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In this paper the removal of a wide range of heavy metal ions from different chemical environments has been explored with the use of phosphate-functionalised superparamagnetic iron oxide nanoparticles (SPIONs), specifically magnetite (Fe3O4).

Abstract Energy system modelling can be used to assess the implications of different scenarios and support improved policymaking. However, access to data is often a barrier to starting energy system modelling in developing countries, thereby causing delays. This article therefore provides data that can be used to create a simple zero order energy system model for Mauritania, which can act as a starting point for further model development and scenario analysis. The data are collected entirely from publicly available and accessible sources, including the websites and databases of international organizations, journal articles, and existing modelling studies. This means that the dataset can be easily updated based on the latest available information or more detailed and accurate local data. These data were also used to calibrate a simple energy system model using the Open Source Energy Modelling System (OSeMOSYS) and two stylized scenarios (Fossil Future and Least Cost ) for 2020-2050. The assumptions used and results of these scenarios are presented in the appendix as an illustrative example of what can be done with these data. This simple model can be adapted and further developed by in-country analysts and academics, providing a platform for future work.

Abstract Post-combustion solvent-based carbon capture is a promising technology that potentially can offset the greenhouse gas emissions from fossil-driven power generation systems. The challenge is that CO2 absorption (similar to other CCS technologies) imposes energetic penalties, and constrains the operational flexibility. In this paper, we build upon our recent contributions in the field (Sharifzadeh et al., 2016; Sharifzadeh and Shah, 2016), and study the dynamic response of such process to the electricity load changes in the power plant. The key research question is to investigate if the steady-state integrated process design and control framework applied in the previous studies, can also ensure controllability under a wide range of disturbances. The present study considers the mutual interactions between the power plant and capture process. Other features of interest include the implications of key design and operational decisions such as reboiler temperature, solvent circulation flow rate, solvent concentration and the rate of power load change or CO2 setpoint tracking for flexible process operation. The results suggest that the capture process exhibits a high degree of flexibility and the integrated design and control framework could be the key enabler for the commercialization of post-combustion solvent-based carbon capture.

[EN] The objective of this article is to compare the behaviour of the most representative domestic hot water systems (DHW) in single-family buildings. The study evaluates the energy consumption, equivalent CO2 emissions and cost for each system over a 15-year life period. This analysis is carried out in four cli- matic zones across Europe to observe the influence of climatic conditions on the results. The four climatic zones are located in the cities of Athens, Madrid, London and Berlin. The analysed systems are: a) natural gas-fired instantaneous water heaters, b) electric storage water heater, c) solar thermal system with gas- fired instantaneous, d) solar thermal system with electric storage water heater, e) air-source heat pump, f) photovoltaic system with electric storage water heater, and g) photovoltaic system with air-source heat pump. This range of technologies covers the most likely solutions to be implemented across domestic buildings in Europe.The heat pump system (HPWH) with PV considering self-consumption shows the lowest environmen- tal impact in all zones, but is not an attractive investment in the coldest zones due to lower natural gas prices. Thermal solar systems have a high purchase and maintenance costs which do not compensate their energy savings. The PV HPWH system has a greater reduction of emissions and a lower cost than HPWH across a 15-year life. The gas boiler system has the lowest cost in a 15-year period in the coldest areas, despite having a greater environmental impact than the heat pump.(c) 2023 Elsevier B.V. All rights reserved.

Abstract Diagnosing the state-of-health of lithium ion batteries in-operando is becoming increasingly important for multiple applications. We report the application of differential thermal voltammetry (DTV) to lithium iron phosphate (LFP) cells for the first time, and demonstrate that the technique is capable of diagnosing degradation in a similar way to incremental capacity analysis (ICA). DTV has the advantage of not requiring current and works for multiple cells in parallel, and is less sensitive to temperature introducing errors. Cells were aged by holding at 100% SOC or cycling at 1C charge, 6D discharge, both at an elevated temperature of 45 °C under forced air convection. Cells were periodically characterised, measuring capacity fade, resistance increase (power fade), and DTV fingerprints. The DTV results for both cells correlated well with both capacity and power, suggesting they could be used to diagnose SOH in-operando for both charge and discharge. The DTV peak-to-peak capacity correlated well with total capacity fade for the cycled cell, suggesting that it should be possible to estimate SOC and SOH from DTV for incomplete cycles within the voltage hysteresis region of an LFP cell.

