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This paper investigates the impact of the standard approximations embodied in the well-known Momentum Theory on its performance prediction capabilities. To this aim, the results of the momentum theory, which is still widely used in all Blade Element/Momentum codes for the analysis and/or design of wind turbines, are compared with those obtained with an actuator disk model based on Computational Fluid Dynamics techniques. In this method, the axisymmetric and steady Euler equations are solved with a classical finite volume approach, while the turbine effects are modelled through a set of axial and tangential body forces distributed over a disk shaped region representing the rotor swept surface. Since this method does not rely on the momentum theory simplifying assumptions, it can be suitably employed to verify the momentum theory validity. The analysis is carried out using the well documented experimental data of the National Renewable Energy Laboratory Phase VI wind turbine.

Dataset supporting publication of manuscript_GCB-B-RA-24-138

Dielectric and anelastic spectroscopies are complementary techniques and their combination allows valuable information to be obtained in the field of multifunctional materials. Whereas the dielectric spectroscopy measures the dielectric susceptibility ?(?,T) and it is sensitive to fluctuations of electric dipoles, the anelastic spectroscopy measures the elastic compliance or elastic susceptibility s(?,T) and it is sensitive to fluctuations of elastic dipoles. Both susceptibilities are complex, their immaginary part being due to the delayed response of the mobile defects coupled to the electric field/stress. The great advantage of using a combination of both techniques is that the anelastic measurements are insensitive to free charges, therefore it is possible to measure the dynamics of ions also in the presence of free charges. Two main types of investigations have been pursued by the combination of these techniques: the study of structural phase transitions and the study of microscopic mechanisms associated with the presence of defects, both important for the knowledge and development of multifunctional materials. We have applied this approach for different functional materials with perovskite framework: multiferroic, ferroelectric and relaxor ferroelectric ceramics, and organic-inorganic perovskite photovoltaics. Thanks to the combination of the two spectroscopies, it has been possible to probe more accurately the structural transitions involving the antiferrodisortive tilt modes of the octahedra in PZT [1] and NBT-BT [2]. It was also possible to evidence incipient phase separation in lead titanate-based multiferroics [3]. Moreover, since the elastic response is insensitive to free charges, it has been used to probe the piezoelectric response even in unpoled ceramics [4] and for the study of coexisting ferroelectric and metallic states [5]. The combination of the two techniques allowed also new features to be revealed on the reorientation dynamics of the organic molecules in MAPbI3 photovoltaic organic-inorganic perovskites and the hindrance of their ferroelectric order by coupling with the tilt modes [6]. 1. F. Cordero, F. Trequattrini, F. Craciun, C. Galassi, Phys. Rev. B, 87 (2013) 094108 2. F. Cordero, F. Craciun, F. Trequattrini, et al., Phys. Rev. B, 81 (2010) 144124 3. F. Craciun, F. Cordero, B. Vasile, et al., Phys. Chem. Chem. Phys., 20 (2018) 14652 4. F. Cordero, F. Craciun, F. Trequattrini, C. Galassi, Phys. Rev. B, 93 (2016) 174111 5. F. Cordero, F. Trequattrini, F. Craciun, et al., Phys. Rev. B, 99 (2019) 064106 6. F. Cordero, F. Craciun, F. Trequattrini, et al., J. Phys. Chem. Lett., 9 (2018) 4401

1. Marine Heat Waves (MHWs) are episodes of anomalous warming in the ocean that can last from a few days to months. MHWs have different characteristics in terms of intensity, duration, and frequency and generate thermal stress on marine ecosystems. In reef ecosystems, they are one of the main causes of decreased presence and abundance of corals, invertebrates, and fish. The deleterious capacity of thermal stress often depends upon biotic factors such as resource availability (bottom-up control on predators) and predation (top-down control on prey). Despite the evidence of thermal stress and biotic factors affecting individual species, the combined effects of both stressors on the entire reef ecosystems are far less studied. 2. Here, using a food-web modeling approach, we estimated the rate of change in species’ biomass due to different MHW scenarios based on their physical characteristics. Specifically, we modeled the mechanistic link between species’ consumption rate and seawater temperature (thermal stressor), simulating species’ biomass dynamics for different MHW scenarios under different trophic control assumptions (biotic factor). 3. We find that total reef ecosystem biomass declined by 10% ± 5% under MHWs with severe intensity and top-down control assumption. The bottom-up control assumption moderates the total ecosystem biomass reduction by 5% ± 5%. Irrespective of the MHW scenario and the trophic control assumption, the most substantial biomass changes occur among top, meso-predators, and corals (5% to 20% ± 10%).4. Since habitat degradation may lead to reef ecosystems governed by top-down control on prey, our findings point to the critical importance of protecting reef ecosystems as a pivotal strategy to alleviate the impacts of thermal stress induced by MHWs. Overall, our results provide a unified understanding of the interplay between abiotic stressors and biotic factors in reef ecosystems under extreme thermal events, offering insights into present baselines and future ecological states for reef ecosystems.

