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Drying experiments have been performed with potato cylinders and slices using a laboratory scale designed natural convection mixed-mode solar dryer. The drying data were fitted to eight different mathematical models to predict the drying kinetics, and the validity of these models were evaluated statistically through coefficient of determination (R(2)), root mean square error (RMSE) and reduced chi-square (χ (2)). The present investigation showed that amongst all the mathematical models studied, the Modified Page model was in good agreement with the experimental drying data for both potato cylinders and slices. A mathematical framework has been proposed to estimate the performance of the food dryer in terms of net CO2 emissions mitigation potential along with unit cost of CO2 mitigation arising because of replacement of different fossil fuels by renewable solar energy. For each fossil fuel replaced, the gross annual amount of CO2 as well as net amount of annual CO2 emissions mitigation potential considering CO2 emissions embodied in the manufacture of mixed-mode solar dryer has been estimated. The CO2 mitigation potential and amount of fossil fuels saved while drying potato samples were found to be the maximum for coal followed by light diesel oil and natural gas. It was inferred from the present study that by the year 2020, 23 % of CO2 emissions can be mitigated by the use of mixed-mode solar dryer for drying of agricultural products.

Environment-friendly treatment of sewage sludge has become tremendously important. Conversion of sewage sludge into energy products by environment-friendly conversion process, with its energy recovery and environmental benefits, is being paid significant attention. Direct liquefaction of sewage sludge into bio-oils with supercritical water (SCW) was therefore put forward in this study, as de-water usually requiring intensive energy input is not necessary in this direct liquefaction. Supercritical water may act as a strong solvent and also a reactant, as well as catalyst promoting reaction process. Experiments were carried out in a self designed high-pressure reaction system with varying operating conditions. Through orthogonal experiments, it was found that temperature and residence time dominated on bio-oil yield compared with other operating parameters. Temperature from 350 to 500°C and reaction residence time of 0, 30, 60min were accordingly investigated in details, respectively. Under supercritical conversion, the maximum bio-oil yield could achieve 39.73%, which was performed at 375°C and 0min reaction residence time. Meanwhile, function of supercritical water was concluded. Fuel property analysis showed the potential of bio-oil application as crude fuel.

Abstract This study investigates the non-linear relationship between urbanization paths and CO2 emissions in selected South, South-East, and East Asian countries over the period 1971–2014. Based on the STIRPAT (Stochastic Impacts by Regression on Population, Affluence, and Technology) framework, we applied the advanced and robust methods of dynamic seemingly unrelated regression (DSUR), dynamic OLS (DOLS), and fully modified OLS (FMOLS) to estimate the long-term effects. The empirical findings revealed the inverted U-shaped effects of urbanization and urban agglomeration and the U-shaped impact of the largest city ratio on CO2 emissions. Urbanization and urban agglomerations improve environmental quality in the long-run and support ecological modernization theory. However, excessive concentration in the largest cities have severely affected the environmental quality and violates the notion of compact-city efficiencies. Moreover, energy intensity and economic growth positively affect CO2 emissions, while trade openness negatively influences CO2 emissions. Our robustness analysis at the country-level applies the augmented mean group (AMG) panel ARDL technique, which further supports the non-linear effect of urbanization paths on CO2 emissions except for a few countries. The results of the panel Granger non-causality approach unveil bidirectional causality of energy efficiency, economic growth, urbanization, and largest city ratio with CO2 emissions. In contrast, unidirectional causality runs from urban agglomeration to CO2 emissions. Our findings have important policy implications as we suggest green urban infrastructures, eco-friendly dwellings, smart cities, country-specific trade policies, and renewable energy options to improve the environmental quality.

Abstract As a burgeoning theoretical framework, energy justice has been mostly focused on the energy transition in Western countries, where socio-political settings are largely featured by liberalism and democracy, leaving an obvious gap in its application in other socio-political contexts. As a major energy consumer and a leader of the global low-carbon transition, China is characterized by a distinctive socio-political regime. An array of grand strategies to transform its coal-dominant energy structure have been initiated to ameliorate deteriorating environmental crises in particular and materialize a low-carbon transition in general. Based on extensive evidence, this article incorporates the energy justice framework into the analysis of an ongoing energy transition project in rural Northern China. It contributes to the related research in three dimensions. First, empirically, it demonstrates that the coal-to-gas heating transition project has been swamped with social injustices; the absence of measures to address these would lead this mega-project to profound failure. Second, theoretically, it illustrates that the concerns of justice are even more paramount in an authoritarian context where policy processes are characterized by strong political-administrative intervention and the pursuit of efficiency at all cost. In light of this, it stresses the indispensable role of restorative justice as a core tenet in achieving energy justice in authoritarian socio-political contexts, such as China. Third, this study advocates expanding the evaluation parameters of authoritarian environmentalism to include social consequences.

