• Energy Research
• 7. Clean energy close
• 2. Zero hunger close
• HR close

We are witnesses of excessive depletion of natural resources, climate change and a loss of biodiversity. Water, air, soil, light and noise pollution is increasing. At the end the quality of life is worsening as well. Interdisciplinary approach is needed. Economy and chemistry are two different scientific areas, which facing environmental challenges develop divergently. The results are that we have green economy and green chemistry; we deal with complex problems sharing our knowledge and supporting each other. Green chemistry is a new paradigm that provides solutions to contemporary environmental, ecological and sustainable challenges. The aim of the paper is to present approaches of green economy and green chemistry, collaborations between them and integrative effort in solving environmental challenges toward sustainability. The goal is to present examples of green business based on green chemistry. Methodology encompasses case studies of companies with green business. This paper contributes to existing research in three ways: it spreads knowledge and good business experiences, it shows long term benefits and it raises awareness of a paradigm shift towards ecology and sustainability.

Abstract Advanced combustion engine (ACE) research is typically carried out on single-cylinder research engines. These engines are designed to tightly control fueling and conditions at intake valve closure (IVC) and to precisely measure in-cylinder conditions and emissions. However, to be able to measure and control engine operation so precisely, these research engines typically do not feature intake and exhaust tracts that resemble those in production engines, specifically in regards to turbomachinery, heat exchangers, and exhaust gas recirculation (EGR) systems. For this reason, these research engines are effective for understanding in-cylinder combustion parameters such as heat release rate, burn duration, combustion efficiency, pollutant formation, and exhaust valve opening (EVO) conditions. This paper applies high fidelity simulations to determine the feasibility of achieving a chosen single cylinder engine operating point on a production type homogeneous charge compression ignition (HCCI) engine, using a partial fuel stratification (PFS) strategy. To accomplish this, a Converge 3 dimensional (3D) – computational fluid dynamics (CFD) model of the experimental combustion chamber and intake and exhaust runners was created to simulate the experimental engine. This model was used to simulate an operating point achieved experimentally, as well as to determine the sensitivity of the operating point to variations in intake pressure, intake temperature, injection timing, injected mass, and EGR fraction. The results from these simulations were fed into a 1-dimensional engine simulation created in AVL Boost, featuring production-type intake and exhaust systems, including turbomachinery and heat exchangers necessary to create the required IVC conditions. This full engine simulation was used to assess the cycle efficiency of the engine at the experimental operating condition, and to assess whether changes to this operating point in intake temperature, intake pressure, direct injection timing, or fueling are beneficial to the cycle efficiency and engine-out emissions. In addition, the sensitivity of promising engine operating points to injection timing and injection mass are determined to evaluate the potential stability of these operating points.

Maize silage is the main forage for ruminant livestock in Croatia. Production of substances determines quality of ensiling during the process and, therefore, has an impact on nutritive value, consumption, and health of cattle. Since in Croatia there is no systematic research of ensiling quality, this study aimed to determine quality parameters values of maize silage from large farms in continental Croatia during the spring of 2016. In total 33 samples of maize silage were representatively sampled by taking silage from the entire cross-section of the silo. Selected quality parameters included dry matter (DM) and ash contents, pH and titratable acidity, water holding capacity, particle size of the whole silage and separated grains, and aroma according to the "Sil-All for corn silage" (Danstar Ferment Ag, Switzerland). Nearly half of the analyzed samples had DM content outside the optimal range (300 – 400 g*kg-1). The pH value of silages was within the optimal range (3.5 – 4.2) which indicated that the active phase of ensiling was properly done. However, two-thirds of samples had an undesirable aroma which indicated changes of fermentation products occurred during the stable phase. Titratable acidity of tested silages, with a range from 11.61 to 128.93 meqv. NaOH*100 g-1 DM, indicated their different buffering properties in the rumen. Water holding capacity varied from 4.4 to 8.57 g*g-1 DM and this range implied variable fiber content in analyzed samples. Grain content in silages ranged from 23.86 to 45.05% whereas its geometric particle size was in a range from 2.15 to 4.3 mm. When considering particle distribution of whole silage on PSPS (Penn State Forage Particle Separator) sieves, a half or more than half samples had content on individual sieves outside the optimal ranges. In conclusion, maize silages on large dairy and fattening farms in continental Croatia are very variable in quality and, in many parameters, of lower quality than the standards implying that more attention must be given to the silage production procedures.

Bioenergy villages can be defined as villages, municipalities, settlements or communities, which produce and use most of their energy from local bioenergy and other renewable energy sources. A bioenergy village approach has not been applied in Macedonia yet, and it is at a nascent stage of implementation in other South-Eastern European countries. This work aims to integrate a techno-economic, social and environmental assessment and an implementation strategy into a bioenergy village concept, which is not often seen in works dedicated to bioenergy villages and biomass based heating systems. The assessment was conducted by means of energy audit and project-related tools, whilst the strategy was composed by bioenergy working group meetings. Results show that a biomass based district heating system is a more attractive solution for heating several public buildings instead of a fossil fuelled system, with numerous associated benefits. Such concepts can be replicated with variety of renewables, thus contributing to sustainable development pathways of small communities.

