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Abstract Orange Peel Waste (OPW) is a widely produced residue whose management is complicated by its physical and chemical properties. Anaerobic digestion (AD), which is commonly used for the treatment and exploitation of many biodegradable wastes, is inefficient on OPW due to the presence of essential oils (mainly d -Limonene) as well as the low pH, which cause the process to be unstable. Here we explore the effect of alkaline pre-treatment of OPW and of the addition of granular activated carbon (GAC) and Zero Valent Iron (ZVI) in improving AD in two semi-continuous reactors at a laboratory scale. The addition and pre-treatment of ZVI/GAC were shown to help process stability up to a loading of 3 kgVS·m−3·d−1 and to increase methane production even at a sub-optimal pH. The investigation of the bacterial community, by high-throughput sequencing, has also increased our insight on their involvement in AD in the presence of ZVI, including its biotic oxidation. In addition, direct interspecies electron transfer was shown to play a role in the reactor supplemented with ZVI.

The building and construction sector is a large contributor to anthropogenic greenhouse gas emissions and consumes vast natural resources. Improvements in this sector are of fundamental importance for national and global targets to combat climate change. In this context, vertical greenery systems (VGS) in buildings have become popular in urban areas to restore green space in cities and be an adaptation strategy for challenges such as climate change. However, only a small amount of knowledge is available on the different VGS environmental impacts. This paper discusses a comparative life cycle assessment (LCA) between a building with green walls, a building with green facades and a reference building without any greenery system in the continental Mediterranean climate. This life cycle assessment is carried according to ISO 14040/44 using ReCiPe and GWP indicators. Moreover, this study fills this gap by thoroughly tracking and quantifying all impacts in all phases of the building life cycle related to the manufacturing and construction stage, maintenance, use stage (operational energy use experimentally tested), and final disposal. The adopted functional unit is the square meter of the facade. Results showed that the operational stage had the highest impact contributing by up to 90% of the total environmental impacts during its 50 years life cycle. Moreover, when considering VGS, there is an annual reduction of about 1% in the environmental burdens. However, in summer, the reduction is almost 50%. Finally, if the use stage is excluded, the manufacturing and the maintenance stage are the most significant contributors, especially in the green wall system.

This paper analyzes different policies that may promote the transition to sustainability, with a particular focus on the energy sector. We present a dynamic simulation model where three different strategies for sustainability are identified: reduction in GHG emissions, improvements in energy efficiency and the development of the renewable energy sector. Our aim is to evaluate the dynamics that those strategies may produce in the economy, looking at different performance indicators: rate of growth, unemployment, fiscal position, GHG emission, and transition to renewable energy sources.

Artículos en revistas Liberalization policies, the challenges of integrating distributed generation resources, and the recent flattening of electricity demand due to the economic crisis and technological change have led to lower returns for European electricity suppliers. Innovative and sustainable business models are needed to serve electricity customers while reflecting the operational needs of the system and maintaining supplier financial viability. This paper describes a novel model of Integrated Energy Services that encompasses distributed generation (DG) and demand response (DR) resources for industrial customers. We further reflect on some of the market opportunities and regulatory drivers for the development of similar schemes across Europe. info:eu-repo/semantics/publishedVersion

The development of heat transfer fluids (HTF) and heat storage materials (HSM) is crucial to design concentrating solar plant (CSP). Binary alkaline nitrate mixtures are currently used as sensible thermal energy storage materials. However, multi-component nitrate/nitrite systems were proposed as possible better candidates. In particular, ternaries mixtures containing sodium, potassium, and calcium are extremely promising as thermal fluids, given their reduced toxicity and greater cost-effectiveness. Nevertheless, very few data are present in the scientific literature regarding the correspondent phase diagram, and only the properties of specific compositions are reported. For this reason, a regular solution model was developed and employed in this work, and validated by comparing the simulation results with experimentally obtained phase change values. In particular, given that the common calorimetric techniques are impracticable for detecting the transition temperatures of calcium containing nitrate mixtur...

A Life Cycle Assessment (LCA) with focus on carbon footprint, followed by Life Cycle Costing (LCC) of municipal solid waste (MSW) management were conducted in a residential area of a medium-sized European city of 80,000 inhabitants. The initial results showed high environmental impacts and lack of economic sustainability, due to the high amounts of waste landfilled, the low extent of separate collection, low performance of mechanical-biological treatment as well as absence from alternatives to landfilling of non-recyclable materials. Taking this result as a baseline scenario, three improvement.s were tested with the aim of turning the carbon footprint of the local MSW management system into a neutral value: (i) increased separate collection of recyclables, (ii) enhanced biogas production and (iii) refuse-derived fuel (RDF) production. Successively adding the improvements, three alternative improved scenarios were defined, until reaching a negative carbon footprint, meaning that an optimised system would avoid GHG emissions. The proposed changes were sufficient to achieve carbon neutrality, as well as reduce overall environmental impacts, but were not enough for achieving economic sustainability due to the great influence of collection costs, especially for separate collection. It was concluded that by using an adequate combination of several treatment options and increasing the separate collection of recyclable materials it is possible to turn MSW management into a carbon neutral activity as well as improve its economic balance.

The aim of the joint activity between CNR ITAE and University of Malta, funded in the framework of a bilateral agreement is the preliminary study of the possible application of thermally-activated technologies for the refrigeration of fish on-board of fishing vessels, with particular attention to the Mediterranean area. In such a context, the two partners, given their expertise in the adsorption and absorption cooling technologies, dedicated the first year of the joint project on several activities needed to define possible integration solutions on-board. The following report is then organized as follows: - Section 3 reports an analysis of the state-of-the-art concerning existing refrigeration systems currently employed in the fishing vessels' application as well as innovative activities recently performed on the possible integration of thermally-driven technologies for the refrigeration. - Section 4 focuses on the definition of possible integration between the waste heat recovered from the engines of the fishing vessel and the sorption technology for refrigeration. This analysis takes into account different possible applications, in terms of refrigeration temperatures as well as capacities. Furthermore, different possible waste heat streams at different temperature levels are investigated. - Section 5 identifies the typical working boundary conditions under which the fishing vessel operates, in terms of cooling demand, also considering different climatic zones (i.e. different geographical areas in which the vessel operates) and vessels' typology. - Section 6 investigates possible working pairs, both for adsorption and absorption technologies, which are promising for the given boundary conditions in Section 5. This activity is needed to set the operational limits that each technology and working pair cannot overcome. - Section 7 reports the calculations performed for each working pair and operating conditions, both taking into account thermodynamic constraints as well as analysing literature results on different prototypes realized and tested. - Section 8 introduces a dynamic model, implemented in TRNSYS environment, of an absorption refrigerator, which was validated and will be used in the following activities to investigate the defined schematics in Section 4. - Section 9 defines the Key Performance Indicators (KPIs) that will be used in the following activities to compare the achievable results of the different configurations.