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Abstract This paper presents a non-stoichiometric equilibrium model for the simulation of biomass downdraft gasifiers. The chemical equilibrium is determined by minimizing the Gibbs free energy. Five elements characterize the biomass and 15 chemical species are considered in the syngas. The model calculates the lower heating value of the syngas and the relative abundances of gasification products. An advantage of this model is that it can easily calculate not only the concentrations of the main gasification products, but also the concentrations of minor product, especially the pollutant chemical species containing Nitrogen and Sulfur. To analyse the model behaviour, a sensitivity analysis on process parameters is presented. The model is validated by comparing its results with the results of simulation carried out with a stoichiometric model and with experimental data found in literature. Finally, the model is applied to the study of the gasification of forest waste.

Abstract Probability density functions (PDFs) are normally used to describe wind speed distribution for the proper selection of wind turbines in a given location. The identification of a suitable PDF is fundamental for accurately assessing the wind energy potential and designing the wind farms. To achieve this objective, the use of a mixture of two truncated normal distributions (MTTND), defined for v ≥ 0 and obtained by linearly combining two normal distributions with different means and variances, is proposed in this work for the representation of the wind speed PDF. The distribution is a function of five parameters, does not require a high computational burden and allows the representation of wind calm hours (v = 0). The use of the MTTND allows an accurate estimation to be obtained of the experimental discrete distribution of the probability density and cumulative probability, and the characteristic statistical quantities used to estimate the available energy and the performance indicators in the selection of both the site and wind turbine. The validity of the use of the MTTND was verified by comparison with the most widespread PDFs in the scientific literature: Weibull, Rayleigh, lognormal, gamma, inverse Gaussian and Burr. This comparison was developed using experimental wind speed data relating to five Italian locations and a location in Colorado (USA) belonging to the National Renewable Energy Laboratory. For each location, the parameters of each PDF were obtained with the least squares non-linear regression method. The results of the comparisons, in terms of the coefficient of determination R2 and root mean square error (RMSE) for goodness of fit and in terms of relative error in the calculation of the statistical quantities, show that the use of the MTTND gives rise to greater accuracy than a conventional wind speed PDF.

Abstract Reaching universal access to electricity by 2030 requires a massive deployment of mini-grids in rural areas of developing countries. Among the many challenges hindering this process, there are the high uncertainties in assessing demand patterns in rural communities, the costs of field survey campaigns, and the absence of ample and reliable datasets coming from existing projects. This paper tries to address these issues by presenting and discussing a database of load profiles from sixty-one off-grid mini-grids from developing countries worldwide, gathered from the literature, private developers and fieldworks, and reported with technical, socio-economic and geographical characterization factors. A clustering procedure led to the identification of five archetypal load profile clusters, which are presented and analyzed together with their load duration curves. Subsequently, the distribution among the clusters of the various characterization factors selected is studied. The proposed approach allows to widen the range of load profiles usually considered, and to seek correlations between the load profile shapes, the peak power and average energy consumption per connection, the number of customers, the age of measurement, geographical position, operator model, type of tariff and generation technologies present. This work establishes a first step in the creation of a shared database for load profiles of rural mini-grids, helping to overcome the lack of available data and difficulties of demand assessment, proposing original insights for researchers to understand load patterns, and contributing to reduce risks and uncertainties for mini-grid developers.

As part of the Copenhagen Accord, individual countries have submitted greenhouse gas reduction proposals for the year 2020. This paper analyses the implications for emission reductions, the carbon price, and abatement costs of these submissions. The submissions of the Annex I (industrialised) countries are estimated to lead to a total reduction target of 12-18% below 1990 levels. The submissions of the seven major emerging economies are estimated to lead to an 11-14% reduction below baseline emissions, depending on international (financial) support. Global abatement costs in 2020 are estimated at about USD 60-100 billion, assuming that at least two-thirds of Annex I emission reduction targets need to be achieved domestically. The largest share of these costs are incurred by Annex I countries, although the costs as share of GDP are similar for Annex I as a group and the seven emerging economies as a group, even when assuming substantial international transfers from Annex I countries to the emerging economies to finance their abatement costs. If the restriction of achieving two-thirds of the emission reduction target domestically is abandoned, it would more than double the international carbon price and at the same time reduce global abatement costs by almost 25%.