This paper elaborates different hybrid energy scenarios for applications in small or medium residential building facilities in typical Mediterranean climate conditions. Proposed hybrid energy solutions are based on the split air conditioning units as they are the most used individually energy sources able to cover heating and cooling demands in residential building facilities in considered climate conditions. Four different hybrid energy options have been analysed as they represent highly efficient energy solutions that could reduce overall energy consumption as well as also carbon dioxide emissions from residential sector. For each proposed energy solution a technical aspect was addressed, as well as also an economic aspect through obtained LCOE analysis. Therefore, the proposed and analysed hybrid energy concepts turned out to be a viable energy solution for residential applications as calculated LCOE was competitive with current retail prices of electricity on the EU market. The calculated LCOE ranged from 0.036 €/kWh up to 0.159 €/kWh, depending from the considered hybrid energy solution. The solution with the modified split heat pump system turned out to be most favourable. However, as each solution is characteristic one an additional evaluation framework was developed. Finally, the results of this study could be useful as examples of good practice as well as also a useful guidance for policy makers.

AbstractThe operating experience feedback is important for maintaining and improving safety and availability in nuclear power plants. Detailed investigation of all events is challenging since it requires excessive resources, especially in case of large event databases. This paper presents an event groups ranking method to complement the analysis of individual operating events. The basis for the method is the use of an internationally accepted events characterization scheme that allows different ways of events grouping and ranking. The ranking method itself consists of implementing the analytical hierarchy process (AHP) by means of a custom developed tool which allows events ranking based on ranking indexes pre-determined by expert judgment. Following the development phase, the tool was applied to analyze a complete set of 5 years of real nuclear power plants operating events (1453 events). The paper presents the potential of this ranking method to identify possible patterns throughout the event database and therefore to give additional insights into the events as well as to give quantitative input for the prioritization of further more detailed investigation of selected event groups.

Sustainable management of agricultural resources is needed to meet people’s increasing demands for food, fiber and energy while maintaining the quality of the environment and protecting natural resources. With the rapid growth of agriculture and the mechanization of farming, the agricultural sector has become one of the main contributors to the increase in CO2 emissions and other greenhouse gases in the world. Therefore, the aim of this study was to determine the effect, dependence and correlations of CO2 in soil with native vegetation (presence/absence, corn yield) and climatic conditions (soil temperature and moisture) during three years of measurements under different management practices in a classical conventional agroecosystem. This research contains four different treatments: control treatment (CT), dolomite/organic fertilization (DOL/OF), mineral fertilization (MF) and black fallow (BF). During the investigated period, the average overall C-CO2 flux ranged from 7.98 kg ha−1 day−1 on bare soil to 16.26 kg ha−1 day−1 on soil treated with mineral fertilization. No statistically significant difference was observed among different fertilization treatments, except in 2013 and 2015 when comparing different fertilization treatments to bare soil. In all three years, there was a positive correlation between average C-CO2 fluxes and soil temperature. Additionally, in 2013 and 2017, there was a positive correlation between average C-CO2 fluxes and soil moisture, while a negative correlation was observed in 2015. Obtained values of crop yield ranged from 0.89 t ha−1 in the control treatment (in 2015) to 14.81 t ha−1 in the treatment with mineral fertilization (in 2017). Growing global concern about the effects of climate change calls for intensive research on the carbon cycle, and these results will contribute to the understanding of carbon transformation in different crops and soil management practices.

Accelerating the development of renewable energy is seen as an effective way for achieving the goals of carbon peak and carbon neutrality. The polices of Renewable Electricity Standard (RES) and Renewable Energy Certificates (REC) play increasing and important roles in developing renewable energy. In this paper, we develop an analytical model to analyze the impacts of the interaction of RES and REC polices on the renewable energy investment levels of an electricity generation firm and the carbon emissions. Our analysis reveals several interesting insights. First, we find that the green tags price under REC policy has a non-monotonic effect on the renewable energy investment, which highly depends on the quota (i.e., the required percentage of renewable electricity consumption on total electricity consumption) under the RES policy. Specifically, when the quota in RES policy is set too high, an increase in the green tags price will increase renewable energy investment; otherwise it will reduce the electricity generation firm's incentive to invest in renewable energy. Second, we show that the green tags price also has a non-monotonic effect on the carbon emissions. Specifically, when the quota in RES policy is set small enough, an increase in the green tags price will decrease the carbon emission. However, when the quota in RES policy is high enough, an increase in the green tags price will increase the carbon emission.