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  • Energy Research
  • 12. Responsible consumption
  • IT
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  • Energies

  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Martin Zapf; Hermann Pengg; Christian Weindl;

    Avoiding irreversible climate change as effectively as possible is one of the most pressing challenges of society. Carbon pricing that is uniformly valid on a global and cross-sectoral basis represents a cost-efficient policy tool to meet this challenge. Carbon pricing allows external costs to be allocated or internalized on a polluter-pays principle. It is shown that a global emissions cap-and-trade system is the most suitable market-based instrument for reducing global emissions levels, in line with the temperature goal set by the Paris Agreement. A proposal for its design is presented in this paper. This instrument encourages worldwide measures, with the lowest marginal abatement cost, according to a pre-defined reduction path. Thereby, it ensures compliance with a specified remaining carbon budget to meet a certain temperature limit in a cost-efficient manner. Possible reduction paths are presented in this paper. Weaknesses in the design of existing emissions trading systems (ETS), such as the EU ETS, are identified and avoided in the proposed instrument. The framework solves several problems of today’s climate change policies, like the free rider problem, carbon leakage, rebound effects or the green paradox. The introduction of a global uniform carbon pricing instrument and its concrete design should be the subject of policy, especially at the United Nations climate change conferences, as soon as possible in order to allow for rapid implementation. If a global ETS with a uniform carbon price could be introduced, additional governmental regulations with regard to carbon emissions would become obsolete.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Energies
    Article . 2019 . Peer-reviewed
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    Energies
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    Energies
    Article . 2019
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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      Energies
      Article . 2019 . Peer-reviewed
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Energies
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      Energies
      Article . 2019
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    Authors: Artur Kraszkiewicz; Artur Przywara; Alexandros Sotirios Anifantis;

    Nowadays, heating using wood, briquettes, or pellets is a curious replacement to fossil fuels such as coal, oil, or gas. Unfortunately, the combustion of biofuels, especially in low-power boilers with unstable operating conditions, releases a lot of gas pollutants (e.g., carbon monoxide (CO), nitric oxide (NO), and various organic compounds) that are usually generated due to the incomplete product combustion. The combustion of biofuel in grate boilers with top-down ignition is a new approach, popular in society (mainly used for coal fuels), which improves the combustion process and reduces the amount of pollutants emitted. This study evaluated the impact of ignition techniques on the emission level of gas pollutants during the combustion of wood logs, briquettes, and pellets of pine in grate-based charging boilers. The combination of top ignition mode with pinewood logs allowed us to achieve a reduction of 6% in CO and sulfur dioxide (SO2) emission into the atmosphere. However, the combination of top-down ignition mode with pellets and briquettes produced, in fully operational conditions, 1- to 18-fold higher levels of CO and SO2 respectively, than bottom-up ignition, after an initial period of low level CO and SO2 emissions. During the tests (mainly with ignition from top), substantial emissions of NO were observed of up to 400 mg·m−3 at 10% O2. Therefore, further research is required to decrease emission related to the content of nitrogen in biomass. In this respect, research of impact on the combustion temperature of such emissions is needed.

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    Energies
    Article . 2020 . Peer-reviewed
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    Energies
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    Energies
    Article . 2020
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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      Energies
      Article . 2020 . Peer-reviewed
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      Energies
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      Energies
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Xiaonan Wang; Licheng Wang; Jianping Chen; Shouting Zhang; +1 Authors