Whether the thermal sensitivity of an organism's traits follows the simple Boltzmann-Arrhenius model remains a contentious issue that centers around consideration of its operational temperature range and whether the sensitivity corresponds to one or a few underlying rate-limiting enzymes. Resolving this issue is crucial, because mechanistic models for temperature dependence of traits are required to predict the biological effects of climate change. Here, by combining theory with data on 1,085 thermal responses from a wide range of traits and organisms, we show that substantial variation in thermal sensitivity (activation energy) estimates can arise simply because of variation in the range of measured temperatures. Furthermore, when thermal responses deviate systematically from the Boltzmann-Arrhenius model, variation in measured temperature ranges across studies can bias estimated activation energy distributions toward higher mean, median, variance, and skewness. Remarkably, this bias alone can yield activation energies that encompass the range expected from biochemical reactions (from ~0.2 to 1.2 eV), making it difficult to establish whether a single activation energy appropriately captures thermal sensitivity. We provide guidelines and a simple equation for partially correcting for such artifacts. Our results have important implications for understanding the mechanistic basis of thermal responses of biological traits and for accurately modeling effects of variation in thermal sensitivity on responses of individuals, populations, and ecological communities to changing climatic temperatures.

Les développements des systèmes de transport, les changements dans les tendances de consommation et des conditions telles que la COVID-19 ont augmenté à la fois la demande et la charge du transport de marchandises. Étant donné que diverses entreprises transportent des marchandises dans le monde entier pour évaluer la durabilité, la vitesse et la résilience des systèmes de transport de marchandises, des systèmes de mesure de la fluidité des données et du fret sont nécessaires. Dans cette étude, un modèle de prise de décision intégré est proposé pour donner la priorité aux alternatives de mesure de la fluidité du fret. Le modèle proposé est composé de deux étapes principales. Dans la première étape, la méthodologie logarithmique des poids additifs (LMAW) basée sur les normes de Dombi est utilisée pour trouver les poids des critères. Dans la deuxième phase, une évaluation étendue basée sur la méthode de la distance de la solution moyenne (EDAS) avec Dombi onction pour l'agrégation est présentée pour déterminer les résultats finaux de classement des alternatives. Trois alternatives de mesure de la fluidité du fret sont proposées, à savoir ne rien faire, intégrer les activités de fret dans Metaverse pour mesurer la fluidité et former une gouvernance mondiale des activités de fret pour mesurer la fluidité à partir des données disponibles. Treize critères, qui sont regroupés sous quatre aspects principaux à savoir la technologie, la gouvernance, l'efficacité et la durabilité environnementale, et une étude de cas au cours de laquelle un cadre de base est formé pour que les experts évaluent les alternatives compte tenu des critères utilisés dans le processus décisionnel multicritères. Les résultats de l'étude indiquent que l'intégration des activités de fret dans Metaverse pour mesurer la fluidité est l'alternative la plus avantageuse, alors que ne rien faire est la moins avantageuse. Los desarrollos en los sistemas de transporte, los cambios en las tendencias de consumismo y condiciones como el COVID-19 han aumentado tanto la demanda como la carga en el transporte de mercancías. Dado que varias empresas transportan mercancías en todo el mundo para evaluar la sostenibilidad, la velocidad y la resistencia de los sistemas de transporte de mercancías, se necesitan sistemas de medición de datos y fluidez de la carga. En este estudio, se propone un modelo integrado de toma de decisiones para priorizar las alternativas de medición de la fluidez de la carga. El modelo propuesto se compone de dos etapas principales. En la primera etapa, se utiliza la Metodología Logarítmica de Pesos Aditivos (LMAW) basada en normas Dombi para encontrar los pesos de los criterios. En la segunda fase, se presenta una Evaluación extendida basada en el método de Distancia de la Solución Media (EDAS) con Dombi unción para la agregación para determinar los resultados finales de clasificación de las alternativas. Se proponen tres alternativas de medición de la fluidez de la carga, a saber, no hacer nada, integrar las actividades de carga en Metaverse para medir la fluidez y formar una gobernanza global de las actividades de carga para medir la fluidez a través de los datos disponibles. Trece criterios, que se agrupan en cuatro aspectos principales: tecnología, gobernanza, eficiencia y sostenibilidad ambiental, y un estudio de caso en el que se forma un marco básico para que los expertos evalúen las alternativas considerando que los criterios se utilizan en el proceso de toma de decisiones multicriterio. Los resultados del estudio indican que integrar las actividades de carga en Metaverso para medir la fluidez es la alternativa más ventajosa, mientras que no hacer nada es la menos ventajosa. Developments in transportation systems, changes in consumerism trends, and conditions such as COVID-19 have increased both the demand and the load on freight transportation. Since various companies are transporting goods all over the world to evaluate the sustainability, speed, and resiliency of freight transportation systems, data and freight fluidity measurement systems are needed. In this study, an integrated decision-making model is proposed to advantage prioritize the freight fluidity measurement alternatives. The proposed model is composed of two main stages. In the first stage, the Dombi norms based Logarithmic Methodology of Additive Weights (LMAW) is used to find the weights of criteria. In the second phase, an extended Evaluation based on the Distance from Average Solution (EDAS) method with Dombi unction for aggregation is presented to determine the final ranking results of alternatives. Three freight fluidity measurement alternatives are proposed, namely doing nothing, integrating freight activities into Metaverse for measuring fluidity, and forming global governance of freight activities for measuring fluidity through available data. Thirteen criteria, which are grouped under four main aspects namely technology, governance, efficiency, and environmental sustainability, and a case study at which a ground framework is formed for the experts to evaluate the alternatives considering the criteria are used in the multi-criteria decision-making process. The results of the study indicate that integrating freight activities into Metaverse for measuring fluidity is the most advantageous alternative, whereas doing nothing is the least advantageous one. أدت التطورات في أنظمة النقل، والتغيرات في اتجاهات النزعة الاستهلاكية، وظروف مثل COVID -19 إلى زيادة الطلب والحمل على نقل البضائع. نظرًا لأن العديد من الشركات تنقل البضائع في جميع أنحاء العالم لتقييم استدامة وسرعة ومرونة أنظمة نقل البضائع، فهناك حاجة إلى أنظمة قياس سيولة البيانات والشحن. في هذه الدراسة، يُقترح نموذج متكامل لصنع القرار للاستفادة من إعطاء الأولوية لبدائل قياس سيولة الشحن. يتكون النموذج المقترح من مرحلتين رئيسيتين. في المرحلة الأولى، يتم استخدام منهجية لوغاريتمية الأوزان المضافة (LMAW) القائمة على معايير دومبي لإيجاد أوزان المعايير. في المرحلة الثانية، يتم تقديم تقييم موسع يعتمد على طريقة المسافة من الحل المتوسط (EDAS) مع Dombi unction للتجميع لتحديد نتائج الترتيب النهائي للبدائل. يتم اقتراح ثلاثة بدائل لقياس سيولة الشحن، وهي عدم القيام بأي شيء، ودمج أنشطة الشحن في ميتافيرس لقياس السيولة، وتشكيل حوكمة عالمية لأنشطة الشحن لقياس السيولة من خلال البيانات المتاحة. ثلاثة عشر معيارًا، تم تجميعها تحت أربعة جوانب رئيسية وهي التكنولوجيا والحوكمة والكفاءة والاستدامة البيئية، ودراسة حالة يتم فيها تشكيل إطار أرضي للخبراء لتقييم البدائل مع مراعاة استخدام المعايير في عملية صنع القرار متعددة المعايير. تشير نتائج الدراسة إلى أن دمج أنشطة الشحن في ميتافيرس لقياس السيولة هو البديل الأكثر فائدة، في حين أن عدم القيام بأي شيء هو البديل الأقل فائدة.

Layered O3-phase LiNi0.8Co0.1Mn0.1O2 (NCM811) material has shown great potential for lithium-ion batteries (LIBs). However, capacity attenuation and irreversible phase transitions have been serious...