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Binary and ternary systems of Ni(2+), Zn(2+), and Pb(2+) were investigated at initial metal concentrations of 0.5, 1.0 and 2.0mM as competitive adsorbates using Arthrospira platensis and Chlorella vulgaris as biosorbents. The experimental results were evaluated in terms of equilibrium sorption capacity and metal removal efficiency and fitted to the multi-component Langmuir and Freundlich isotherms. The pseudo second order model of Ho and McKay described well the adsorption kinetics, and the FT-IR spectroscopy confirmed metal binding to both biomasses. Ni(2+) and Zn(2+) interference on Pb(2+) sorption was lower than the contrary, likely due to biosorbent preference to Pb. In general, the higher the total initial metal concentration, the lower the adsorption capacity. The results of this study demonstrated that dry biomass of C. vulgaris behaved as better biosorbent than A. platensis and suggest its use as an effective alternative sorbent for metal removal from wastewater.

Abstract A simple transient analytical approach has been adopted for developing an explicit expression for the water temperature of an indoor swimmingpool coupled to a panel of collectors. For qualitative assessment of the analytical results, computations have been made for the winter climatic conditions of Sri Nagar, India. The effects of several parameters, viz. inlet temperature, heat removal factors, collector, etc. on the performance of the proposed systems have been studied in detail. It is observed that (i) the proposed model agrees with the experimental results of the Australian passive solar swimming pool and (ii) the desired temperature for the indoor swimming pool can be achieved by the active method.

Abstract Anaerobic digestion (AD) technology has piqued scientists’ interest in light of the growing demand for renewable energy and environmental preservation. This paper discusses the analysis of national biogas producing capacity, energy demand, and methods for meeting that demand. Also, public health and environmental issue, biogas technology and their utilization, current national scenario, and future in the biogas field have been discussed. The Government of India (GOI) has been providing subsidies or financial support through various programs. They support the rural area for generating biogas and also announced the Sustainable Alternative Towards Affordable Transportation (SATAT) initiative for the generation of compressed biogas (CBG) for the installation of 5000 plants up to 2023-24. These plants are expected to produce 15 million metric tonnes (MMT) of CBG per annum, which is about 40% of the current compressed natural gas (CNG) consumption of 44 MMT per annum in the region.

In this study, a novel two-step integrated process is proposed to facilitate the microalgae biofuel production as well as fresh cheese whey wastewater (FCWW) treatment simultaneously. The pre- and post-treatment of high-strength FCWW were performed by means of coagulation and algal cultivation, respectively. The pre-treatment of FCWW for maximum removal of chemical oxygen demand (COD), turbidity (TUR) and total solids (TS) as responses was obtained by statistical optimization of coagulation parameters. The maximum removal of COD, TUR and TS at the optimum level of variables was obtained as 68.09%, 47.80% and 73.63%, respectively. The pre-treated FCWW was further treated by Chlorella pyrenoidosa and observed a significant reduction in the above-mentioned responses (87-94%). The maximum algal biomass yield and lipid productivity were observed as 2.44 g L-1 and 77.41 mg L-1 day-1, respectively. Based on promising results of FCWW treatment and its use as a third-generation biodiesel feedstock, a cost-benefit analysis of the developed process was assessed for microalgal oil production. The total profit earned by the integrated process model was $9.59 million year-1. Accordingly, the estimated production cost of algal oil (TAG) from the developed system was estimated to be $79.03 per barrel.

Increasing energy demand and depleting fossil fuel sources have intensified the focus on biofuel production. Microalgae have emerged as a desirable source for biofuel production because of high biomass and lipid production from waste water source. In this study, five microalgae were isolated from effluents of Nisargruna biogas plants. These isolates were identified based on morphology and partial 18S and 23S rRNA gene sequences. Growth and lipid accumulation potential of these microalgae were investigated. One isolate, Chlorella sp. KMN3, accumulated high biomass (1.59 ± 0.05 g L(-1)) with moderate lipid content (20%), while another isolate Monoraphidium sp. KMN5 showed moderate biomass accumulation of 0.65 ± 0.05 g L(-1) with a very high (35%) lipid content. The fatty acid methyl esters mainly composed of C-16:0, C-18:0, C-18:1 and C-18:2. This observation makes these microalgae immensely potential candidate for biodiesel production using the effluent of a biogas plant as feed stock.

