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The presented article will describe an 'effect-cause' model for the purpose of simulating the energy consumption of DC fed light rail vehicles. The model will assess the advantages of hybrid vehicles in terms of energy consumption, network power and voltage variations, line current and losses; and will help sizing and designing a supercapacitor based energy storage system (ESS) for both on-board, and stationary applications. The proposed modeling needs to allow the ESS sizing according to the objective that needs to be achieved, being braking energy recovery, voltage drop compensation and peak power shaving the most common goals of ESS use in hybrid vehicles. The needed power and energy levels will vary in function of the vehicle features and the driving cycle followed. This all can be determined by the quasi-static simulation tool to ease the design process. Another objective of the modeling tool is to evaluate the behaviour of the vehicle power flow controller, which manages the power from/to the ESS in function of the state of several variables.

This study adopts a life cycle approach to analyse the principal critical elements, opportunities and limits of biogas production's socio-economic aspects and environmental implications. From this perspective, the biogas supply chain sustainability and the opportunity for a closed-loop approach have been assessed starting from existing studies. The analysis revealed that the biogas sector could play a strategic role in making energy systems more resilient in a context characterised by sudden changes, such as the current scenario. In particular, the research is focused on this sector's potential to support the energy transition in Italy, which presents a structural vulnerability related to fossil resource scarcity. The paper contributes to the literature on the sustainable assessment of the biogas supply chain and paves the way for future researchers to understand the complex issues involved in the biogas sector sustainable development process. Furthermore, it provides policy, managerial and social implications, showing that the complete diffusion of biogas - a renewable, scalable and flexible resource - can foster security and decarbonisation of the energy system. It can also create new business opportunities at the local level, promoting a circular and bio-based economy.

The electrodissolution of p-Ge in aqueous NaOH solutions (pH 12-13) has been investigated with steady-state and impedance techniques. In the potential region where the process is under kinetic control, the impedance patterns are characterised by a high frequency capacitive loop, associated with the space charge, largely merged with another due to charge transfer resistance and double layer capacitance, and two low frequency loops changing from inductive to capacitive upon increasing the potential. At larger potential, under mixed control, the same high frequency features are observed, while a convection diffusion impedance dominates the low frequency response. The data relevant to pure kinetic control are interpreted with a simplified kinetic model, based on the classical scheme of Beck and Gerischer [Z. Electrochem., Ber. Bunsenges. Physik. Chem. 63 (1959) 500], neglecting transport effects and assuming only three electrochemical steps: (i) oxidation, involving water molecules, of Ge(0) to dihydroxylated Ge(II) by two holes; (ii) oxidation by one hole of Ge(II)-Ge(III) in a step requiring OH-; (iii) oxidative dissolution of Ge(III) proceeding either by hole capture or electron injection, leaving behind a surface Ge(0) species. Diagrams calculated for the limiting cases of pure depletion layer control reproduce the essential features of the experimental ones.

The winter package to reform EU’s energy system Diritto dell'energia

AbstractClimate change effects along with anthropogenic activities present the main factors that threaten the existence of heritage sites across the north Nile Delta of Egypt close to the coastline of the Mediterranean Sea. Observing the changes in the landscape close to the archaeological sites is an important issue for decision‐makers in terms of reducing the negative impact of natural events and human activities. The coastal heritage sites are becoming strongly threatened by the rising sea level phenomena that will happen due to global warming. Focusing on the distribution of the archaeological sites, this study aims to detect the areas at risk of shoreline erosion or accretion in the northern shoreline of the Nile Delta. In this study, the changes in the northern shoreline of the Nile Delta were observed and calculated during the last hundred years based on the integration between the old topographic maps from surveys in 1900, 1925 and 1945, optical satellite images captured by Landsat in 1972, 1986 and 2000; Sentinel2 2021; and the Radar SRTM data. The results of this study showed that the changes were enormous with a great shoreline erosion process over the last 121 years recorded along the shoreline in the periods between 1900–1925, 1925–1945, 1945–1972, 1972–1986, 1986–2000 and 2000–2021. The areas eroded were about 5.3, 4.7, 5.6, 8.9, 2.5 and 5.4 km2, respectively. Such negative movements caused the loss of two heritage sites, and the expected changes will lead to the loss of additional heritage sites in the next 500 years. Furthermore, a model was suggested for protecting the coastal heritage sites threatened by the risk of submergence. This study can help the decision‐makers to detect the coastal archaeological sites at risk and create innovative solutions for protecting these irreplaceable heritage sites.

It is well known that the efficiency of PV modules decreases with increasing module temperatures. Many studies have paid attention to the development and validation of heuristic models to calculate the PV module temperature in higher latitudes, however only a few focus on the thermal behaviour of PV modules in tropical regions of the world, where constantly high temperatures prevail. Also, little is known about the effect of including wind speed in these thermal models. This study evaluates three of such models - one that excludes wind, and two others including the wind influence - using hourly data for two tropical locations. Results show that the average hourly wind speeds in Singapore and Jayapura (Indonesia) are low and therefore the influence of the wind on the PV module temperature is minor. The three evaluated models produce about the same results with RMSE between 1.5-3.8 °C during daytime, which corresponds to a deviation in power output in the range of 0.3-1.6 %, depending on the PV module technology.

beta-Carotene and six xanthophylls (lutein, neoxanthin, violaxanthin, luteoxanthin, cryptoxanthin, and echinenone) have been identified and semiquantitatively or quantitatively determined in musts and port wines for the first time. An HPLC method was developed and compared with that of one based on thin layer cromatography with scanning densitometry. The most abundant carotenoids present in red grape varieties are beta-carotene and lutein. In wines, significant quantities of violaxanthin, luteoxanthin, and neoxanthin were found. This study was done with berries (skin and pulp), musts, and fortified wines. Some experiments were performed to follow carotenoid content from grapes to wines. Although the levels of beta-carotene and lutein found in fortified wines were lower than those found in musts, other xanthophylls, such as neoxanthin, violaxanthin, and luteoxanthin, exist in appreciable amounts in young ports.

AbstractThe potential impacts of future climate scenarios on water balance and flow regime are presented and discussed for a temporary river system in southern Italy. Different climate projections for the future (2030–2059) and the recent conditions (1980–2009) were investigated. A hydrological model (Soil and Water Assessment Tool) was used to simulate water balance at the basin scale and streamflow in a number of river sections under various climate change scenarios, based on different combinations of global and regional models (global circulation models and regional climate models). The impact on water balance components was quantified at the basin and subbasin levels as deviation from the baseline (1980–2009), and the flow regime alteration under changing climate was estimated using a number of hydrological indicators. An increase in mean temperature for all months between 0.5–2.4 °C and a reduction in precipitation (by 4–7%) was predicted for the future. As a consequence, a decline of blue water (7–18%) and total water yield (11–28%) was estimated. Although the river type classification remains unvaried, the flow regime distinctly moves towards drier conditions and the divergence from the current status increases in future scenarios, especially for those reaches classified as I‐D (ie, intermittent‐dry) and E (ephemeral). Hydrological indicators showed a decrease in both high flow and low flow magnitudes for various time durations, an extension of the dry season and an exacerbation of extreme low flow conditions. A reduction of snowfall in the mountainous part of the basin and an increase in potential evapotranspiration was also estimated (4–4.4%). Finally, the paper analyses the implications of the climate change for river ecosystems and for River Basin Management Planning. The defined quantitative estimates of water balance alteration could support the identification of priorities that should be addressed in upcoming years to set water‐saving actions.