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In the present work the influence of accelerated mineral carbonation on the leaching behaviour of basic oxygen furnace steel slag was investigated. The environmental behaviour of the material as evaluated through the release of major elements and toxic metals under varying pH conditions was the main focus of the study. Geochemical modelling of the eluates was used to derive a theoretical description of the underlying leaching phenomena for the carbonated material as compared to the original slag. Among the investigated elements, Ca and Si were most appreciably affected by carbonation. A very clear effect of carbonation on leaching was observed for silicate phases, and lower-Ca/Si-ratio minerals were found to control leaching in carbonated slag eluates as compared to the corresponding untreated slag sample as a result of Ca depletion from the residual slag particles. Clear evidence was also gained of solubility control for Ca, Mg and Mn by a number of carbonate minerals, indicating a significant involvement of the original slag constituents in the carbonation process. The release of toxic metals (Zn, V, Cr, Mo) was found to be variously affected by carbonation, owing to different mechanisms including pH changes, dissolution/precipitation of carbonates as well as sorption onto reactive mineral surfaces. The leaching test results were used to derive further considerations on the expected metal release levels on the basis of specific assumptions on the relevant pH domains for the untreated and carbonated slag.

In the present work the influence of accelerated mineral carbonation on the leaching behaviour of basic oxygen furnace steel slag was investigated. The environmental behaviour of the material as evaluated through the release of major elements and toxic metals under varying pH conditions was the main focus of the study. Geochemical modelling of the eluates was used to derive a theoretical description of the underlying leaching phenomena for the carbonated material as compared to the original slag. Among the investigated elements, Ca and Si were most appreciably affected by carbonation. A very clear effect of carbonation on leaching was observed for silicate phases, and lower-Ca/Si-ratio minerals were found to control leaching in carbonated slag eluates as compared to the corresponding untreated slag sample as a result of Ca depletion from the residual slag particles. Clear evidence was also gained of solubility control for Ca, Mg and Mn by a number of carbonate minerals, indicating a significant involvement of the original slag constituents in the carbonation process. The release of toxic metals (Zn, V, Cr, Mo) was found to be variously affected by carbonation, owing to different mechanisms including pH changes, dissolution/precipitation of carbonates as well as sorption onto reactive mineral surfaces. The leaching test results were used to derive further considerations on the expected metal release levels on the basis of specific assumptions on the relevant pH domains for the untreated and carbonated slag.

The safeguard of power equipments is assuming a major role in the deregulated electricity market, where a malfunctioning power system could be responsible for serious damages to a large number of system operators having access to the shared energy resource. In this context thermal monitoring of power cables represents a key issue in evaluating the risks associated with a given load management policy especially during emergency conditions. In particular this demands for reliable assessment models that should be able to predict the transient thermal behaviour when the load exceeds the nameplate value. In this connection the application of both simplified and detailed power cable thermal models is often complicated by the presence of uncertainties affecting the tolerances of the input data. The effect of these uncertainties could influence the final solution to a considerable extent. A comprehensive tolerance analysis is therefore required in order to incorporate the effect of data uncertainties into the thermal modelling process. To address this problem, in the paper the employment of interval mathematic is proposed. Several numerical results are presented and discussed in order to assess the effectiveness of the proposed methodology which offer a rough qualitative insight of the solution in a very short time, comparable to the time required for a deterministic numerical simulation.

The safeguard of power equipments is assuming a major role in the deregulated electricity market, where a malfunctioning power system could be responsible for serious damages to a large number of system operators having access to the shared energy resource. In this context thermal monitoring of power cables represents a key issue in evaluating the risks associated with a given load management policy especially during emergency conditions. In particular this demands for reliable assessment models that should be able to predict the transient thermal behaviour when the load exceeds the nameplate value. In this connection the application of both simplified and detailed power cable thermal models is often complicated by the presence of uncertainties affecting the tolerances of the input data. The effect of these uncertainties could influence the final solution to a considerable extent. A comprehensive tolerance analysis is therefore required in order to incorporate the effect of data uncertainties into the thermal modelling process. To address this problem, in the paper the employment of interval mathematic is proposed. Several numerical results are presented and discussed in order to assess the effectiveness of the proposed methodology which offer a rough qualitative insight of the solution in a very short time, comparable to the time required for a deterministic numerical simulation.

[EN] The objective of this article is to compare the behaviour of the most representative domestic hot water systems (DHW) in single-family buildings. The study evaluates the energy consumption, equivalent CO2 emissions and cost for each system over a 15-year life period. This analysis is carried out in four cli- matic zones across Europe to observe the influence of climatic conditions on the results. The four climatic zones are located in the cities of Athens, Madrid, London and Berlin. The analysed systems are: a) natural gas-fired instantaneous water heaters, b) electric storage water heater, c) solar thermal system with gas- fired instantaneous, d) solar thermal system with electric storage water heater, e) air-source heat pump, f) photovoltaic system with electric storage water heater, and g) photovoltaic system with air-source heat pump. This range of technologies covers the most likely solutions to be implemented across domestic buildings in Europe.The heat pump system (HPWH) with PV considering self-consumption shows the lowest environmen- tal impact in all zones, but is not an attractive investment in the coldest zones due to lower natural gas prices. Thermal solar systems have a high purchase and maintenance costs which do not compensate their energy savings. The PV HPWH system has a greater reduction of emissions and a lower cost than HPWH across a 15-year life. The gas boiler system has the lowest cost in a 15-year period in the coldest areas, despite having a greater environmental impact than the heat pump.(c) 2023 Elsevier B.V. All rights reserved.