With the rising population, environmental pollution, and social development, potable water is reducing and being contaminated day by day continually. Thus, several researchers have focused their studies on seas and oceans in order to get potable fresh water by desalination of their saltwater. Solar still of basin type is one of the available technologies to purify water because of free solar energy. The computational fluid dynamic CFD model of the solar still can significantly improve means for optimization of the solar still structure because it reduces the need for conducting large amount of experiments. Therefore, the main purpose of this study is presenting a multi-phase, three-dimensional CFD model, which predicts the performance of the solar still without using any experimental measurements, depending on the CFD solar radiation model. Simulated results are compared with experimental values of water and glass cover temperatures and yield of fresh water in climate conditions of Sheben El-Kom, Egypt (latitude 30.5° N and longitude 31.01° E). The simulation results were found to be in acceptable agreement with the experimental measured data. The results indicated that the daily simulated and experimental accumulated productivities of the single-slope solar still were found to be 1.982 and 1.785 L/m2 at a water depth of 2 cm. In addition, the simulated and experimental daily efficiency were around 16.79% and 15.5%, respectively, for the tested water depth.

The objective of this study is to evaluate the hydrological impacts of climate change on rainfall, temperature and streamflow in a west flowing river originating in the Western Ghats of India. The long-term trend analysis for 110 yr of meteorological variables (rainfall and temperature) was carried out using the modified Mann–Kendall trend test and the magnitude of the trend was quantified using the Sen’s slope estimator. The Regional Climate Model (RCM), COordinated Regional climate Downscaling EXperiment (CORDEX) simulated daily weather data of baseline (1951–2005) and future RCP 4.5 scenarios (2006–2060) were used to run the hydrological model, Soil and Water Assessment Tool (SWAT), in order to evaluate the effect of climate change on rainfall, temperature and streamflow. Significant changes were observed with regard to rainfall, which have shown decreasing trend at the rate of 2.63 mm per year for the historical and 8.85 mm per year for RCP 4.5 future scenarios. The average temperature was found to be increasing at $$0.10\,^{\circ }\hbox {C}$$ per decade for both historical and future scenarios. The impact of climate change on the annual streamflow yielded a decreasing trend at the rate of $$1.2\,\hbox {Mm}^{3}$$ per year and 2.56 $$\hbox {Mm}^{3},$$ respectively for the past and future scenarios. The present work also investigates the capability of SWAT to simulate the groundwater flow. The simulated results are compared with the recession limb of the hydrograph and were found to be reasonably accurate.

In the present study, the extracts of Cytinus hypocistis (L.) L using both traditional solvents (hexane, ethyl acetate, dichloromethane, ethanol, ethanol/water, and water) and natural deep eutectic solvents (NADESs) were investigated in terms of their total polyphenolic contents and antioxidant and enzyme-inhibitive properties. The extracts were found to possess total phenolic and total flavonoid contents in the ranges of 26.47–186.13 mg GAE/g and 0.68–12.55 mg RE/g, respectively. Higher total phenolic contents were obtained for NADES extracts. Compositional differences were reported in relation to antioxidant potential studied by several assays (DPPH: 70.19–939.35 mg TE/g, ABTS: 172.56–4026.50 mg TE/g; CUPRAC: 97.41–1730.38 mg TE/g, FRAP: 84.11–1534.85 mg TE/g). Application of NADESs (choline chloride—urea 1:2, a so-called Reline) allowed one to obtain the highest number of extracts having antioxidant potential in the radical scavenging and reducing assays. NADES-B (protonated by HCl L-proline-xylitol 5:1) was the only extractant from the studied solvents that isolated a specific fraction without chelating activity. Reline extract exhibited the highest acetylcholinesterase inhibition compared to NADES-B and NADES-C (protonated by H2SO4 L-proline-xylitol 5:1) extracts, which showed no inhibition. The NADES extracts were observed to have higher tyrosinase inhibitory properties compared to extracts obtained by traditional organic solvents. Furthermore, the NADES extracts were relatively better inhibitors of the diabetic enzymes. These findings provided an interesting comparison in terms of total polyphenolic content yields, antioxidant and enzyme inhibitory properties (cholinesterase, amylase, glucosidase, and tyrosinase) between traditional solvent extracts and NADES extracts, used as an alternative. While the organic solvents showed better antioxidant activity, the NADES extracts were found to have some other improved properties, such as higher total phenolic content and enzyme-inhibiting properties, suggesting functional prospects for their use in phytonutrient extraction and fractionation. The obtained results could also be used to give a broad overview of the different biological potentials of C. hypocistis.