The increasing depletion of natural resources, combined with a wider set of pressures on the environment, has, in recent years, highlighted the need for a more efficient use of energy and a development process that involves alternative energy sources. Energy efficiency has received much attention as a solution, implying both monetary and emissions savings. However, the latter may be partially offset by the income and demand effects of the former, both in more efficient sectors and in spreading to the wider economy. This is the problem of rebound effects. Taking Spain as a case study, and introducing an energy-related CGE model that develops the inclusion of renewables, this paper evaluates a combination of efficiency initiatives to deliver both reduced energy use by households and a more sustainable supply of energy. Our findings suggest that a package aimed at improving efficiency in household electricity and petroleum use, combined with a more competitive supply of energy from renewable sources, may be the only way to get reductions in all energy use, and thus benefit the economy. Specifically, we consider how this package may lead to positive economic impacts and associated rebound effects, where the latter are focused on a greener energy supply.

Microbial electrochemical technologies (METs) constitute the core of a number of emerging technologies with a high potential for treating urban wastewater due to a fascinating reaction mechanism—the electron transfer between bacteria and electrodes to transform metabolism into electrical current. In the current work, we focus on the model electroactive microorganism Geobacter sulfurreducens to explore both the design of new start-up procedures and electrochemical operations. Our chemostat-grown plug and play cells, were able to reduce the start-up period by 20-fold while enhancing chemical oxygen demand (COD) removal by more than 6-fold during this period. Moreover, a filter-press based bioreactor was successfully tested for both acetate-supplemented synthetic wastewater and real urban wastewater. This proof-of-concept pre-pilot treatment included a microbial electrolysis cell (MEC) followed in time by a microbial fuel cell (MFC) to finally generate electrical current of ca. 20 A·m−2 with a power of 10 W·m−2 while removing 42 g COD day−1·m−2. The effective removal of acetate suggests a potential use of this modular technology for treating acetogenic wastewater where Geobacter sulfurreducens outcompetes other organisms.

The pandemic caused by Covid-19 has tested the resilience of public institutions, already burdened by a deep and complex crisis (political, economic, managerial). This crisis has revealed a discrepancy between the needs expressed by the community and the solutions adopted to satisfy them. This has been accompanied by a progressive worsening of decision-making efficiency and weak implementation capacity in a context of increasing environmental uncertainty. It is in local institutions, in particular, that the greatest problems are revealed, because of many endemic negative factors: political fragmentation, reduced economic resources, new forms of poverty. Against the background of this scenario, our study aims to analyze the reaction of local institutions to the pandemic crisis by looking at both welfare and communication services. The objective is to identify key features in understanding the resilience of municipalities. In other words, their ability to react and adapt to change, which is essential not only to deal with emergencies, such as the pandemic, but also to make the institution itself sustainable. Our interest is focused on a specific dimension of the resilience of the municipalities, related to collaboration with the third sector. The pandemic has shown that the continuous activism of non-profit organizations has allowed for the continuation of many so-called "ordinary" services, as well as the launch of several initiatives aimed at alleviating other social problems. The research has, first of all, an exploratory character that befits a new and still ongoing phenomenon. The basic questions concern the production of local welfare policies by municipalities. The data show different levels of "interventism" and different modes of communication. On this latter point, we observe the presence of significant attention-seeking among Mayors as community builders able, on the one hand, to reinforce the spirit of solidarity and, on the other, to uphold respect for the rules. On the services side, three main models of response to the pandemic emerge, two of which refer to the public-private relationship in local welfare policies. Findings suggest that these different reactions will have consequences in the immediate future for the management of the pandemic crisis (still ongoing). Specifically, the tendency is to employ a management of services based on partnership-model, which means that public-private collaboration is a pillar of local welfare. This seems to entail a greater legitimacy for individuals or associations to participate in the formulation and implementation of policies.