    Coal will continue to be the main energy source in China for the immediate future, although the environmental pollution and ecological impacts of each stage in the full life cycle of coal mining, transportation, and combustion generate large quantities of external costs. The Late Permian coals in southwestern (SW) China usually contain high amounts of fluorine (F), arsenic (As), and ash, which together with high-F clays cause abnormally high levels of endemic fluorosis, As poisoning, and lung cancer in areas where coal is mined and burned. In this paper, we estimate the external costs of the life cycle of coal. The results show that the externalities of coal in SW China are estimated at USD 73.5 billion or 284.3 USD/t, which would have accounted for 6.5 % of the provincial GDP in this area in 2018. The external cost of human health accounts for 87.2% of the total external costs, of which endemic skeletal fluorosis diseases and related lung cancers have the most important impact. Our study provides a more precise estimate of externalities compared with its counterparts in other provinces in China. Therefore, several policy recommendations would be proposed to internalize the external cost.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Energies
    Article . 2020 . Peer-reviewed
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    Authors: Nsair, Abdullah; Önen Çınar, Senem; Alassali, Ayah; Abu Qdais, Hani; +1 Authors

    The biogas production technology has improved over the last years for the aim of reducing the costs of the process, increasing the biogas yields, and minimizing the greenhouse gas emissions. To obtain a stable and efficient biogas production, there are several design considerations and operational parameters to be taken into account. Besides, adapting the process to unanticipated conditions can be achieved by adequate monitoring of various operational parameters. This paper reviews the research that has been conducted over the last years. This review paper summarizes the developments in biogas design and operation, while highlighting the main factors that affect the efficiency of the anaerobic digestion process. The study’s outcomes revealed that the optimum operational values of the main parameters may vary from one biogas plant to another. Additionally, the negative conditions that should be avoided while operating a biogas plant were identified.

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    Energies
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      Article . 2020
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    Authors: Patrizia Ghisellini; Amos Ncube; Gianni D’Ambrosio; Renato Passaro; +1 Authors

    In this study, our aim was to explore the potential energy savings obtainable from the recycling of 1 tonne of Construction and Demolition Waste (C&DW) generated in the Metropolitan City of Naples. The main fraction composing the functional unit are mixed C&DW, soil and stones, concrete, iron, steel and aluminium. The results evidence that the recycling option for the C&DW is better than landfilling as well as that the production of recycled aggregates is environmentally sustainable since the induced energy and environmental impacts are lower than the avoided energy and environmental impacts in the life cycle of recycled aggregates. This LCA study shows that the transition to the Circular Economy offers many opportunities for improving the energy and environmental performances of the construction sector in the life cycle of construction materials by means of internal recycling strategies (recycling C&DW into recycled aggregates, recycled steel, iron and aluminum) as well as external recycling by using input of other sectors (agri-food by-products) for the manufacturing of construction materials. In this way, the C&D sector also contributes to realizing the energy and bioeconomy transition by disentangling itself from fossil fuel dependence.

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    Authors: Mauro Luberti; Alexander Brown; Marco Balsamo; Mauro Capocelli;

    The increasing demand for energy and commodities has led to escalating greenhouse gas emissions, the chief of which is represented by carbon dioxide (CO2). Blue hydrogen (H2), a low-carbon hydrogen produced from natural gas with carbon capture technologies applied, has been suggested as a possible alternative to fossil fuels in processes with hard-to-abate emission sources, including refining, chemical, petrochemical and transport sectors. Due to the recent international directives aimed to combat climate change, even existing hydrogen plants should be retrofitted with carbon capture units. To optimize the process economics of such retrofit, it has been proposed to remove CO2 from the pressure swing adsorption (PSA) tail gas to exploit the relatively high CO2 concentration. This study aimed to design and numerically investigate a vacuum pressure swing adsorption (VPSA) process capable of capturing CO2 from the PSA tail gas of an industrial steam methane reforming (SMR)-based hydrogen plant using NaX zeolite adsorbent. The effect of operating conditions, such as purge-to-feed ratio and desorption pressure, were evaluated in relation to CO2 purity, CO2 recovery, bed productivity and specific energy consumption. We found that conventional cycle configurations, namely a 2-bed, 4-step Skarstrom cycle and a 2-bed, 6-step modified Skarstrom cycle with pressure equalization, were able to concentrate CO2 to a purity greater than 95% with a CO2 recovery of around 77% and 90%, respectively. Therefore, the latter configuration could serve as an efficient process to decarbonize existing hydrogen plants and produce blue H2.