[EN] The objective of this article is to compare the behaviour of the most representative domestic hot water systems (DHW) in single-family buildings. The study evaluates the energy consumption, equivalent CO2 emissions and cost for each system over a 15-year life period. This analysis is carried out in four cli- matic zones across Europe to observe the influence of climatic conditions on the results. The four climatic zones are located in the cities of Athens, Madrid, London and Berlin. The analysed systems are: a) natural gas-fired instantaneous water heaters, b) electric storage water heater, c) solar thermal system with gas- fired instantaneous, d) solar thermal system with electric storage water heater, e) air-source heat pump, f) photovoltaic system with electric storage water heater, and g) photovoltaic system with air-source heat pump. This range of technologies covers the most likely solutions to be implemented across domestic buildings in Europe.The heat pump system (HPWH) with PV considering self-consumption shows the lowest environmen- tal impact in all zones, but is not an attractive investment in the coldest zones due to lower natural gas prices. Thermal solar systems have a high purchase and maintenance costs which do not compensate their energy savings. The PV HPWH system has a greater reduction of emissions and a lower cost than HPWH across a 15-year life. The gas boiler system has the lowest cost in a 15-year period in the coldest areas, despite having a greater environmental impact than the heat pump.(c) 2023 Elsevier B.V. All rights reserved.

Abstract Thermal energy storage (TES) systems are growing to a relevant role in solar cooling applications. Hence, high energy density is a desirable property of the TES system. Phase change materials (PCM) helps to increase this characteristic. A high temperature pilot plant able to test different types of TES systems and materials was designed and built at the University of Lleida (Spain). This pilot plant is composed mainly of three parts: heating system, cooling system, and different storage tanks. Two identical storage tanks based on the shell-and-tubes heat exchanger, one of them including 196 squared fins in the bundle of the tubes and the other without, were experimentally tested. Hydroquinone was selected as the storage material, having a latent heat of 205 kJ/kg and a phase change temperature between 168 and 173 °C. The aim of this paper is to test experimentally, and compare the average effectiveness of the TES systems analyzed using PCM for solar cooling and refrigeration applications. It was found out that for the same tank configurations (shell-and-tubes) even changing drastically the dimensions of the tank or the number and the diameter of the tubes, the average effectiveness curve proposed in the literature fits well with the results showed here.

Abstract Thermal energy storage (TES) systems are growing to a relevant role in solar cooling applications. Hence, high energy density is a desirable property of the TES system. Phase change materials (PCM) helps to increase this characteristic. A high temperature pilot plant able to test different types of TES systems and materials was designed and built at the University of Lleida (Spain). This pilot plant is composed mainly of three parts: heating system, cooling system, and different storage tanks. Two identical storage tanks based on the shell-and-tubes heat exchanger, one of them including 196 squared fins in the bundle of the tubes and the other without, were experimentally tested. Hydroquinone was selected as the storage material, having a latent heat of 205 kJ/kg and a phase change temperature between 168 and 173 °C. The aim of this paper is to test experimentally, and compare the average effectiveness of the TES systems analyzed using PCM for solar cooling and refrigeration applications. It was found out that for the same tank configurations (shell-and-tubes) even changing drastically the dimensions of the tank or the number and the diameter of the tubes, the average effectiveness curve proposed in the literature fits well with the results showed here.

In recent years, the portable technology is receiving a great interest and significant improvement due to the progresses in electronic technology development and energy storage solutions. The decrease in power requirements for working energy systems, due to the increased efficiency and to the reduction in components size, opens the access to new solutions for power supplying. In particular, alternative backup systems for battery charging or replacement could be designed taking advantage of unconventional technologies. It is the case of small photovoltaic portable panels or fuel cells technology: in these solutions different sources are used to produce limited electrical powers required to keep devices on. In this paper, a thermoelectric solution for the power generation has been considered: the generator has been designed and assembled starting from a catalytic combustor. Catalytic combustion allows safe control of the processes, and the choice of a hydrocarbon fuel ensures the power availability and a fast recharge. The size of the system is set to fit a volume close to the one of AA batteries. The electrical power output obtained is close to 1 W with a cold side temperature below 40 °C. The limited values of these physical parameters allow obtaining a portable and safe device. The generator has been fully characterized in different ranges of fuel flow rates and the performances have been thoroughly analysed for processes optimization and efficiency improvement.

In recent years, the portable technology is receiving a great interest and significant improvement due to the progresses in electronic technology development and energy storage solutions. The decrease in power requirements for working energy systems, due to the increased efficiency and to the reduction in components size, opens the access to new solutions for power supplying. In particular, alternative backup systems for battery charging or replacement could be designed taking advantage of unconventional technologies. It is the case of small photovoltaic portable panels or fuel cells technology: in these solutions different sources are used to produce limited electrical powers required to keep devices on. In this paper, a thermoelectric solution for the power generation has been considered: the generator has been designed and assembled starting from a catalytic combustor. Catalytic combustion allows safe control of the processes, and the choice of a hydrocarbon fuel ensures the power availability and a fast recharge. The size of the system is set to fit a volume close to the one of AA batteries. The electrical power output obtained is close to 1 W with a cold side temperature below 40 °C. The limited values of these physical parameters allow obtaining a portable and safe device. The generator has been fully characterized in different ranges of fuel flow rates and the performances have been thoroughly analysed for processes optimization and efficiency improvement.