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Abstract With drastic fossil fuel depletion and environmental deterioration concerns, a move towards a more sustainable bioenergy-based economy is essential. Lately, the application of microwave (MW) irradiation for waste processing has been attracting interest globally. MW-assisted heating possesses several advantages such as the provision of high microwave energy into dielectric materials with deeper penetration for internal heat generation, showing beneficial features in improving the heating rate and reducing the reaction time. Consequently, the most recent literature regarding the applications of MW-assisted heating for biomass pretreatment as well as biofuel and bioenergy production was reviewed and consolidated in this study. An impressive increase in the product yield and improvement of the product properties are reported, with the use of MW-assisted heating in several conversion routes to produce biofuels. Despite being a promising technology for biofuel production, some major fundamental data of MW-assisted heating have not been comprehensively identified. Therefore, the feasibility of this technology for large-scale implementation is still subpar. Understanding the interaction between the feedstock and the microwave electromagnetic field, and the optimization of several operational and mechanical parameters are the two main keystones that would propel the industrialization of MW heating in the near future. This provides key insights leading to increased feasibility and more advanced application of MW heating.

The production of charcoal for its many uses requires a careful selection of biomass and pyrolysis conditions, especially temperature, to ensure suitable quality. To do so, physical, chemical, and mechanical energy must be considered. This study aimed to analyze the yields and properties of charcoal produced at different pyrolysis temperatures. Eucalyptus saligna wood was pyrolyzed in a reactor with final temperatures of 450, 550, 650, 750, 850 and 950 °C. The yields of charcoal, pyroligneous liquid and non-condensable gases were determined. Mass loss was determined for each temperature. Charcoal analysis included the determination of the apparent density, proximate analysis, heating value, mechanical strength, X-ray images for the internal visualization of its structure and hygroscopicity test. Relevant charcoal properties for the steel industry and barbecue, such as density, mechanical strength, heating value and hygroscopicity, show variable trends from pyrolysis at 650 °C. The results show that pyrolysis temperature had a great impact on the properties of charcoal. The apparent density of charcoal rose from 500 °C and had no relation to the breaking strength. When the pyrolysis temperature was raised, an increase in both apparent and true densities, internal fissures and cracks and fixed carbon content of charcoal was observed.

AbstractWe report a nickel complex for catalytic oxidation of ammonia to dinitrogen under ambient conditions. Using the aryloxyl radical 2,4,6‐tri‐tert‐butylphenoxyl (tBu3ArO⋅) as a H atom acceptor to cleave the N−H bond of a coordinated NH3 ligand up to 56 equiv of N2 per Ni center can be generated. Employing the N‐oxyl radical 2,2,6,6‐(tetramethylpiperidin‐1‐yl)oxyl (TEMPO⋅) as the H‐atom acceptor, up to 15 equiv of N2 per Ni center are formed. A bridging Ni‐hydrazine product identified by isotopic nitrogen (15N) studies and supported by computational models indicates the N−N bond forming step occurs by bimetallic homocoupling of two paramagnetic [Ni]−NH2 fragments. Ni‐mediated hydrazine disproportionation to N2 and NH3 completes the catalytic cycle.

Abstract The configuration of a latent heat thermal energy storage (LHTES) is an important factor considered by manufacturers of heat storage systems. In this study, an applicable and low-cost way of improving melting behavior in a rectangular cavity was remarked. There was a preconceived idea that with a single conductive baffle, embedded on the upper wall of the cavity, the melting rate and the amount of heat storage could improve. Therefore, for different locations as well as lengths of a baffle, the heat transfer and melting characteristic of gallium as a phase change material (PCM) in a rectangular cavity were investigated numerically. The cavity has the insulated upper and bottom walls. The sidewalls are regarded to have constant temperatures one higher and another lower than the melting point of gallium. The phase change process is modeled with the fixed grid-based enthalpy-porosity method coupled with the semi-implicit method for pressure-linked equations (SIMPLE) algorithm. The isotherm lines and streamlines, as well as the liquid fraction and Nusselt number on the hot wall, are considered to present the results at a constant Rayleigh number equal to 106. The results show the baffle imposes noticeable improvement on the melting process of gallium in a rectangular cavity by influencing the feature of convective heat transfer. Investigating the different baffle’s locations (LX/L = 0.2 to 0.9) revealed that when the baffle located at the right half of the cavity, melting initiates from the left side, the more amount of PCM melts in comparison with the other cases. Ultimately, the dimensionless location of LX/L = 0.8 demonstrates the best melting characteristic and the most final liquid fraction. The more liquid-fraction, the more energy storing concluded. It also observed a dimensionless height of LY/L = 0.4 represents the most liquid-fraction compared to the heights of LY/L = 0.2, 0.3, and 0.4.