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    Authors: Douglas Mulhall; Anne-Christine Ayed; Jeannot Schroeder; Katja Hansen; +1 Authors

    Background. Laws that enable a circular economy (CE) are being enacted globally, but reliable standardized and digitized CE data about products is scarce, and many CE platforms have differing exclusive formats. In response to these challenges, the Ministry of The Economy of Luxembourg launched the Circularity Dataset Standardization Initiative to develop a globalized open-source industry standard to allow the exchange of standardized data throughout the supply cycle, based on these objectives: (a) Provide basic product circularity data about products. (b) Improve circularity data sharing efficiency. (c) Encourage improved product circularity performance. A policy objective was to have the International Organization for Standardization (ISO) voted to create a working group. Methods. A state-of-play analysis was performed concurrently with consultations with industry, auditors, data experts, and data aggregation platforms. Results. Problem statements were generated. Based on those, a solution called Product Circularity Data Sheet (PCDS) was formulated. A proof of concept (POC) template and guidance were developed and piloted with manufacturers and platforms, thus fulfilling objective (a). For objective (b), IT ecosystem requirements were developed, and aspects are being piloted in third party aggregation platforms. Objective (c) awaits implementation of the IT ecosystem. The policy objective related to the ISO was met. Conclusions and future research. In order to fully test the PCDS, it is necessary to: conduct more pilots, define governance, and establish auditing and authentication procedures.

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    Authors: Steffen Wehkamp; Lucas Schmeling; Lena Vorspel; Fabian Roelcke; +1 Authors

    The change from a centralized to a decentralized energy supply creates new challenges in the planning of such energy supply concepts. Specialized planning tools that can cope with the complex requirements and multi-layered boundary conditions of local energy use are therefore needed. Existing methods need to be further developed and optimized to suit the complex stakeholder structures encountered in innovative district projects, as well as for research purposes. This paper presents selected aspects and challenges in the development of an application-oriented planning tool. Using a North German district as a case study, the usability of a Building Information Model as an aggregated data platform is tested in the context of a residential energy district planning process. In addition, the modeling of heating grids using a combination of Geographic Information System and open source thermodynamic tools is presented. Economic valuation methods are examined to determine the extent to which the value of flexibility and access to local flexibility markets can be taken into account. Finally, an approach for evaluating the ecological aspects of the district energy supply is presented, based on the dynamic assessment of imported and exported energy quantities.

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    Authors: Selina Hafner; Max Schmid; Günter Scheffknecht;

    Finding a way for mitigating climate change is one of the main challenges of our generation. Sorption-enhanced gasification (SEG) is a process by which syngas as an important intermediate for the synthesis of e.g., dimethyl ether (DME), bio-synthetic natural gas (SNG) and Fischer–Tropsch (FT) products or hydrogen can be produced by using biomass as feedstock. It can, therefore, contribute to a replacement for fossil fuels to reduce greenhouse gas (GHG) emissions. SEG is an indirect gasification process that is operated in a dual-fluidized bed (DFB) reactor. By the use of a CO2-active sorbent as bed material, CO2 that is produced during gasification is directly captured. The resulting enhancement of the water–gas shift reaction enables the production of a syngas with high hydrogen content and adjustable H2/CO/CO2-ratio. Tests were conducted in a 200 kW DFB pilot-scale facility under industrially relevant conditions to analyze the influence of gasification temperature, steam to carbon (S/C) ratio and weight hourly space velocity (WHSV) on the syngas production, using wood pellets as feedstock and limestone as bed material. Results revealed a strong dependency of the syngas composition on the gasification temperature in terms of permanent gases, light hydrocarbons and tars. Also, S/C ratio and WHSV are parameters that can contribute to adjusting the syngas properties in such a way that it is optimized for a specific downstream synthesis process.