Abstract The main hindrances to the large-scale development of renewable-energy projects are the lack of bankability and the inability to align investments and investors with suitable financial instruments or robust policy measures. To illustrate a bankable project, this paper presents a research-based case study on the installation of solar photovoltaic panels on the rooftops of 195 trains of the Indian Railways. Detailed information on the annual running hours, exposure to sunlight, efficiency of solar photovoltaic generation and electrical power demands of each rail coach is considered to conduct a quantitative measure of the tentative amount of fossil fuel savings. The purpose is to provide insight into the types of renewable-energy projects that can be highly attractive to financial institutions and promoters due to their lucrative internal return on investment. As seen in this case study, there are annual savings in diesel of 12 323 088 litres and a CO2 reduction of 32 755 tonnes, with return on investment of 1.3 years. Furthermore, this study conducts a comprehensive analysis of the limitations of existing renewable-energy project financing mechanisms in India. Subsequently, three policy measures are recommended to develop a robust financial mechanism that can effectively meet the needs of investors and investors. These measures include increasing equity injection through a buy-and-hold strategy, providing direct tax benefits to promoters and financing through real-estate investment trusts. The findings are highly relevant to address the challenges associated with bridging the financial gap between access to finance and capital investment in the renewable-energy sector, especially for Asian countries.

Vegetable oil and animal fat derived fatty acid methyl esters are commonly known as biodiesel and provide an environment friendly and renewable substitute for the conventional diesel fuel. The present work demonstrates an easy preparation of potassium ion impregnated calcium oxide in nano crystalline form (supported by powder X-ray diffraction and transmission electron microscopic studies) and its application as a solid catalyst for the transesterification of waste cottonseed oil with methanol. The catalyst prepared by impregnating 3.5 wt% of potassium in CaO support was found to show the best catalytic activity among the prepared catalysts. The same catalyst was found to be effective for the complete transesterification of less expensive feedstock, waste cotton seed oil, even in the presence of 10.26 wt% moisture and 4.35 wt% free fatty acid contents. The selected catalyst has also been reused successfully for three catalytic cycles. Few physicochemical properties of the prepared biodiesel sample have been studied and found to be within the acceptable limits of EN 14214 standards.

The pyrolysis of waste disposable paper cups (WDPCs) was investigated using a thermogravimetric analyser coupled with a Fourier transform infrared spectrometer. The activation energies of the pyrolysis reactions were obtained by the Flynn–Wall–Ozawa (FWO) and Kissinger–Akahira–Sunose (KAS) methods respectively. The kinetic model was determined by the master plots method. Thermogravimetric results showed that the highest weight loss rate occurred from 345 to 365 °C as the heating rate was increased from 10 to 30 °C min−1, indicating the pyrolysis of cellulosic material in the WDPC. The weight loss between 400 and 500 °C can be attributed to the decomposition of polyethylene. By analysing the FTIR spectra, it was found that the absorbance of all the evolved gaseous products had peaks at 360 °C due to the decomposition of cellulose fibres and the cracking of polyethylene at 485 °C led to the emergence of a second hydrocarbon peak. Ketones were the most abundant condensable organic products and CO2 was the dominating gaseous product, which can also be produced via secondary cracking of the small molecule organics above 400 °C. Kinetic analysis revealed that the average activation energy of the pyrolysis of the WDPC was 153.75 kJ mol−1 from the FWO method and 151.43 kJ mol−1 from the KAS method. The reaction mechanism can be described by the R3 model.

Abstract The Renewable energy power generation capacity has been rapidly increasing in China recently. Meanwhile, the contradiction between power supply and demand is becoming increasingly more prominent due to the intermittence of renewable energies. On the other hand, on the mitigation of carbon dioxide (CO2) emissions in China needs immediate attention. Power-to-Gas (PtG), a chemical energy storage technology, can convert surplus electricity into combustible gases. Subsurface energy storage can meet the requirements of long term storage with its large capacity. This paper provides a discussion of the entire PtG energy storage technology process and the current research progress. Based on the comparative study of different geological storage schemes for synthetic methane, their respective research progress and limitations are noted. In addition, a full investigation of the distribution and implementation of global PtG and CO2 capture and storage (CCS) demonstration projects is performed. Subsequently, the opportunities and challenges of the development of this technology in China are discussed based on techno-economic and ecological effects analysis. While PtG is expected to be a revolutionary technology that will replace traditional power systems, the main issues of site selection, energy efficiency and the economy still need to be adequately addressed. Additionally, based on the comprehensive discussion of the results of the analysis, power-to-gas and subsurface energy storage implementation strategies, as well as outlook in China are presented.

Abstract Hydrothermal treatment (HT) is one of the efficient approaches for upgrading municipal solid waste (MSW). In the present study, emission characteristics of polycyclic aromatic hydrocarbons (PAHs) from hydrothermally treated municipal solid waste (H-MSW) combustion alone and H-MSW/coal co-combustion were investigated at different temperatures. The results showed that for all fuel combustion, the majority of PAHs were 3- or 4-ring PAHs. In addition, flue gas had the highest yields of PAHs followed by fly ash and bottom ash, while the ring number of dominated PAHs in fly ash was higher than those in flue gas and bottom ash. Compared to MSW, H-MSW combustion generated less PAHs at the value of 1131.95–7649.24 μg/g. The blending of H-MSW and coal reduced total PAH emissions and positive interactions were observed between H-MSW and coal during co-combustion. The toxicity equivalent quantity (TEQ) values of the PAHs from combustion were in the order MSW > H-MSW > H-MSW/coal, which was consistent with the total PAH emissions. The present study illustrated that significant reduction of PAH emissions and toxicity from combustion could be achieved by HT and the blending of H-MSW and coal.