• Energy Research
• Restricted close
• Open Source close
• 13. Climate action close
• HK close

Abstract The early diagenetic characteristics of pyrite formation processes in a Miocene freshwater sequence of mixed sediments (coal fragments in clays, sandstones or shales) alternating with continuous brown coal layers was investigated. Based on abundant minerals, the following main sedimentary environments were distinguished: the illite-montmorillonitic (I-M), calcitic (Ct) and coal-forming environment (CL). For these hydrogeochemically differing environments the effects of limiting factors on the pyrite formation process (availability of sulphate and Fe, amount of organic matter and participation of organic sulphur) were assessed by correlation analysis. Significant differences in the effects of these limiting factors in the particular environments were observed. These differences were explained taking in account the different oxidative activity, Fe-complex and surface complex forming properties of humic substances in dependence of pH of environment and the abundance of sorptionally active clay minerals. In environments having a relatively low pH and containing clay minerals (I-M-and CL-environments) the oxidative activity of humic substances (Hs) on pyrite precursors was greatly prevented however pyrite formation depended on reactive Fe availability as the consequence of complex formation. On the contrary, in environments with a relatively high pH, as it was the calcitic, the oxidative activity of Hs was greatly enhanced, thus oxidizing the sulfur precursors of pyrite. The oxidation degree of organic matter was probably also a consequence of the differing activity of the humic electron-acceptors.

The concept of sustainability and sustainable development has been widely incorporated in energy and industrial systems. This paper is the second part of a two-paper series dealing with multi-actor multi-criteria sustainability assessment of alternative energy and industrial systems in life cycle perspective under uncertainties. The criteria system including four macroscopic aspects (environmental, safety, social and economic aspects) has been developed for sustainability assessment of energy and industrial systems. An improved extension theory which can address interval decision-making matrix has been developed for determining the sustainability degree of the energy and industrial systems. The weights of the criteria for sustainability assessment are the first part of the two-paper series. An illustrative case has been studied by the proposed multi-criteria decision-making method, and the sustainability of six alternative options for the production of a 1-t product was investigated. The sustainability degree of these six alternative options can be determined by the proposed method. A methodology for multi-actor multi-criteria sustainability assessment of energy and industrial options has been developed in this study, the traditional extension theory has been modified to deal with the uncertainty problems and the proposed method can rank the alternative energy and industrial systems with the decision-making matrix in which the data of the alternatives with respect to the evaluation criteria are intervals. In the improved extension theory, sustainability has been dived into five grades: excellent, good, satisfied, barely adequate and fail. According to the method for calculating the weights of the criteria for sustainability assessment proposed in part 1, these weights were used to calculate the integrated dependent degree which is a measure of what degree an alternative belongs to the classical fields. An optimal programming model for maximizing the satisfied degree has been developed to rank the sustainability sequence of the alternative options and determine the sustainability degree of each alternative.