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    https://dx.doi.org/10.18419/op...
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      Energies
      Article . 2021 . Peer-reviewed
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      https://dx.doi.org/10.18419/op...
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      Energies
      Article . 2021
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Jonathan Banks; Spencer Poulette; Jens Grimmer; Florian Bauer; +1 Authors

    The campus of the Karlsruhe Institute of Technology (KIT) contains several waste heat streams. In an effort to reduce greenhouse gas emissions by optimizing thermal power consumption on the campus, researchers at the KIT are proposing a ‘DeepStor’ project, which will sequester waste heat from these streams in an underground reservoir during the summer months, when the heat is not required. The stored heat will then be reproduced in the winter, when the campus’s thermal power demand is much higher. This paper contains a preliminary geochemical risk assessment for the operation of this subsurface, seasonal geothermal energy storage system. We used equilibrium thermodynamics to determine the potential phases and extent of mineral scale formation in the plant’s surface infrastructure, and to identify possible precipitation, dissolution, and ion exchange reactions that may lead to formation damage in the reservoir. The reservoir in question is the Meletta Beds of the Upper Rhein Graben’s Froidefontaine Formation. We modeled scale- and formation damage-causing reactions during six months of injecting 140 °C fluid into the reservoir during the summer thermal storage season and six months of injecting 80 °C fluid during the winter thermal consumption season. Overall, we ran the models for 5 years. Anhydrite and calcite are expected mineral scales during the thermal storage season (summer). Quartz is the predicted scale-forming mineral during the thermal consumption period (winter). Within ~20 m of the wellbores, magnesium and iron are leached from biotite; calcium and magnesium are leached from dolomite; and sodium, aluminum, and silica are leached from albite. These reactions lead to a net increase in both porosity and permeability in the wellbore adjacent region. At a distance of ~20–75 m from the wellbores, the leached ions recombine with the reservoir rocks to form a variety of clays, i.e., saponite, minnesotaite, and daphnite. These alteration products lead to a net loss in porosity and permeability in this zone. After each thermal storage and production cycle, the reservoir shows a net retention of heat, suggesting that the operation of the proposed DeepStor project could successfully store heat, if the geochemical risks described in this paper can managed.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ KITopen (Karlsruhe I...arrow_drop_down
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    Energies
    Article . 2021 . Peer-reviewed
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Martin Zapf; Hermann Pengg; Christian Weindl;

    Avoiding irreversible climate change as effectively as possible is one of the most pressing challenges of society. Carbon pricing that is uniformly valid on a global and cross-sectoral basis represents a cost-efficient policy tool to meet this challenge. Carbon pricing allows external costs to be allocated or internalized on a polluter-pays principle. It is shown that a global emissions cap-and-trade system is the most suitable market-based instrument for reducing global emissions levels, in line with the temperature goal set by the Paris Agreement. A proposal for its design is presented in this paper. This instrument encourages worldwide measures, with the lowest marginal abatement cost, according to a pre-defined reduction path. Thereby, it ensures compliance with a specified remaining carbon budget to meet a certain temperature limit in a cost-efficient manner. Possible reduction paths are presented in this paper. Weaknesses in the design of existing emissions trading systems (ETS), such as the EU ETS, are identified and avoided in the proposed instrument. The framework solves several problems of today’s climate change policies, like the free rider problem, carbon leakage, rebound effects or the green paradox. The introduction of a global uniform carbon pricing instrument and its concrete design should be the subject of policy, especially at the United Nations climate change conferences, as soon as possible in order to allow for rapid implementation. If a global ETS with a uniform carbon price could be introduced, additional governmental regulations with regard to carbon emissions would become obsolete.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Energiesarrow_drop_down
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    Energies
    Article . 2019 . Peer-reviewed
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    Energies
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    Energies
    Article . 2019
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      Energies
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Artur Kraszkiewicz; Artur Przywara; Alexandros Sotirios Anifantis;

