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The Indian Ocean Experiment (INDOEX) was an international, multiplatform field campaign to measure long-range transport of air pollution from South and Southeast Asia toward the Indian Ocean during the dry monsoon season in January to March 1999. Surprisingly high pollution levels were observed over the entire northern Indian Ocean toward the Intertropical Convergence Zone at about 6°S. We show that agricultural burning and especially biofuel use enhance carbon monoxide concentrations. Fossil fuel combustion and biomass burning cause a high aerosol loading. The growing pollution in this region gives rise to extensive air quality degradation with local, regional, and global implications, including a reduction of the oxidizing power of the atmosphere.

Abstract The aim of the present study was to assess the influence of substrate concentration on the fermentative hydrogen production from sweet sorghum extract, in a continuous stirred tank bioreactor. The reactor was operated at a Hydraulic Retention Time (HRT) of 12 h and carbohydrate concentrations ranging from 9.89 to 20.99 g/L, in glucose equivalents. The maximum hydrogen production rate and yield were obtained at the concentration of 17.50 g carbohydrates/L and were 2.93 ± 0.09 L H 2 /L reactor/d and 0.74 ± 0.02 mol H 2 /mol glucose consumed, corresponding to 8.81 ± 0.02 L H 2 /kg sweet sorghum, respectively. The main metabolic product at all steady states was butyric acid, while ethanol production was high at high substrate concentrations. The experiments showed that hydrogen productivity depends significantly on the initial carbohydrate concentration, which also influences the distribution of the metabolic products.

We study the optical response of CH3NH3PbI3 layers to light solicitation under different environmental gas and temperature conditions. The measurements were performed in nonreactive (Ar or N-2) and reactive (O-2 or humid air) gas in the range 40-80 degrees C crossing the tetragonal cubic transition (similar to 50 degrees C). With respect to truly inert Ar, the use of N-2, not only assures the reversibility of the optical constants during thermal cycles but also improves the optical response of the material. While in N-2 and Ar atmospheres the optical parameters of the material can be recovered at the end of the cycle, in contrast, the presence of humidity in the air causes the absorption coefficient to.monotonically and inexorably decrease in the whole visible range, especially after the lattice has moved to cubic. The use of N-2 thus represents an effective strategy to improve the absorption under thermal operation conditions.

Improper management of pig manure has resulted in environmental problems such as surface water eutrophication, ground water pollution, and greenhouse gas emissions. This study develops and compares 14 alternative manure management scenarios aiming at energy and nutrient extraction. The scenarios based on combinations of thermal pretreatment, anaerobic digestion, anaerobic co-digestion, liquid/solid separation, drying, incineration, and thermal gasification were compared with respect to their energy, nutrient and greenhouse gas balances. Both sole pig manure and pig manure mixed with other types of waste materials were considered. Data for the analyses were obtained from existing waste treatment facilities, experimental plants, laboratory measurements and literature. The assessment reveals that incineration combined with liquid/solid separation and drying of the solids is a promising management option yielding a high potential energy utilization rate and greenhouse gas savings. If maximum electricity production is desired, anaerobic digestion is advantageous as the biogas can be converted to electricity at high efficiency in a gas engine while allowing production of heat for operation of the digestion process. In conclusion, this study shows that the choice of technology has a strong influence on energy, nutrient and greenhouse gas balances. Thus, to get the most reliable results, it is important to consider the most representative (and up-to-date) technology combined with data representing the area or region in question.

Six hydrothermal liquefaction experiments on Nannochloropsis salina and Spirulina platensis at subcritical and supercritical water conditions (220–375 °C, 20–255 bar) were carried out to explore the feasibility of extracting lipids from wet algae, preserving nutrients in lipid-extracted algae solid residue, and recycling process water for algae cultivation. GC–MS, elemental analyzer, FT-IR, calorimeter and nutrient analysis were used to analyze bio-crude, lipid-extracted algae and water samples produced in the hydrothermal liquefaction process. The highest bio-crude yield of 46% was obtained on N. salina at 350 °C and 175 bar. For S. platensis algae sample, the optimal hydrothermal liquefaction condition appears to be at 310 °C and 115 bar, while the optimal condition for N. salina is at 350 °C and 175 bar. Preliminary data also indicate that a lipid-extracted algae solid residue sample obtained in the hydrothermal liquefaction process contains a high level of proteins.

