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© 2020 Elsevier Ltd Free cooling of buildings uses the nocturnal outdoor air as a heat sink via a ventilation process. This could be performed by storing the night coolness for use during the daytime as appropriate. Due to the latent heat capacity, phase change material (PCM) could play anessential role in the effective operation of the free cooling systems by shifting the daytime peak load to the night. However, there is a scarceness on the technology application in hot climates. This paper presents results of a parametric investigation into the application of PCMs as thermal energy storage (TES) to provide sustainable cooling to buildings in hot arid climate by making use of the night-time free cooling. The proposed TES medium comprises an arrangement of metallic modules filled with RT28HC PCM. Numerous geometrical configurations and operational parameters have been assessed. A transient CFD simulation has been employed using ANSYS Fluent software. Validation of the numerical results with experimental data has shown a good agreement. The results have demonstrated that the temperature difference between the PCM and the air, at appropriate air flow rate would have a significant impact on the performance of the system. A free cooling system based on the proposed arrangement has the potential to meet around 42% of a typical building cooling load and has the ability to save up to 67% of building cooling energy load in summer season compared to conventional air-conditioning systems in hot arid climates.

Decarbonizing the building sector is extremely important to mitigating climate change as the sector contributes 40% of the overall energy consumption and 36% of the total greenhouse gas emissions in the world. Net-zero energy buildings are one of the promising decarbonization attempts due to their potential of decreasing the use of energy and increasing the total share of renewable energy. To achieve a net-zero energy building, it is necessary to decrease the energy demand by applying efficiency enhancement measures and using renewable energy sources. Net-zero energy buildings can be classified into four models (Net-Zero Site Energy buildings, Net-Zero Emissions buildings, Net-Zero Source Energy buildings, and Net-Zero Cost Energy buildings). A variety of technical, financial, and environmental factors should be considered during the decision-making process of net-zero energy building development, justifying the use of multi-criteria decision analysis methods for the design of net-zero energy buildings. This paper also discussed the contributions of renewable energy generation (hydropower, wind energy, solar, heat pumps, and bioenergy) to the development of net-zero energy buildings and reviewed its role in tackling the decarbonization challenge. Cost-benefit analysis and life cycle assessment of building designs were reviewed to shape the priorities of future development. It is important to develop a universal decision instrument for optimum design and operation of net-zero energy buildings.

With the aim to fully exploit the by-products obtained after the industrial extraction of starch from sweet potatoes, a cascading approach was developed to extract high-value molecules, such as proteins and pectins, and to valorize the solid fraction, rich in starch and fibrous components. This fraction was used to prepare new biocomposites designed for food packaging applications. The sweet potato residue was added to poly(3-hydroxybutyrate-co-3-hydroxyvalerate) in various amounts up to 40 wt % by melt mixing, without any previous treatment. The composites are semicrystalline materials, characterized by thermal stability up to 260 °C. For the composites containing up to 10 wt % of residue, the tensile strength remains over 30 MPa and the strain stays over 3.2%. A homogeneous dispersion of the sweet potato waste into the bio-polymeric matrix was achieved but, despite the presence of hydrogen bond interactions between the components, a poor interfacial adhesion was detected. Considering the significant percentage of sweet potato waste used, the biocomposites obtained show a low economic and environmental impact, resulting in an interesting bio-alternative to the materials commonly used in the packaging industry. Thus, according to the principles of a circular economy, the preparation of the biocomposites closes the loop of the complete valorization of sweet potato products and by-products.

Beside their technological importance in soldering, the low melting eutectic alloys based on bismuth and indium have potential for commercial application in the field of phase- change materials (PCMs). In this respect, the knowledge of their microstructure and thermal properties such as melting temperature, latent heat of melting, supercooling tendency, thermal conductivity, etc. is of large importance. In this study, two ternary eutectic Bi-In-Sn alloys were investigated by means of scanning electron microscopy (SEM) with energy dispersive X-ray spectrometry (EDS) and differential scanning calorimetry (DSC). Microstructure of the prepared eutectic alloys was analyzed using SEM- EDS and identification of co-existing phases was done. Melting temperatures and latent heats of eutectic melting were measured using DSC technique. Experimentally obtained results were compared with the results of thermodynamic calculation according to CALPHAD (calculation of phase diagram) approach and good mutual agreement was obtained.

Biomass plays an important role in the world primary energy supplies, currently providing ∼14% of the world's primary energy needs and being the fourth largest contributor following coal, oil and natural gas. Over the past decade, domestic biomass heating has received more governmental and public supports than ever before in many developed countries, such as the UK. Although biomass combustion releases some combustion pollutants, biomass is renewable and produces little net CO 2 emissions to the atmosphere. Owing to the low sulphur and low nitrogen contents of many biomass materials, substituting biomass for fossil fuels, particularly coal, can reduce SO x and NO x emissions. This study investigated flue gas emissions, particularly carbon monoxide and nitrogen oxides, of a domestic biomass boiler under various operating conditions. The biomass boiler used in this study satisfies the current EU regulation (EN 303-05) on emissions of domestic biomass boilers. Emissions of the boiler had been measured not only under normal combustion conditions, but also under 'idle' combustion conditions when the boiler was not in but was ready for full operation. The experimental results are analysed and presented in this paper. Copyright The Author 2010. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oxfordjournals.org, Oxford University Press.

The use of hydrogen gas as a means of decoupling supply from demand is crucial for the transition to carbon-neutral energy sources and a greener, more distributed energy landscape. This work shows how simple commercially available titanium nitride coatings can be used to extend the lifetime of 316 grade stainless-steel electrodes for use as the cathode in an alkaline electrolysis cell. The material was subjected to accelerated ageing, with the specific aim of assessing the coating’s suitability for use with intermittent renewable energy sources. Over 2000 cycles lasting 5.5 days, an electrolytic cell featuring the coating outperformed a control cell by 250 mV, and a reduction of overpotential at the cathode of 400 mV was observed. This work also confirms that the coating is solely suitable for cathodic use and presents an analysis of the surface changes that occur if it is used anodically.

Abstract A biomass oil/diesel blend was prepared using an emulsion method and combusted in a diesel engine. An injector was then removed and the morphology, composition, and structure of the carbonaceous deposits on the pintle-type nozzle were characterized using a combination of HRTEM, SEM/EDAX, Raman and XRD. Results showed that the carbon deposition of the emulsified fuel with high crystallinity was greater than that of diesel. The agglomerated particulate diameters of the deposited carbon from diesel and emulsified fuel were approximately 10–30 μm and 50 μm, respectively. The carbon deposition mechanism from the emulsified fuel was attributed to the high oxygen content of the groups leading to increased polymerization and subsequent condensation on the nozzle surfaces that was then carbonised.