    Nowadays, heating using wood, briquettes, or pellets is a curious replacement to fossil fuels such as coal, oil, or gas. Unfortunately, the combustion of biofuels, especially in low-power boilers with unstable operating conditions, releases a lot of gas pollutants (e.g., carbon monoxide (CO), nitric oxide (NO), and various organic compounds) that are usually generated due to the incomplete product combustion. The combustion of biofuel in grate boilers with top-down ignition is a new approach, popular in society (mainly used for coal fuels), which improves the combustion process and reduces the amount of pollutants emitted. This study evaluated the impact of ignition techniques on the emission level of gas pollutants during the combustion of wood logs, briquettes, and pellets of pine in grate-based charging boilers. The combination of top ignition mode with pinewood logs allowed us to achieve a reduction of 6% in CO and sulfur dioxide (SO2) emission into the atmosphere. However, the combination of top-down ignition mode with pellets and briquettes produced, in fully operational conditions, 1- to 18-fold higher levels of CO and SO2 respectively, than bottom-up ignition, after an initial period of low level CO and SO2 emissions. During the tests (mainly with ignition from top), substantial emissions of NO were observed of up to 400 mg·m−3 at 10% O2. Therefore, further research is required to decrease emission related to the content of nitrogen in biomass. In this respect, research of impact on the combustion temperature of such emissions is needed.

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    Energies
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    Article . 2020
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Xiaonan Wang; Licheng Wang; Jianping Chen; Shouting Zhang; +1 Authors

    Coal will continue to be the main energy source in China for the immediate future, although the environmental pollution and ecological impacts of each stage in the full life cycle of coal mining, transportation, and combustion generate large quantities of external costs. The Late Permian coals in southwestern (SW) China usually contain high amounts of fluorine (F), arsenic (As), and ash, which together with high-F clays cause abnormally high levels of endemic fluorosis, As poisoning, and lung cancer in areas where coal is mined and burned. In this paper, we estimate the external costs of the life cycle of coal. The results show that the externalities of coal in SW China are estimated at USD 73.5 billion or 284.3 USD/t, which would have accounted for 6.5 % of the provincial GDP in this area in 2018. The external cost of human health accounts for 87.2% of the total external costs, of which endemic skeletal fluorosis diseases and related lung cancers have the most important impact. Our study provides a more precise estimate of externalities compared with its counterparts in other provinces in China. Therefore, several policy recommendations would be proposed to internalize the external cost.

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    Authors: Nsair, Abdullah; Önen Çınar, Senem; Alassali, Ayah; Abu Qdais, Hani; +1 Authors

    The biogas production technology has improved over the last years for the aim of reducing the costs of the process, increasing the biogas yields, and minimizing the greenhouse gas emissions. To obtain a stable and efficient biogas production, there are several design considerations and operational parameters to be taken into account. Besides, adapting the process to unanticipated conditions can be achieved by adequate monitoring of various operational parameters. This paper reviews the research that has been conducted over the last years. This review paper summarizes the developments in biogas design and operation, while highlighting the main factors that affect the efficiency of the anaerobic digestion process. The study’s outcomes revealed that the optimum operational values of the main parameters may vary from one biogas plant to another. Additionally, the negative conditions that should be avoided while operating a biogas plant were identified.

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    Authors: Patrizia Ghisellini; Amos Ncube; Gianni D’Ambrosio; Renato Passaro; +1 Authors

    In this study, our aim was to explore the potential energy savings obtainable from the recycling of 1 tonne of Construction and Demolition Waste (C&DW) generated in the Metropolitan City of Naples. The main fraction composing the functional unit are mixed C&DW, soil and stones, concrete, iron, steel and aluminium. The results evidence that the recycling option for the C&DW is better than landfilling as well as that the production of recycled aggregates is environmentally sustainable since the induced energy and environmental impacts are lower than the avoided energy and environmental impacts in the life cycle of recycled aggregates. This LCA study shows that the transition to the Circular Economy offers many opportunities for improving the energy and environmental performances of the construction sector in the life cycle of construction materials by means of internal recycling strategies (recycling C&DW into recycled aggregates, recycled steel, iron and aluminum) as well as external recycling by using input of other sectors (agri-food by-products) for the manufacturing of construction materials. In this way, the C&D sector also contributes to realizing the energy and bioeconomy transition by disentangling itself from fossil fuel dependence.