In 2011 the Global Bioenergy Partnership (GBEP) released a set of indicators for sustainable bioenergy. However, two important issues still remain unresolved. One of them is the definition of “sustainability”, and the other is the lack of a holistic assessment tool for drawing conclusions from the indicators. The aim of this paper is to provide clarification on the concept of sustainability in the context of the GBEP indicators, and to develop a holistic assessment tool for assessing the sustainability of bioenergy programmes. The GBEP indicators are diverse in terms of “what to measure”, and some of them are not sufficiently directly related to the concept of sustainability. This makes the indicators ambiguous regarding to sustainability assessment. This study identifies whether the GBEP indicators are concerned with strong or weak sustainability, and develops a tool based on Multi Criteria Analysis (MCA) which can be used for assessing sustainability of bioenergy programmes using the GBEP indicators. The tool is demonstrated in an example for assessing the sustainability of biofuel production in a case study of Kyoto. We found that the biodiesel production in Kyoto performs well on the environmental pillar, but badly on the economic pillar, and based on the weights applied in this study the overall sustainability is better than diesel fuel. The holistic assessment tool provides practical information to policymakers on both ex-ante and ex-post policy evaluations.

Abstract Agriculture in the Black Sea catchment is responsible for a considerable share of the area's total water withdrawal and the majority of its total water consumption. It therefore plays a key role in sustainable water resources management. However, in the future water resources will be exposed to climate change. This assessment aims at identifying the most vulnerable regions and to explain the reasons of this vulnerability. It is based on a combination of the well-known Driver–Pressure–State–Impact–Response framework (DPSIR) and the vulnerability concept as defined by the Intergovernmental Panel on Climate Change (IPCC). Three distinctive climate change scenarios are used to assess their impacts on water resources for agriculture: (1) an increase in temperature; (2) a decrease in precipitation; and (3) a combination of the first and second scenarios. The data for this assessment is derived from a SWAT model (Soil and Water Assessment Tool). The results show that the regions of the Black Sea catchment are impacted by climate change differently. Some countries benefit from climate change (e.g., Turkey, Ukraine, Romania, Moldova, Hungary, Bulgaria) while others will encounter considerably worse agro-climatic conditions in the future (e.g., Montenegro, Austria, Bosnia–Herzegovina). Additionally, natural plant growth conditions mostly improve due to more suitable temperature conditions. In contrast, the deteriorating agricultural conditions mainly result from a diminishing irrigation potential that is caused by reduced precipitation. The conclusion emphasises the important role of the legal framework as well as more sustainable agronomic practices and proposes improvements for future assessment methods in this research field.

Abstract Biogas production is one of the number of tools that may be used to alleviate the problems of global warming, energy security and waste management. Biogas plants can be difficult to sustain from a financial perspective. The facilities must be financially optimized through use of substrates with high biogas potential, low water content and low retention requirement. This research carried out in laboratory scale batch digesters assessed the biogas potential of energy crops (maize and grass silage) and solid manure fractions from manure separation units. The ultimate methane productivity in terms of volatile solids (VS) was determined as 330, 161, 230, 236, 361 L/kg VS from raw pig slurry, filter pressed manure fiber (FPMF), chemically precipitated manure fiber (CPMF), maize silage and grass silage respectively. Methane productivity based on mass (L/kg substrate) was significantly higher in FPMF (55 L/kg substrate), maize silage (68 L/kg substrate) and grass silage (45–124 L/kg substrate (depending on dry solids of feedstock)) as in comparison to raw pig slurry (10 L/kg substrate). The use of these materials as co-substrates with raw pig slurry will increase significantly the biomethane yield per unit feedstock in the biogas plant.