Dolomite-based binders are characterised by interesting technical and environmental features. For their synthesis, sources of both CaO and MgO are required. The idea developed in this work is to couple the synthesis of dolomite-based binders, starting from a natural dolomite, through the concept of concentrated solar energy (needed to drive the endothermal dolomite calcination process) in fluidised bed reactors. To this end, a fluidised bed system, where the concentrated solar radiation is mimicked by the use of Xe-lamps (short-arc), has been set up and operated. Natural dolomite (sieved in the 420-590 ?m size range) was calcined at a nominal temperature of 850 °C, and bed temperature profiles during solar-driven calcination were investigated. Then, four binders were prepared by mixing slaked dolomite (obtained from the hydration of solar calcined dolomite) with either blast furnace slag or coal fly ash as supplementary cementitious materials. The binders were hydrated for curing times ranging from 7 to 56 days. X-ray fluorescence, X-ray diffraction and combined differential thermal and thermogravimetric analyses were employed as characterisation techniques both to analyse the chemical composition of starting materials and to investigate the evolution of the hydration in the four systems.

Наукове дослідження висвітлює актуальні проблеми залежності Європейського Союзу (далі – ЄС) від поставок енергетичних ресурсів з Росії на тлі військової агресії в бік України та обґрунтовується значимість подолання такої залежності. Вторгнення в Україну істотно похитнуло стан енергетичної безпеки держав-членів ЄС та всього європейському континенту загалом. Це, в свою чергу, активізувало процес розробки нової та вдосконалення існуючої правової бази ЄС в енергетичній сфері у максимально звужені строки. Автор статті аналізує сукупність законодавчих ініціатив ЄС, що мають на меті допомогти державам-членам пройти опалювальний сезон без масштабних потрясінь. З проаналізованих автором пропозицій Європейської Комісії вбачається, що істотний внесок у подолання європейської енергетичної залежності від Росії можуть внести положення трансформаційного плану REPowerEU, що передбачає використання для потреб ЄС екологічно чистої енергетики. Автор доходить до висновку, що економічно ефективне, швидке та широкомасштабне розгортання сталої відновлювальної енергії відповідно до положень Європейської зеленої угоди та повідомлення REPowerEU не може бути досягнуто державами-членами самостійно. Визначено, що нівелювання негативних наслідків неможливе без ефективної координації та об’єднанні дій всіх держав-членів ЄС. Останні десятиліття енергетична політика є центральним пунктом зовнішньої політики ЄС та наразі виступає джерелом багатьох суперечок, які перешкоджають спробам ЄС налагодити стратегічні відносини зі своїми сусідами та постачальники енергії. Тому дослідження проблем залежності від третіх країн та пошук шляхів їх вирішення відповідає найважливішим потребам сучасності та має суттєве значення для подальшого розвитку енергетичного сектору ЄС. Підсумовано, що така сукупність заходів неодмінно буде супроводжуватися наслідками економічного характеру в бюджетній сфері, в інвестиційній політиці, структурі галузевого виробництва, в сфері амортизаційних видатків, ціновій політиці та оподаткуванні тощо. Problem setting. The article ...

Abstract The use of simplifying techniques to obtain skeletal kinetic mechanisms with the required accuracy is often a necessary step when computationally demanding simulations are concerned. In this work, a novel approach for an automatic mechanism reduction, aimed at retaining accuracy on specific target species, is proposed. Starting from the consolidated coupling between flux analysis and sensitivity analysis, a methodology based on curve matching and functional data analysis was developed, through which the importance of a species in the target accuracy is assessed via a proper metric. The error associated with the removal of uncertain species from the detailed mechanism is quantified in terms of distance and similarity indices before and after such a removal, within a Species-Targeted Sensitivity Analysis (STSA) framework. A species ranking is then generated, and the original mechanism is progressively reduced. The whole algorithm also implements several improvements to enhance a faster convergence, and adds a novel criterion to remove unimportant reactions, based on sensitivity analysis to kinetic parameters. The capability of this algorithm was tested through two case studies in this work. A kinetic mechanism for a Toluene Reference Fuel (TRF) was first obtained, with the overall reactivity as reduction target. The numerical procedure allowed to obtain a compact skeletal mechanism (115 species and 856 reactions), able to retain good accuracy in ignition delay time and laminar flame speed predictions of both fuel mixture and pure compounds. More important, two skeletal mechanisms for methane combustion, including chemistry of nitrogen oxides (NO x ), were developed, with different degrees of reduction. The agreement between the original and the skeletal mechanisms in terms of NO formation was successfully assessed with satisfactory results. Attention was also dedicated to the choice of the type of reactor where undertaking reduction, which turned out to play a major role in the overall process.