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    Authors: Mauro Luberti; Alexander Brown; Marco Balsamo; Mauro Capocelli;

    The increasing demand for energy and commodities has led to escalating greenhouse gas emissions, the chief of which is represented by carbon dioxide (CO2). Blue hydrogen (H2), a low-carbon hydrogen produced from natural gas with carbon capture technologies applied, has been suggested as a possible alternative to fossil fuels in processes with hard-to-abate emission sources, including refining, chemical, petrochemical and transport sectors. Due to the recent international directives aimed to combat climate change, even existing hydrogen plants should be retrofitted with carbon capture units. To optimize the process economics of such retrofit, it has been proposed to remove CO2 from the pressure swing adsorption (PSA) tail gas to exploit the relatively high CO2 concentration. This study aimed to design and numerically investigate a vacuum pressure swing adsorption (VPSA) process capable of capturing CO2 from the PSA tail gas of an industrial steam methane reforming (SMR)-based hydrogen plant using NaX zeolite adsorbent. The effect of operating conditions, such as purge-to-feed ratio and desorption pressure, were evaluated in relation to CO2 purity, CO2 recovery, bed productivity and specific energy consumption. We found that conventional cycle configurations, namely a 2-bed, 4-step Skarstrom cycle and a 2-bed, 6-step modified Skarstrom cycle with pressure equalization, were able to concentrate CO2 to a purity greater than 95% with a CO2 recovery of around 77% and 90%, respectively. Therefore, the latter configuration could serve as an efficient process to decarbonize existing hydrogen plants and produce blue H2.

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    Authors: Douglas Mulhall; Anne-Christine Ayed; Jeannot Schroeder; Katja Hansen; +1 Authors

    Background. Laws that enable a circular economy (CE) are being enacted globally, but reliable standardized and digitized CE data about products is scarce, and many CE platforms have differing exclusive formats. In response to these challenges, the Ministry of The Economy of Luxembourg launched the Circularity Dataset Standardization Initiative to develop a globalized open-source industry standard to allow the exchange of standardized data throughout the supply cycle, based on these objectives: (a) Provide basic product circularity data about products. (b) Improve circularity data sharing efficiency. (c) Encourage improved product circularity performance. A policy objective was to have the International Organization for Standardization (ISO) voted to create a working group. Methods. A state-of-play analysis was performed concurrently with consultations with industry, auditors, data experts, and data aggregation platforms. Results. Problem statements were generated. Based on those, a solution called Product Circularity Data Sheet (PCDS) was formulated. A proof of concept (POC) template and guidance were developed and piloted with manufacturers and platforms, thus fulfilling objective (a). For objective (b), IT ecosystem requirements were developed, and aspects are being piloted in third party aggregation platforms. Objective (c) awaits implementation of the IT ecosystem. The policy objective related to the ISO was met. Conclusions and future research. In order to fully test the PCDS, it is necessary to: conduct more pilots, define governance, and establish auditing and authentication procedures.

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    Authors: Steffen Wehkamp; Lucas Schmeling; Lena Vorspel; Fabian Roelcke; +1 Authors

    The change from a centralized to a decentralized energy supply creates new challenges in the planning of such energy supply concepts. Specialized planning tools that can cope with the complex requirements and multi-layered boundary conditions of local energy use are therefore needed. Existing methods need to be further developed and optimized to suit the complex stakeholder structures encountered in innovative district projects, as well as for research purposes. This paper presents selected aspects and challenges in the development of an application-oriented planning tool. Using a North German district as a case study, the usability of a Building Information Model as an aggregated data platform is tested in the context of a residential energy district planning process. In addition, the modeling of heating grids using a combination of Geographic Information System and open source thermodynamic tools is presented. Economic valuation methods are examined to determine the extent to which the value of flexibility and access to local flexibility markets can be taken into account. Finally, an approach for evaluating the ecological aspects of the district energy supply is presented, based on the dynamic assessment of imported and exported energy quantities.

