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Abstract Ammonia-based chemisorption cycle driven by low grade heat exhibits vast potential for power generation because there exists huge pressure difference between the two salt-adsorbent-filled reactors. However, the intrinsic feature of ammonia as a wet fluid and the difficult match between chemisorption cycle and expansion device impede the development of such a power generation system and also increase the difficulty of practical implementation. To explore maximum benefits of this technology, the present work has proposed and studied a new resorption power generation cycle that applies multiple expansion. The application of multiple expansion integrated with reheating processes aims to overcome the limitation of the ammonia being wet fluid and fully harness the huge pressure difference that chemisorption can offer for power generation, leading to the improvement of energy efficiency. The performance of the proposed multiple expansion resorption power generation cycle using three typical resorption salt pairs, including sodium bromide – manganese chloride, strontium chloride – manganese chloride and sodium bromide – strontium chloride, have been investigated not just based on theoretical thermodynamics but also with the consideration of practical factors to obtain better understanding and more insights for a real system design. The multiple expansion resorption power generation using sodium bromide – manganese chloride and sodium bromide – strontium chloride pairs can achieve 100–600 kJ/kg (ammonia) work output when heat source temperature is from 30 °C to 150 °C; the multiple expansion using strontium chloride – manganese chloride pair has higher average work output per one expansion stage than that using the other two pairs. The cyclic energy efficiency can be achieved as 0.06–0.15 when implementing 2–4 expansions in a more practical scenario where the equilibrium pressure drop is set to 2 bar and the heat source temperature is in the range of 80–150 °C. Such efficiencies are circa 27–62% of Carnot efficiency under the same thermal conditions.

This paper presents a one-dimensional finite-volume model of an unglazed photovoltaic/thermal (PVT) solar collector. The unit consists of a conventional solar photovoltaic (PV) collector coupled with a suitable heat exchanger. In particular, the collector includes a roll bond heat exchanger and it is not equipped with back and frame insulation. The system is discretized along the flow direction (longitudinal) of the cogenerative collector. For each finite-volume element of the discretized computational domain, mass and energy balances are implemented. The collector geometry and materials parameters are taken from a commercially available device. An on-field experimental investigation is performed in order to validate the proposed model. The model is used to evaluate both electrical and thermodynamic parameters for each element of the domain and for fixed operating conditions. Finally, a sensitivity analysis is also performed in order to investigate the energetic performance of the cogenerative collector as a function of the main design/environmental parameters.

Photosynthetic chromatophore vesicles found in some purple bacteria constitute one of the simplest light-harvesting systems in nature. The overall architecture of chromatophore vesicles and the structural integration of vesicle function remain poorly understood despite structural information being available on individual constituent proteins. An all-atom structural model for an entire chromatophore vesicle is presented, which improves upon earlier models by taking into account the stoichiometry of core and antenna complexes determined by the absorption spectrum of intact vesicles in Rhodobacter sphaeroides, as well as the well-established curvature-inducing properties of the dimeric core complex. The absorption spectrum of low-light-adapted vesicles is shown to correspond to a light-harvesting-complex 2 to reaction center ratio of 3:1. A structural model for a vesicle consistent with this stoichiometry is developed and used in the computation of excitonic properties. Considered also is the packing density of antenna and core complexes that is high enough for efficient energy transfer and low enough for quinone diffusion from reaction centers to cytochrome bc(1) complexes.

The agriculture and horticulture sector in the Netherlands is one of the most productive in the world. Although the sector is one of the most advanced and intense agricultural production systems worldwide, it faces challenges, such as climate change and environmental and social unsustainability of industrial production. To overcome these challenges, alternative food production initiatives have emerged, especially in large cities such as Amsterdam. Some initiatives involve producing food in the urban environment, supported by new technologies and practices, so-called high-tech urban agriculture (HTUA). These initiatives make cultivation of plants inside and on top of buildings possible and increase green spaces in urban areas. The emerging agricultural technologies are creating new business environments that are shape d by technology developers (e.g., suppliers of horticultural light emitting diodes (LED) and control environment systems) and developers of alternative food production practices (e.g., HTUA start-ups). However, research shows that the uptake of these technological innovations in urban planning processes is problematic. Therefore, this research analyzes the barriers that local government planners and HTUA developers are facing in the embedding of HTUA in urban planning processes, using the city of Amsterdam as a case study. This study draws on actor-network theory (ANT) to analyze the interactions between planners, technologies, technology developers and developers of alternative food production practices. Several concepts of ANT are integrated into a multi-level perspective on sustainability transitions (MLP) to create a new theoretical framework that can explain how interactions between technologies and planning actors transform the incumbent social–technical regime. The configuration of interactions between social and material entities in technology development and adoption processes in Amsterdam is analyzed through the lens of this theoretical framework. The data in this study were gathered by tracing actors and their connections by using ethnographic research methods. In the course of the integration of new technologies into urban planning practices, gaps between technologies, technology developers, and planning actors have been identified. The results of this study show a lacking connection between planning actors and technology developers, although planning actors do interact with developers of alternative food production practices. These interactions are influenced by agency of artefacts such as visualizations of the future projects. The paper concludes that for the utilization of emerging technologies for sustainability transition of cities, the existing gap between technology developers and planning actors needs to be bridged through the integration of technology development visions in urban agendas and planning processes.

Degradation issues correlated to microstructural changes are the main obstacles to solid oxide fuel cell and electrolyser applications, making their identification and understanding fundamental steps. Coupling experimental activities with modelling, this work analyses the state-of-the-art Ni-YSZ (Yttria-Stabilized Zirconia)/YSZ/CGO (Cerium Gadolinium Oxide)/LSCF (Lanthanum Strontium Cobalt Ferrite)-CGO-based cell after 1000 h of galvanostatic electrolysis operation at fixed temperature and high steam composition in the inlet gas. Following a multiscale approach, the system behaviour is characterized through electrochemical impedance spectra and polarization curves as well as studying microstructure evolution, with a focus on Ni-cermet functional layer in view of Ni instability detected as the main degradation cause. A comparison with a cell consisting of the same initial geometrical structure and materials but aged in fuel cell mode allows to highlight the influence of operating mode and parameters on Ni-YSZ microstructure. Ni particle size and phase fraction variations experimentally observed on the electrode surface are correlated to water content and applied polarization simulated local values. Ni uneven distribution at the electrolyte interface and particle coarsening, above all, lead to an increase in polarization loss under electrolysis and fuel cell mode, respectively, since both penalise the charge transfer reaction and migration.

The implementation of agroecology principles within organic farming research is a crux to redesign sustainable agri-food systems. To govern this transition, the local research demand should be addressed by direct engagement of all stakeholders in the research process. The first step is the involvement of farmers and technicians, with the aim of restoring their decision-making role, switching governance to local scale. The co-design/co-management of Long-Term Experiments (LTEs) can be crucial to govern the above-described transition through networking and participatory activities. In this study, we report the experience of co-designing a new LTE in Southern Italy by local actors and scientists. Through a participatory action research methodology, an LTE was considered as a biophysical component of an agroecological living lab, a public–private environment aimed to design a local food system. The setup of parallel field trials in satellite farms stands for the other biophysical component, whereas the stakeholder platform represents the social one. Through definition of common objectives, a step-by-step process is presented, which highlights the interest of local organic actors to share ideas and perspectives for the territory, pointing out the inclusion of end-users (the consumers) in the process to complete the transition to sustainable food systems.