). There was a significant decrease in the tensile stress at break point for PLAr + 0.25% (v/v) NCF and PLAr + 1% (v/v) NCF as compared to control (p = 0.006 and 0.002, respectively). No significant difference was observed between treatments for tensile stress at yield.