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    Authors: Selina Hafner; Max Schmid; Günter Scheffknecht;

    Finding a way for mitigating climate change is one of the main challenges of our generation. Sorption-enhanced gasification (SEG) is a process by which syngas as an important intermediate for the synthesis of e.g., dimethyl ether (DME), bio-synthetic natural gas (SNG) and Fischer–Tropsch (FT) products or hydrogen can be produced by using biomass as feedstock. It can, therefore, contribute to a replacement for fossil fuels to reduce greenhouse gas (GHG) emissions. SEG is an indirect gasification process that is operated in a dual-fluidized bed (DFB) reactor. By the use of a CO2-active sorbent as bed material, CO2 that is produced during gasification is directly captured. The resulting enhancement of the water–gas shift reaction enables the production of a syngas with high hydrogen content and adjustable H2/CO/CO2-ratio. Tests were conducted in a 200 kW DFB pilot-scale facility under industrially relevant conditions to analyze the influence of gasification temperature, steam to carbon (S/C) ratio and weight hourly space velocity (WHSV) on the syngas production, using wood pellets as feedstock and limestone as bed material. Results revealed a strong dependency of the syngas composition on the gasification temperature in terms of permanent gases, light hydrocarbons and tars. Also, S/C ratio and WHSV are parameters that can contribute to adjusting the syngas properties in such a way that it is optimized for a specific downstream synthesis process.

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    https://dx.doi.org/10.18419/op...
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    Authors: Jonathan Banks; Spencer Poulette; Jens Grimmer; Florian Bauer; +1 Authors

    The campus of the Karlsruhe Institute of Technology (KIT) contains several waste heat streams. In an effort to reduce greenhouse gas emissions by optimizing thermal power consumption on the campus, researchers at the KIT are proposing a ‘DeepStor’ project, which will sequester waste heat from these streams in an underground reservoir during the summer months, when the heat is not required. The stored heat will then be reproduced in the winter, when the campus’s thermal power demand is much higher. This paper contains a preliminary geochemical risk assessment for the operation of this subsurface, seasonal geothermal energy storage system. We used equilibrium thermodynamics to determine the potential phases and extent of mineral scale formation in the plant’s surface infrastructure, and to identify possible precipitation, dissolution, and ion exchange reactions that may lead to formation damage in the reservoir. The reservoir in question is the Meletta Beds of the Upper Rhein Graben’s Froidefontaine Formation. We modeled scale- and formation damage-causing reactions during six months of injecting 140 °C fluid into the reservoir during the summer thermal storage season and six months of injecting 80 °C fluid during the winter thermal consumption season. Overall, we ran the models for 5 years. Anhydrite and calcite are expected mineral scales during the thermal storage season (summer). Quartz is the predicted scale-forming mineral during the thermal consumption period (winter). Within ~20 m of the wellbores, magnesium and iron are leached from biotite; calcium and magnesium are leached from dolomite; and sodium, aluminum, and silica are leached from albite. These reactions lead to a net increase in both porosity and permeability in the wellbore adjacent region. At a distance of ~20–75 m from the wellbores, the leached ions recombine with the reservoir rocks to form a variety of clays, i.e., saponite, minnesotaite, and daphnite. These alteration products lead to a net loss in porosity and permeability in this zone. After each thermal storage and production cycle, the reservoir shows a net retention of heat, suggesting that the operation of the proposed DeepStor project could successfully store heat, if the geochemical risks described in this paper can managed.

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