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When the weak forces producing parity-violating effects are taken into account, there is a tiny energy difference between the total electronic energies of two enantiomers (ΔEPV), which might be the key to understanding the evolution of the biological homochirality. We focus on the electronic chirality measure (ECM), a powerful descriptor based on the electronic charge density, for quantifying the chirality degree of a molecule, in a representative set of chiral molecules, together with their EPV energies. Our results show a novel, strong, and positive correlation between ΔEPV and ECM, supporting a subtle interplay between the weak forces acting within the nuclei of a given molecule and its chirality. These findings suggest that experimental investigations for molecular parity violation detection should consider molecules with ECM values as large as possible and may support that a chiral signature is imprinted on life by fundamental physics via the parity-violating weak interactions.

Abstract The feasibility of integrating a commercially available reheat gas turbine with a methane steam reformer is analyzed. A slight modification to the original reheat design is proposed to improve the methane conversion rate in the reforming process and, consequently, the efficiency in recovering waste exhaust heat from the gas turbine. Two solutions are proposed for the heat recovery scheme: a first reformer has a single pressure level while the second has two in order to match the different pressures of the combustors. While the single pressure scheme gives good performance with respect to the stand alone gas turbine, the dual pressure reformer can give a further benefit, as far as an accurate optimization of the steam management is performed.

Abstract Dye-sensitized solar cells (DSSCs) with photoanodes composed of chirality selected single-wall carbon nanotubes (SWNTs) have been fabricated and tested for first time. Single chirality SWCNTs separation (93% purity) have been achieved by modifying standard size exclusion gel chromatography. Chirality selection has allowed for “tuning” of the energy barrier at the TiO2/SWNT/FTO interface, electronic conductivity enhancement, and reduced SWCNTs-ruthenium dye competition for light absorption resulting in a 81% energy conversion efficiency improvement compared to mixed chirality cells. Unfortunately, energy conversion efficiency has been limited by cells’ low shunt resistance. Additionally, SWCNTs electron transfer properties have been exploited to prepare mixed and chirality specific CNTs based DSSCs’ counter electrodes.

In this context, phytochemicals were extracted from Ranunculus constantinopolitanus using ethyl acetate (EA), ethanol, ethanol/water (70%), and water solvent. The analysis encompassed quantification of total phenolic and flavonoid content using spectrophotometric assays, chemical profiling via high performance liquid chromatography-mass spectrometry/mass spectrometry (HPLC-MS/MS) for the extracts, and assessment of antioxidant activity via 2,2-diphenyl-1-picrylhydrazyl (DPPH), 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid (ABTS), Cupric reducing antioxidant capacity (CUPRAC), ferric reducing antioxidant power (FRAP), metal chelating (MCA), and phosphomolybdenum (PBD) assays. Moreover, antimicrobial activity was assessed against four different bacterial strains, as well as various yeasts. Enzyme inhibitory activities were evaluated against five types of enzymes. Additionally, the extracts were examined for their anticancer and protective effects on several cancer cell lines and the human normal cell line. All of the extracts exhibited significant levels of ferulic acid, kaempferol, and caffeic acid. All tested extracts demonstrated antimicrobial activity, with Escherichia coli and Pseudomonas aeruginosa being most sensitive to EA and ethanol extracts. Molecular docking studies revealed that kaempferol-3-O-glucoside strong interactions with AChE, BChE and tyrosinase. In addition, network pharmacology showed an association between gastric cancer and kaempferol-3-O-glucoside. Based on the results, R. constantinopolitanus can be a potential reservoir of bioactive compounds for future bioproduct innovation and pharmaceutical industries.

Abstract The International Geothermal Association (IGA), founded in 1988, is an international, worldwide, non-profit and non-governmental association whose objective and mission is to promote the research and utilization of geothermal resources, through the compilation, publication, and dissemination of scientific and technical data and information. The Information Committee (IC) of the IGA is responsible for advising the IGA Board on policies concerned with the collection, compilation, publication, exchange and dissemination of geothermal information, including information on utilization, development, technical findings, scientific research, meetings, publications and Association activities. The Committee is also responsible for the implementation of information policies determined by the Board.

A linear-array, silicon pixel detector, capable of counting single photons, was applied to mammography by using a synchrotron radiation beam. Images were obtained of both a mammographic phantom and a breast-tissue sample. The phantom image was acquired with a mean glandular dose of 0.32 mGy. This detector combined with a synchrotron radiation beam allows acquisition of high-contrast, low-dose images of soft tissues.

In this paper the results from a in-depth life cycle analysis of production and use of a novel grid-connected photovoltaic micromorph system are presented and compared to other thin film and traditional crystalline silicon photovoltaic technologies. Among the new thin film technologies, the micromorph tandem junction appears to be one of the most promising devices from the industrial point of view. The analysis was based on actual production data given to the authors directly from the PRAMAC Swiss Company and it is consistent with the recommendations provided by the ISO norms and updates. The gross energy requirement, green house gas emissions and energy pay-back time have been calculated for the electric energy output virtually generated by the studied system in a lifetime period of 20 years. A comparative framework is also provided, wherein results obtained for the case study are compared with data from literature previously obtained for the best commercially available competing photovoltaic technologies. Results clearly show a significant decrease in gross energy requirement, in green house gas emissions and also a shorter energy pay-back time for the micromorph technology.

Abstract Methane conversion to a rich H2 fuel by reforming reactions is a largely applied industrial process. Recently, it has been considered for applications combined to gas turbine powerplants, as a mean for (I) chemical recuperation (i.e. chemical looping CRGT) and (II) decarbonising the primary fuel and make the related power cycle a low CO2 releaser. The possibility of enhancing methane conversion by the addition of CO2 to the steam reactant flow (i.e. tri-reforming) has been assessed and showed interesting results. When dealing with gas turbines, the possibility of applying tri-reforming is related to the availability of some CO2 into the fluegas going to the reformer. This happens in semi-closed gas turbine cycles (SCGT), where the fluegas has a typical 14–15% CO2 mass content. The possibility of joining CRGT and SCGT technologies to improve methane reforming and propose an innovative, low CO2 emissions gas turbine cycle was assessed here. One of the key issues of this joining is also the possibility of greatly reduce the external water consumption due to the reforming, as the SCGT is a water producer cycle. The SCGT-TRIREF cycle is an SCGT cycle where fuel tri-reforming is applied. The steam due to the reformer is generated by the vaporization of the condensed water coming out from the fluegas condensing heat exchanger, upstream the main compressor, where the exhausts are cooled down and partially recirculated. The heat due to the steam generation is recuperated from the turbine exhausts cooling. The reforming process is partially sustained by the heat recovered from the turbine exhausts (which generates superheated steam) and partially by the auto thermal reactions of methane with fresh air, coming from the compressor (i.e. partial combustion). The effect of CO2 on methane reforming (tri-reforming effect) increases with decreasing steam/methane ratio: at very low values, around 30% of methane is converted by reactions with CO2. At high values of steam/methane ratio, the steam reforming reactions are dominant and only a marginal fraction of methane is interested to tri-reforming. Under optimised conditions, which can be reached at relatively high pressure ratios (25–30), the power cycle showed a potential efficiency around 46% and specific work at 550 kJ/kg level. When the amine CO2 capture is applied, the specific CO2 emissions range between 45 and 55 g CO 2 / kW h .